Nanofibers of self-doped polyaniline
Self-doping polyaniline (SPANI) nanofibers were synthesized by using self-assembly process consisting of a self-doping monomer ( o-aminobenzenesulfonic acid, SAN) and aniline (AN). SAN plays the key roles of a self-doping monomer and a surfactant in the process of forming nanofibers. TEM and SEM res...
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| Veröffentlicht in: | Polymer (Guilford) 2005-11, Vol.46 (24), p.10688-10698 |
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| creator | Yang, Chien-Hsin Chih, Yi-Kai Cheng, Hsyi-En Chen, Cheng-Ho |
| description | Self-doping polyaniline (SPANI) nanofibers were synthesized by using self-assembly process consisting of a self-doping monomer (
o-aminobenzenesulfonic acid, SAN) and aniline (AN). SAN plays the key roles of a self-doping monomer and a surfactant in the process of forming nanofibers. TEM and SEM results revealed that the morphology, average diameter of the resulting nanofibers depended on the mole ratio of AN to SAN and reaction conditions. NMR, FTIR, XPS, UV–vis spectra were used to describe the molecular structures of the nanofibers. X-ray diffraction was used to characterize the crystallinity in these structures. Results revealed that the molecular structures of polymer chains were similar to those of the emeraldine form of polyaniline (PANI). The doping degree ranged from 21 to 27% corresponding to the AN/SAN mole ratio from 4 to 1. |
| doi_str_mv | 10.1016/j.polymer.2005.09.044 |
| format | Article |
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o-aminobenzenesulfonic acid, SAN) and aniline (AN). SAN plays the key roles of a self-doping monomer and a surfactant in the process of forming nanofibers. TEM and SEM results revealed that the morphology, average diameter of the resulting nanofibers depended on the mole ratio of AN to SAN and reaction conditions. NMR, FTIR, XPS, UV–vis spectra were used to describe the molecular structures of the nanofibers. X-ray diffraction was used to characterize the crystallinity in these structures. Results revealed that the molecular structures of polymer chains were similar to those of the emeraldine form of polyaniline (PANI). The doping degree ranged from 21 to 27% corresponding to the AN/SAN mole ratio from 4 to 1.</description><identifier>ISSN: 0032-3861</identifier><identifier>EISSN: 1873-2291</identifier><identifier>DOI: 10.1016/j.polymer.2005.09.044</identifier><identifier>CODEN: POLMAG</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>Applied sciences ; Exact sciences and technology ; Nanofibers ; Organic polymers ; Physicochemistry of polymers ; Polymers with particular properties ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; Self assembly ; Self-doping polyaniline (SPANI)</subject><ispartof>Polymer (Guilford), 2005-11, Vol.46 (24), p.10688-10698</ispartof><rights>2005 Elsevier Ltd</rights><rights>2005 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c438t-854175fc67cf78b41383d055681980908764c28053207a19b27f47a759c3200b3</citedby><cites>FETCH-LOGICAL-c438t-854175fc67cf78b41383d055681980908764c28053207a19b27f47a759c3200b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.polymer.2005.09.044$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3548,27922,27923,45993</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=17217934$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Yang, Chien-Hsin</creatorcontrib><creatorcontrib>Chih, Yi-Kai</creatorcontrib><creatorcontrib>Cheng, Hsyi-En</creatorcontrib><creatorcontrib>Chen, Cheng-Ho</creatorcontrib><title>Nanofibers of self-doped polyaniline</title><title>Polymer (Guilford)</title><description>Self-doping polyaniline (SPANI) nanofibers were synthesized by using self-assembly process consisting of a self-doping monomer (
