Assembly of highly efficient overall CO2 + H2O electrolysis cell with the matchup of CO2 reduction and water oxidation catalyst

The exploitation of highly active and stable catalysts for reduction of CO2 and water oxidation is one of the approaches to facilitate scalable and sustainable CO2 reduction potentially at the industrial scale. Herein, a feasible strategy to rationally build an overall CO2 + H2O electrocatalytic rea...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2023-11, Vol.52 (46), p.17273-17278
Hauptverfasser:	Zhang, Li, Hong-Lin, Zhu, Zhong-Yi, Li, Yue-Qing, Zheng
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbon dioxide Catalysts Catalytic activity Electrolysis Oxidation Oxygen evolution reactions
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container_title	Dalton transactions : an international journal of inorganic chemistry
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creator	Zhang, Li Hong-Lin, Zhu Zhong-Yi, Li Yue-Qing, Zheng
description	The exploitation of highly active and stable catalysts for reduction of CO2 and water oxidation is one of the approaches to facilitate scalable and sustainable CO2 reduction potentially at the industrial scale. Herein, a feasible strategy to rationally build an overall CO2 + H2O electrocatalytic reaction device is the preparation and matchup of a high-performance CO2 reduction catalyst and low-cost and highly active oxygen anode catalyst. A heterostructured nanosheet, γ-NiOOH/NiCO3/Ni(HCOO)2, exhibited superior catalytic activity in the oxygen evolution reaction, and was integrated with CoPc/Fe–N–C to build an overall CO2 + H2O cell with a current density of 10 mA cm−2 at a very low cell voltage of 1.97 V, and the faradaic deficiency of CO2 to CO was maintained at greater than 90% at 1.9 V.
doi_str_mv	10.1039/d3dt02599c
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source	Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects	Carbon dioxide Catalysts Catalytic activity Electrolysis Oxidation Oxygen evolution reactions
title	Assembly of highly efficient overall CO2 + H2O electrolysis cell with the matchup of CO2 reduction and water oxidation catalyst
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