Preparation of organo-soluble polyanilines in ionic liquid
A method for preparation of organo-soluble polyaniline (PANI) is described. Oxidative coupling polymerization of anilium chloride with ammonium persulfate in a new ionic liquid, 2-hydroxyethyl ammonium formate (HAF), gives organo-soluble polyaniline with appreciable molecular weights ( M w = 86,400)...
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| Veröffentlicht in: | Synthetic metals 2005-10, Vol.155 (1), p.105-109 |
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| container_title | Synthetic metals |
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| creator | Bıçak, Niyazi Şenkal, B. Filiz Sezer, Esma |
| description | A method for preparation of organo-soluble polyaniline (PANI) is described. Oxidative coupling polymerization of anilium chloride with ammonium persulfate in a new ionic liquid, 2-hydroxyethyl ammonium formate (HAF), gives organo-soluble polyaniline with appreciable molecular weights (
M
w
=
86,400). Interestingly polyaniline (PANI) prepared by this method is highly soluble in many organic solvents such as acetone, tetrahydrofurane, dioxane, dimethyformamide and
N-methyl, 2-pyrrolidinone. Thin films of PANI prepared at 0
°C (by solvent casting) show reasonable conductivities (up to 37.0
S
cm
−1) when doped with
p-toluene sulfonic acid. |
| doi_str_mv | 10.1016/j.synthmet.2005.06.010 |
| format | Article |
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M
w
=
86,400). Interestingly polyaniline (PANI) prepared by this method is highly soluble in many organic solvents such as acetone, tetrahydrofurane, dioxane, dimethyformamide and
N-methyl, 2-pyrrolidinone. Thin films of PANI prepared at 0
°C (by solvent casting) show reasonable conductivities (up to 37.0
S
cm
−1) when doped with
p-toluene sulfonic acid.</description><identifier>ISSN: 0379-6779</identifier><identifier>EISSN: 1879-3290</identifier><identifier>DOI: 10.1016/j.synthmet.2005.06.010</identifier><identifier>CODEN: SYMEDZ</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>Ammonium persulfate ; Applied sciences ; Exact sciences and technology ; Ionic liquid ; Organo-soluble polyaniline ; Oxidative polymerization ; Physicochemistry of polymers ; Polymerization ; Polymers and radiations</subject><ispartof>Synthetic metals, 2005-10, Vol.155 (1), p.105-109</ispartof><rights>2005 Elsevier B.V.</rights><rights>2006 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c439t-66211f0549cd2e8691cdc8dc07e545f1a9e3898b5881dcfb1dbb4bc3de9ab0ec3</citedby><cites>FETCH-LOGICAL-c439t-66211f0549cd2e8691cdc8dc07e545f1a9e3898b5881dcfb1dbb4bc3de9ab0ec3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.synthmet.2005.06.010$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=17283924$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Bıçak, Niyazi</creatorcontrib><creatorcontrib>Şenkal, B. Filiz</creatorcontrib><creatorcontrib>Sezer, Esma</creatorcontrib><title>Preparation of organo-soluble polyanilines in ionic liquid</title><title>Synthetic metals</title><description>A method for preparation of organo-soluble polyaniline (PANI) is described. Oxidative coupling polymerization of anilium chloride with ammonium persulfate in a new ionic liquid, 2-hydroxyethyl ammonium formate (HAF), gives organo-soluble polyaniline with appreciable molecular weights (
M
w
=
86,400). Interestingly polyaniline (PANI) prepared by this method is highly soluble in many organic solvents such as acetone, tetrahydrofurane, dioxane, dimethyformamide and
N-methyl, 2-pyrrolidinone. Thin films of PANI prepared at 0
°C (by solvent casting) show reasonable conductivities (up to 37.0
S
cm
−1) when doped with
