An Experimental and Theoretical Insight into I2/Br2 Oxidation of Bis(pyridin‐2‐yl)Diselane and Ditellane

The reactivity between bis(pyridin‐2‐yl)diselane oPy2Se2 and ditellane oPy2Te2 (L1 and L2, respectively; oPy=pyridyn‐2‐yl) and I2/Br2 is discussed. Single‐crystal structure analysis revealed that the reaction of L1 with I2 yielded [(HL1+)(I−)⋅5/2I2]∞ (1) in which monoprotonated cations HL1+ template...

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Veröffentlicht in:	Chemistry, an Asian journal an Asian journal, 2023-12, Vol.18 (23), p.e202300836-n/a
Hauptverfasser:	Aragoni, M. Carla, Podda, Enrico, Chaudhary, Savita, Bhasin, Aman K. K., Bhasin, Kuldip K., Coles, Simon J., Orton, James B., Isaia, Francesco, Lippolis, Vito, Pintus, Anna, Slawin, Alexandra M. Z., Woollins, J. Derek, Arca, Massimiliano
Format:	Artikel
Sprache:	eng
Schlagworte:	Chalcogen Bonding Chalcogen bonds Chemistry Crystal structure DFT dichalcogenide Electronic structure halogen Halogen Bonding Oxidation Raman Raman spectroscopy Self-assembly Structural analysis
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