Construction of Cyclic Nitrones Enabled by Photodriven and Gold-Catalyzed 1,3-Azaprotio Transfer of Allenyloximes

A protocol was developed to construct five- to seven-membered cyclic nitrones through the gold-catalyzed 1,3-azaprotio transfer of allenyloximes under photoirradiation. The photoisomerization of oximes was suggested to convert the inert stereoisomer to a reactive one. This photodriven and gold-catal...

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Veröffentlicht in:Journal of organic chemistry 2023-11, Vol.88 (21), p.15395-15403
Hauptverfasser: Qi, Zhenjie, Wang, Shaozhong
Format: Artikel
Sprache:eng
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