Catalyst‐ and Additive‐free, Regioselective 1,6‐Hydroarylation of para‐Quinone Methides with Anilines in HFIP

A simple and efficient method for the synthesis of diarylmethyl‐functionalized anilines through the hexafluoroisopropanol (HFIP)‐mediated regioselective 1,6‐hydroarylation reaction of para‐quinone methides (p‐QMs) with anilines under catalyst‐ and additive‐free conditions is reported. Various kinds...

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Veröffentlicht in:	Chemistry, an Asian journal an Asian journal, 2023-12, Vol.18 (23), p.e202300792-n/a
Hauptverfasser:	Zhu, Longzhi, Ren, Yining, Liu, Xianping, Xu, Shipan, Li, Tao, Xu, Weifeng, Li, Zikang, Liu, Yu, Xiong, Biquan
Format:	Artikel
Sprache:	eng
Schlagworte:	1,6-Hydroarylation Amines Aniline Anilines Biological activity Catalysts Chemistry Green synthesis Hydrogen bonding Indoles para-Quinone methides Quinones Reaction mechanisms Regioselectivity Substrates Synthesis Transition-metal free catalysis
Online-Zugang:	Volltext
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