Ceramic-Polymer Electrolytes for All-Solid-State Lithium Rechargeable Batteries

Ceramic-Polymer Electrolytes for All-Solid-State Lithium Rechargeable Batteries

New polyurethane acrylate (PUA)-based nanoceramic-polymer electrolytes in a high ceramic filler content were examined in all-solid-state lithium-polymer cells (Li/PUA-SiO2/Li0.33MnO2) and at 60DGC. The composite electrolyte containing more than 20 wt % hydrophilic nano-SiO2 enhanced its mechanical s...

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Veröffentlicht in:Journal of the Electrochemical Society 2005, Vol.152 (4), p.A767-A773
Hauptverfasser: Jiang, Guoxin, Maeda, Seiji, Saito, Yoichiro, Tanase, Shigeo, Sakai, Tetsuo
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container_end_page A773
container_issue 4
container_start_page A767
container_title Journal of the Electrochemical Society
container_volume 152
creator Jiang, Guoxin
Maeda, Seiji
Saito, Yoichiro
Tanase, Shigeo
Sakai, Tetsuo
description New polyurethane acrylate (PUA)-based nanoceramic-polymer electrolytes in a high ceramic filler content were examined in all-solid-state lithium-polymer cells (Li/PUA-SiO2/Li0.33MnO2) and at 60DGC. The composite electrolyte containing more than 20 wt % hydrophilic nano-SiO2 enhanced its mechanical strength 600% compared to the ceramic-free electrolyte. The additions of nano-SiO2 powders in a high concentration protected the electrode surfaces, improved greatly the interfacial stability between composite cathode and the electrolyte, and gave rise to a further reversible lithium stripping-deposition process. The cells showed good rate capacity and excellent cyclability. The discharge capacity kept 65% of initial capacity after 300 cycles with a coulombic efficiency approaching 100%. Capacity fading upon cycling was believed to be due to the increase of cell resistance during charge-discharge cycling. The cell self-charge loss at 60DGC was extremely low about 0.05% per day.
doi_str_mv 10.1149/1.1865892
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title Ceramic-Polymer Electrolytes for All-Solid-State Lithium Rechargeable Batteries
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