The role of the metal/oxide interface in the growth of passive films in aqueous environments
A mechanistic methodology has been developed to understand the role of the metal/scale interface in the growth of scales at high temperatures. Specifically, cation vacancies arriving at the metal/scale interface are annihilated by the climb of misfit and misorientation interfacial dislocations. If t...
Gespeichert in:
| Veröffentlicht in: | Corrosion science 2005, Vol.47 (1), p.247-256 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 256 |
|---|---|
| container_issue | 1 |
| container_start_page | 247 |
| container_title | Corrosion science |
| container_volume | 47 |
| creator | Pieraggi, Bernard MacDougall, Barry Rapp, Robert A. |
| description | A mechanistic methodology has been developed to understand the role of the metal/scale interface in the growth of scales at high temperatures. Specifically, cation vacancies arriving at the metal/scale interface are annihilated by the climb of misfit and misorientation interfacial dislocations. If this mechanism is blocked, e.g. by the tangling of dislocations within the metal, then cation diffusion cannot continue to support the growth of an adherent oxide. To the extent that adherent, crystalline and epitaxial passive or anodic films formed in aqueous environments also grow by cation diffusion over vacancies, the same mechanisms must apply. The segregation of large reactive element cations to the metal/scale interface and their importance in enhancing scale adherence by blocking vacancy annihilation, also constitute concepts that might find relevance for passive films in aqueous solutions. |
| doi_str_mv | 10.1016/j.corsci.2004.03.004 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_28788392</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0010938X04000599</els_id><sourcerecordid>28788392</sourcerecordid><originalsourceid>FETCH-LOGICAL-c507t-529e2a544b1577d0e6670fdbd3b043bd9dccc65c58050239d0fb106e4c248f113</originalsourceid><addsrcrecordid>eNqNkEtLxDAUhYMoOI7-Axfd6K71pklfG0HEFwhuFFwIIU1unAxtMyZ11H9v6gy4E1fnkvvdk8Mh5JhCRoGWZ8tMOR-UzXIAngHLouyQGa2rJgXelLtkBkAhbVj9vE8OQlgCQB5fZuTlcYGJdx0mziRjnHscZXfmPq3GxA4jeiPVNP0sX737GBcTupIh2DUmxnZ9mNby7R3de0hwWFvvhh6HMRySPSO7gEdbnZOn66vHy9v0_uHm7vLiPlUFVGNa5A3msuC8pUVVacCyrMDoVrMWOGt1o5VSZaGKGgrIWaPBtBRK5CrntaGUzcnpxnflXYwRRtHboLDr5DBlEnld1TVr8n-A5VRME0G-AZV3IXg0YuVtL_2XoCCmzsVSbDoXU-cCmIgSz062_jIo2RkvB2XD723JOI9hIne-4TC2srboRXTCQaG2HtUotLN_f_QN7uKZiw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>28600209</pqid></control><display><type>article</type><title>The role of the metal/oxide interface in the growth of passive films in aqueous environments</title><source>Access via ScienceDirect (Elsevier)</source><creator>Pieraggi, Bernard ; MacDougall, Barry ; Rapp, Robert A.</creator><creatorcontrib>Pieraggi, Bernard ; MacDougall, Barry ; Rapp, Robert A.</creatorcontrib><description>A mechanistic methodology has been developed to understand the role of the metal/scale interface in the growth of scales at high temperatures. Specifically, cation vacancies arriving at the metal/scale interface are annihilated by the climb of misfit and misorientation interfacial dislocations. If this mechanism is blocked, e.g. by the tangling of dislocations within the metal, then cation diffusion cannot continue to support the growth of an adherent oxide. To the extent that adherent, crystalline and epitaxial passive or anodic films formed in aqueous environments also grow by cation diffusion over vacancies, the same mechanisms must apply. The segregation of large reactive element cations to the metal/scale interface and their importance in enhancing scale adherence by blocking vacancy annihilation, also constitute concepts that might find relevance for passive films in aqueous solutions.</description><identifier>ISSN: 0010-938X</identifier><identifier>EISSN: 1879-0496</identifier><identifier>DOI: 10.1016/j.corsci.2004.03.004</identifier><identifier>CODEN: CRRSAA</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>Anodic film ; Applied sciences ; Cation diffusion ; Corrosion ; Corrosion environments ; Corrosion mechanisms ; Exact sciences and technology ; Film growth ; Metals. Metallurgy ; Vacancy annihilation</subject><ispartof>Corrosion science, 2005, Vol.47 (1), p.247-256</ispartof><rights>2004 Elsevier Ltd</rights><rights>2005 INIST-CNRS</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c507t-529e2a544b1577d0e6670fdbd3b043bd9dccc65c58050239d0fb106e4c248f113</citedby><cites>FETCH-LOGICAL-c507t-529e2a544b1577d0e6670fdbd3b043bd9dccc65c58050239d0fb106e4c248f113</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.corsci.2004.03.004$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,4024,27923,27924,27925,45995</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=16344287$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Pieraggi, Bernard</creatorcontrib><creatorcontrib>MacDougall, Barry</creatorcontrib><creatorcontrib>Rapp, Robert A.</creatorcontrib><title>The role of the metal/oxide interface in the growth of passive films in aqueous environments</title><title>Corrosion science</title><description>A mechanistic methodology has been developed to understand the role of the metal/scale interface in the growth of scales at high temperatures. Specifically, cation vacancies arriving at the metal/scale interface are annihilated by the climb of misfit and misorientation interfacial dislocations. If this mechanism is blocked, e.g. by the tangling of dislocations within the metal, then cation diffusion cannot continue to support the growth of an adherent oxide. To the extent that adherent, crystalline and epitaxial passive or anodic films formed in aqueous environments also grow by cation diffusion over vacancies, the same mechanisms must apply. The segregation of large reactive element cations to the metal/scale interface and their importance in enhancing scale adherence by blocking vacancy annihilation, also constitute concepts that might find relevance for passive films in aqueous solutions.