p-toluene sulfonic acid.</description><subject>Ammonium persulfate</subject><subject>Applied sciences</subject><subject>Exact sciences and technology</subject><subject>Ionic liquid</subject><subject>Organo-soluble polyaniline</subject><subject>Oxidative polymerization</subject><subject>Physicochemistry of polymers</subject><subject>Polymerization</subject><subject>Polymers and radiations</subject><issn>0379-6779</issn><issn>1879-3290</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><recordid>eNqFkE1LAzEQhoMoWKt_Qfait10n-5l4UopfUNCDnkM2mdWUNGmTXaH_3l1a8ShzmDk8My_zEHJJIaNA65tVFneu_1pjn-UAVQZ1BhSOyIyyhqdFzuGYzKAY57pp-Ck5i3EFAJTn1YzcvgXcyCB7413iu8SHT-l8Gr0dWovJxtuddMYahzExLhkpoxJrtoPR5-SkkzbixaHPycfjw_viOV2-Pr0s7pepKgvep3WdU9pBVXKlc2Q1p0orphU0WJVVRyXHgnHWVoxRrbqW6rYtW1Vo5LIFVMWcXO_vboLfDhh7sTZRobXSoR-iyFlTTjWC9R5UwccYsBObYNYy7AQFMakSK_GrSkyqBNRiVDUuXh0SZFTSdkE6ZeLfdpOzgudTwN2ew_Hdb4NBRGXQKdQmoOqF9ua_qB88I4Q_</recordid><startdate>20051015</startdate><enddate>20051015</enddate><creator>Bıçak, Niyazi</creator><creator>Şenkal, B. Filiz</creator><creator>Sezer, Esma</creator><general>Elsevier B.V</general><general>Elsevier Science</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20051015</creationdate><title>Preparation of organo-soluble polyanilines in ionic liquid</title><author>Bıçak, Niyazi ; Şenkal, B. Filiz ; Sezer, Esma</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c439t-66211f0549cd2e8691cdc8dc07e545f1a9e3898b5881dcfb1dbb4bc3de9ab0ec3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><topic>Ammonium persulfate</topic><topic>Applied sciences</topic><topic>Exact sciences and technology</topic><topic>Ionic liquid</topic><topic>Organo-soluble polyaniline</topic><topic>Oxidative polymerization</topic><topic>Physicochemistry of polymers</topic><topic>Polymerization</topic><topic>Polymers and radiations</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bıçak, Niyazi</creatorcontrib><creatorcontrib>Şenkal, B. Filiz</creatorcontrib><creatorcontrib>Sezer, Esma</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Synthetic metals</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bıçak, Niyazi</au><au>Şenkal, B. Filiz</au><au>Sezer, Esma</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparation of organo-soluble polyanilines in ionic liquid</atitle><jtitle>Synthetic metals</jtitle><date>2005-10-15</date><risdate>2005</risdate><volume>155</volume><issue>1</issue><spage>105</spage><epage>109</epage><pages>105-109</pages><issn>0379-6779</issn><eissn>1879-3290</eissn><coden>SYMEDZ</coden><abstract>A method for preparation of organo-soluble polyaniline (PANI) is described. Oxidative coupling polymerization of anilium chloride with ammonium persulfate in a new ionic liquid, 2-hydroxyethyl ammonium formate (HAF), gives organo-soluble polyaniline with appreciable molecular weights (
M
w
=
86,400). Interestingly polyaniline (PANI) prepared by this method is highly soluble in many organic solvents such as acetone, tetrahydrofurane, dioxane, dimethyformamide and
N-methyl, 2-pyrrolidinone. Thin films of PANI prepared at 0
°C (by solvent casting) show reasonable conductivities (up to 37.0
S
cm
−1) when doped with
p-toluene sulfonic acid.</abstract><cop>Lausanne</cop><cop>Amsterdam</cop><cop>New York, NY</cop><pub>Elsevier B.V</pub><doi>10.1016/j.synthmet.2005.06.010</doi><tpages>5</tpages></addata></record> |
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| language | eng |
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| subjects | Ammonium persulfate Applied sciences Exact sciences and technology Ionic liquid Organo-soluble polyaniline Oxidative polymerization Physicochemistry of polymers Polymerization Polymers and radiations |
| title | Preparation of organo-soluble polyanilines in ionic liquid |
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