A review of antibiotics in surface water and their removal by advanced electrocoagulation technologies

The overuse and misuse of antibiotics have posed a serious threat to environment and human health, and even given rise to antibiotic resistance genes (ARGs). Antibiotics are ubiquitous in surface water worldwide with concentrations ranging from ng/L to μg/L level, being widely detected in rivers, lakes, seawater, and even drinking water. To address this thorny issue, numerous advanced technologies have been implemented to remove antibiotics. Advanced electrocoagulation (AEC) technologies, known as the combination of EC and other technologies capable of generating •OH in situ, have garnered considerable attention owing to their advances and high efficiency. This critical review investigated >120 relevant publications from the last few years (2017–2023) for the global distribution of commonly used antibiotics in surface water and their removal by various AEC technologies. Significant AEC technologies, such as combined electro-Fenton and EC (EF-EC) and combined electro-oxidation and EC (EO-EC), were reviewed. Their mechanism and characteristics were detailed. The major research results on removing antibiotics or the application potentials were elaborately described and discussed. Finally, the application trends of AEC technologies, as well as the challenges that may arise were prospected. The recommendations for controlling global antibiotic contamination in surface water were shared. [Display omitted] •Antibiotics are widespread in surface water, with a maximum concentration of 16,216 ng/L.•Applications of AEC technologies in antibiotic treatment were discussed.••OH is the dominant species contributing to advanced oxidation.•EO-EC/EF-EC have been applied to actual antibiotic wastewater treatment.