Dual Catalysis of Gold Nanoclusters: Photocatalytic Cross‐Dehydrogenative Coupling by Cooperation of Superatomic Core and Molecularly Modified Staples

Thiolate‐protected gold nanoclusters (AuNCs) have attracted significant attention as nano‐catalysts, revealing a superatomic core and gold‐thiolate staples as distinct structural units. Here, we demonstrate the unprecedented dual catalytic activity of thiolate‐protected [Au25(SR)18]− nanoclusters, i...

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Veröffentlicht in:	Angewandte Chemie International Edition 2024-01, Vol.63 (2), p.e202312135-n/a
Hauptverfasser:	Isozaki, Katsuhiro, Iseri, Kenta, Saito, Ryohei, Ueda, Kyosuke, Nakamura, Masaharu
Format:	Artikel
Sprache:	eng
Schlagworte:	Aliphatic amines Alkynes Amines Carbon Catalysis Catalysts Catalytic activity Coupling Cross-Dehydrogenative Coupling Dehydrogenation Density functional theory Dual Catalysis Gold Gold Nanocluster Intermolecular Interaction Ligands Nanoclusters Photocatalyst Photosensitization Staples
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