Highly Birefringent d0 Transition Metal Fluoroantimonite in the Mid Infrared Band: Order–Disorder Regulation by Cationic Size

An unusual O/F ordered d0 transition metal fluoroantimonite, namely, K2SbMoO2F7, has been created by the cationic size effect of alkali metals. It features the largest birefringence of 0.220@550 nm among inorganic antimonites with a halogen element, which is an order of magnitude larger than the dis...

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Veröffentlicht in:	Journal of the American Chemical Society 2023-11, Vol.145 (44), p.24416-24424
Hauptverfasser:	Wu, Jia-Hang, Hu, Chun-Li, Jiang, Ting-Kun, Mao, Jiang-Gao, Kong, Fang
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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