Determination of dynamic mechanical properties of engineering thermoplastics at wide frequency range using Havriliak-Negami model
Using Havriliak–Negami (HN) model of time–temperature superposition, dynamic mechanical properties for two thermorheologically simple engineering thermoplastics, viz., polyether ether ketone (PEEK) and polycarbonate (PC) were determined. Calculations have been made with respect to (i) temperature‐in...
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| Veröffentlicht in: | Journal of applied polymer science 2006-04, Vol.100 (1), p.677-683 |
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| container_title | Journal of applied polymer science |
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| creator | Setua, D. K. Gupta, Y. N. Kumar, S. Awasthi, R. Mall, A. Sekhar, K. |
| description | Using Havriliak–Negami (HN) model of time–temperature superposition, dynamic mechanical properties for two thermorheologically simple engineering thermoplastics, viz., polyether ether ketone (PEEK) and polycarbonate (PC) were determined. Calculations have been made with respect to (i) temperature‐independent HN parameters from dynamic mechanical analysis (DMA) and (ii) activation energies of the deformation processes involved. Viscoelastic properties, over a wide frequency range, were predicted from the HN model, which were further correlated with the experimentally determined quantities and chemical structure of the polymers. The mathematical calculations were done using Matlab® software. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 677–683, 2006 |
| doi_str_mv | 10.1002/app.23194 |
| format | Article |
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Viscoelastic properties, over a wide frequency range, were predicted from the HN model, which were further correlated with the experimentally determined quantities and chemical structure of the polymers. The mathematical calculations were done using Matlab® software. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 677–683, 2006</description><subject>activation energy</subject><subject>Applied sciences</subject><subject>dynamic mechanical analysis</subject><subject>Exact sciences and technology</subject><subject>Matlab</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Properties and characterization</subject><subject>Rheology and viscoelasticity</subject><subject>thermoplastic</subject><subject>time-temperature superposition</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><recordid>eNp1kE9v1DAQxS0EEkvhwDfwBSQOae04_ndsC22RqlJQK7hZgzPZmiZOamfb7rHfHC9byonTaDS_92bmEfKWs13OWL0H07RbC26bZ2TBmdVVo2rznCzKjFfGWvmSvMr5F2OcS6YW5OEjzpiGEGEOY6RjR9t1hCF4OqC_ghg89HRK44RpDpg3AMZliIgpxCWdr4p4nHrIc_CZwkzvQou0S3izwujXNEFcIl3lDXwCtyn0Aa6rM1yWHXQYW-xfkxcd9BnfPNYdcnn06eLwpDr9cvz5cP-08kKZpmqMBlt7JVtras1s00ENou1A_PSiReCtbFssrbagDePWG2UlazSi8qqgO-T91rd8U47LsxtC9tj3EHFcZVcbI6SUooAftqBPY84JOzelMEBaO87cJmRXQnZ_Qi7su0dTyCWprrzrQ_4n0EopXtvC7W25u9Dj-v-Gbv_8_K9ztVWEPOP9kwLStVNaaOm-nx27g6Nv0hz8-Oqk-A3YIJ2M</recordid><startdate>20060405</startdate><enddate>20060405</enddate><creator>Setua, D. 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K.</au><au>Gupta, Y. N.</au><au>Kumar, S.</au><au>Awasthi, R.</au><au>Mall, A.</au><au>Sekhar, K.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Determination of dynamic mechanical properties of engineering thermoplastics at wide frequency range using Havriliak-Negami model</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2006-04-05</date><risdate>2006</risdate><volume>100</volume><issue>1</issue><spage>677</spage><epage>683</epage><pages>677-683</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>Using Havriliak–Negami (HN) model of time–temperature superposition, dynamic mechanical properties for two thermorheologically simple engineering thermoplastics, viz., polyether ether ketone (PEEK) and polycarbonate (PC) were determined. Calculations have been made with respect to (i) temperature‐independent HN parameters from dynamic mechanical analysis (DMA) and (ii) activation energies of the deformation processes involved. Viscoelastic properties, over a wide frequency range, were predicted from the HN model, which were further correlated with the experimentally determined quantities and chemical structure of the polymers. The mathematical calculations were done using Matlab® software. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 677–683, 2006</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.23194</doi><tpages>7</tpages></addata></record> |
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| subjects | activation energy Applied sciences dynamic mechanical analysis Exact sciences and technology Matlab Organic polymers Physicochemistry of polymers Properties and characterization Rheology and viscoelasticity thermoplastic time-temperature superposition |
| title | Determination of dynamic mechanical properties of engineering thermoplastics at wide frequency range using Havriliak-Negami model |
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