Dependence of the phase separation process on the relative onset of network formation in simultaneous interpenetrating polymer networks
Morphology development during the synthesis at room temperature of an interpenetrating polyurethane/poly(methyl methacrylate) network was investigated by small-angle X-ray scattering in relation with their relative kinetics of formation, determined by Fourier transform infra red spectroscopy. When t...
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| Veröffentlicht in: | Polymer (Guilford) 2005-04, Vol.46 (10), p.3318-3322 |
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| container_title | Polymer (Guilford) |
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| creator | Widmaier, Jean-Michel Nilly, Alexandra Chenal, Jean-Marc Mathis, André |
| description | Morphology development during the synthesis at room temperature of an interpenetrating polyurethane/poly(methyl methacrylate) network was investigated by small-angle X-ray scattering in relation with their relative kinetics of formation, determined by Fourier transform infra red spectroscopy. When the time lag between the onset of the two reactions is short, macroscopic phase separation occurs as the polyurethane network is incompletely formed. However, when the time lag increases, the poly(methyl methacrylate) forms into a more continuous network which limits the growth of phase separation to a close environment. |
| doi_str_mv | 10.1016/j.polymer.2005.02.082 |
| format | Article |
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When the time lag between the onset of the two reactions is short, macroscopic phase separation occurs as the polyurethane network is incompletely formed. 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When the time lag between the onset of the two reactions is short, macroscopic phase separation occurs as the polyurethane network is incompletely formed. 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| ispartof | Polymer (Guilford), 2005-04, Vol.46 (10), p.3318-3322 |
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| language | eng |
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| source | Elsevier ScienceDirect Journals Complete |
| subjects | Applied sciences Exact sciences and technology Interpenetrating polymer network (IPN) Organic polymers Physicochemistry of polymers Polymerization Polyurethane Preparation, kinetics, thermodynamics, mechanism and catalysts Small angle X-ray scattering (SAXS) |
| title | Dependence of the phase separation process on the relative onset of network formation in simultaneous interpenetrating polymer networks |
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