</description><subject>Anodic film</subject><subject>Applied sciences</subject><subject>Cation diffusion</subject><subject>Corrosion</subject><subject>Corrosion environments</subject><subject>Corrosion mechanisms</subject><subject>Exact sciences and technology</subject><subject>Film growth</subject><subject>Metals. Metallurgy</subject><subject>Vacancy annihilation</subject><issn>0010-938X</issn><issn>1879-0496</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><recordid>eNqNkEtLxDAUhYMoOI7-Axfd6K71pklfG0HEFwhuFFwIIU1unAxtMyZ11H9v6gy4E1fnkvvdk8Mh5JhCRoGWZ8tMOR-UzXIAngHLouyQGa2rJgXelLtkBkAhbVj9vE8OQlgCQB5fZuTlcYGJdx0mziRjnHscZXfmPq3GxA4jeiPVNP0sX737GBcTupIh2DUmxnZ9mNby7R3de0hwWFvvhh6HMRySPSO7gEdbnZOn66vHy9v0_uHm7vLiPlUFVGNa5A3msuC8pUVVacCyrMDoVrMWOGt1o5VSZaGKGgrIWaPBtBRK5CrntaGUzcnpxnflXYwRRtHboLDr5DBlEnld1TVr8n-A5VRME0G-AZV3IXg0YuVtL_2XoCCmzsVSbDoXU-cCmIgSz062_jIo2RkvB2XD723JOI9hIne-4TC2srboRXTCQaG2HtUotLN_f_QN7uKZiw</recordid><startdate>2005</startdate><enddate>2005</enddate><creator>Pieraggi, Bernard</creator><creator>MacDougall, Barry</creator><creator>Rapp, Robert A.</creator><general>Elsevier Ltd</general><general>Elsevier Science</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SE</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>JG9</scope><scope>L7M</scope><scope>H8D</scope></search><sort><creationdate>2005</creationdate><title>The role of the metal/oxide interface in the growth of passive films in aqueous environments</title><author>Pieraggi, Bernard ; MacDougall, Barry ; Rapp, Robert A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c507t-529e2a544b1577d0e6670fdbd3b043bd9dccc65c58050239d0fb106e4c248f113</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><topic>Anodic film</topic><topic>Applied sciences</topic><topic>Cation diffusion</topic><topic>Corrosion</topic><topic>Corrosion environments</topic><topic>Corrosion mechanisms</topic><topic>Exact sciences and technology</topic><topic>Film growth</topic><topic>Metals. Metallurgy</topic><topic>Vacancy annihilation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pieraggi, Bernard</creatorcontrib><creatorcontrib>MacDougall, Barry</creatorcontrib><creatorcontrib>Rapp, Robert A.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Corrosion Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Aerospace Database</collection><jtitle>Corrosion science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pieraggi, Bernard</au><au>MacDougall, Barry</au><au>Rapp, Robert A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The role of the metal/oxide interface in the growth of passive films in aqueous environments</atitle><jtitle>Corrosion science</jtitle><date>2005</date><risdate>2005</risdate><volume>47</volume><issue>1</issue><spage>247</spage><epage>256</epage><pages>247-256</pages><issn>0010-938X</issn><eissn>1879-0496</eissn><coden>CRRSAA</coden><abstract>A mechanistic methodology has been developed to understand the role of the metal/scale interface in the growth of scales at high temperatures. Specifically, cation vacancies arriving at the metal/scale interface are annihilated by the climb of misfit and misorientation interfacial dislocations. If this mechanism is blocked, e.g. by the tangling of dislocations within the metal, then cation diffusion cannot continue to support the growth of an adherent oxide. To the extent that adherent, crystalline and epitaxial passive or anodic films formed in aqueous environments also grow by cation diffusion over vacancies, the same mechanisms must apply. The segregation of large reactive element cations to the metal/scale interface and their importance in enhancing scale adherence by blocking vacancy annihilation, also constitute concepts that might find relevance for passive films in aqueous solutions.</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.corsci.2004.03.004</doi><tpages>10</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0010-938X |
| ispartof | Corrosion science, 2005, Vol.47 (1), p.247-256 |
| issn | 0010-938X 1879-0496 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_28788392 |
| source | Access via ScienceDirect (Elsevier) |
| subjects | Anodic film Applied sciences Cation diffusion Corrosion Corrosion environments Corrosion mechanisms Exact sciences and technology Film growth Metals. Metallurgy Vacancy annihilation |
| title | The role of the metal/oxide interface in the growth of passive films in aqueous environments |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-19T16%3A49%3A40IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=The%20role%20of%20the%20metal/oxide%20interface%20in%20the%20growth%20of%20passive%20films%20in%20aqueous%20environments&rft.jtitle=Corrosion%20science&rft.au=Pieraggi,%20Bernard&rft.date=2005&rft.volume=47&rft.issue=1&rft.spage=247&rft.epage=256&rft.pages=247-256&rft.issn=0010-938X&rft.eissn=1879-0496&rft.coden=CRRSAA&rft_id=info:doi/10.1016/j.corsci.2004.03.004&rft_dat=%3Cproquest_cross%3E28788392%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=28600209&rft_id=info:pmid/&rft_els_id=S0010938X04000599&rfr_iscdi=true |