o-aminobenzenesulfonic acid, SAN) and aniline (AN). SAN plays the key roles of a self-doping monomer and a surfactant in the process of forming nanofibers. TEM and SEM results revealed that the morphology, average diameter of the resulting nanofibers depended on the mole ratio of AN to SAN and reaction conditions. NMR, FTIR, XPS, UV–vis spectra were used to describe the molecular structures of the nanofibers. X-ray diffraction was used to characterize the crystallinity in these structures. Results revealed that the molecular structures of polymer chains were similar to those of the emeraldine form of polyaniline (PANI). The doping degree ranged from 21 to 27% corresponding to the AN/SAN mole ratio from 4 to 1.</description><subject>Applied sciences</subject><subject>Exact sciences and technology</subject><subject>Nanofibers</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polymers with particular properties</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>Self assembly</subject><subject>Self-doping polyaniline (SPANI)</subject><issn>0032-3861</issn><issn>1873-2291</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><recordid>eNqNkEtLAzEUhYMoWKs_QehC3c1485okKxHxBUU3ug6ZTAIp6WRMWqH_3hlacKmrC5fvnAMfQpcYagy4uV3VQ4q7tcs1AeA1qBoYO0IzLAWtCFH4GM0AKKmobPApOitlBQCEEzZDV2-mTz60LpdF8ovioq-6NLhuMXWaPsTQu3N04k0s7uJw5-jz6fHj4aVavj-_PtwvK8uo3FSSMyy4t42wXsiWYSppB5w3EisJCqRomCUSOCUgDFYtEZ4JI7iy4wdaOkc3-94hp6-tKxu9DsW6GE3v0rZoIoVkirN_gFwJCmoE-R60OZWSnddDDmuTdxqDnuTplT7I05M8DUqP8sbc9WHAFGuiz6a3ofyGBcFC0Ym723Nu1PIdxpZig-ut60J2dqO7FP5Y-gG60ISj</recordid><startdate>20051121</startdate><enddate>20051121</enddate><creator>Yang, Chien-Hsin</creator><creator>Chih, Yi-Kai</creator><creator>Cheng, Hsyi-En</creator><creator>Chen, Cheng-Ho</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><scope>F28</scope><scope>FR3</scope></search><sort><creationdate>20051121</creationdate><title>Nanofibers of self-doped polyaniline</title><author>Yang, Chien-Hsin ; Chih, Yi-Kai ; Cheng, Hsyi-En ; Chen, Cheng-Ho</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c438t-854175fc67cf78b41383d055681980908764c28053207a19b27f47a759c3200b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><topic>Applied sciences</topic><topic>Exact sciences and technology</topic><topic>Nanofibers</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polymers with particular properties</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>Self assembly</topic><topic>Self-doping polyaniline (SPANI)</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yang, Chien-Hsin</creatorcontrib><creatorcontrib>Chih, Yi-Kai</creatorcontrib><creatorcontrib>Cheng, Hsyi-En</creatorcontrib><creatorcontrib>Chen, Cheng-Ho</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><jtitle>Polymer (Guilford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yang, Chien-Hsin</au><au>Chih, Yi-Kai</au><au>Cheng, Hsyi-En</au><au>Chen, Cheng-Ho</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Nanofibers of self-doped polyaniline</atitle><jtitle>Polymer (Guilford)</jtitle><date>2005-11-21</date><risdate>2005</risdate><volume>46</volume><issue>24</issue><spage>10688</spage><epage>10698</epage><pages>10688-10698</pages><issn>0032-3861</issn><eissn>1873-2291</eissn><coden>POLMAG</coden><abstract>Self-doping polyaniline (SPANI) nanofibers were synthesized by using self-assembly process consisting of a self-doping monomer (
o-aminobenzenesulfonic acid, SAN) and aniline (AN). SAN plays the key roles of a self-doping monomer and a surfactant in the process of forming nanofibers. TEM and SEM results revealed that the morphology, average diameter of the resulting nanofibers depended on the mole ratio of AN to SAN and reaction conditions. NMR, FTIR, XPS, UV–vis spectra were used to describe the molecular structures of the nanofibers. X-ray diffraction was used to characterize the crystallinity in these structures. Results revealed that the molecular structures of polymer chains were similar to those of the emeraldine form of polyaniline (PANI). The doping degree ranged from 21 to 27% corresponding to the AN/SAN mole ratio from 4 to 1.</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.polymer.2005.09.044</doi><tpages>11</tpages></addata></record> |
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| subjects | Applied sciences Exact sciences and technology Nanofibers Organic polymers Physicochemistry of polymers Polymers with particular properties Preparation, kinetics, thermodynamics, mechanism and catalysts Self assembly Self-doping polyaniline (SPANI) |
| title | Nanofibers of self-doped polyaniline |
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