Surface oxidation of electromagnetically levitated molten silicon under a condition of oxygen-supersaturation

Surface oxidation of a molten silicon droplet levitated under undercooled and oxygen-supersaturated conditions was observed. After the melt surface was covered with a SiO 2 film, temperature fluctuation took place; this mainly corresponds to two competing phenomena, i.e. the exothermic reaction of S...

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Veröffentlicht in:Scripta materialia 2006-02, Vol.54 (4), p.695-699
Hauptverfasser: Hibiya, Taketoshi, Hokama, Satoshi, Koike, Yusuke, Rinno, Masaki, Kawamura, Hiroshi, Fukuyama, Hiroyuki, Higuchi, Kensuke, Watanabe, Masahito
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Sprache:eng
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Zusammenfassung:Surface oxidation of a molten silicon droplet levitated under undercooled and oxygen-supersaturated conditions was observed. After the melt surface was covered with a SiO 2 film, temperature fluctuation took place; this mainly corresponds to two competing phenomena, i.e. the exothermic reaction of SiO 2 formation and the endothermic reaction of SiO evaporation, which enhances the undercooling.
ISSN:1359-6462
1872-8456
DOI:10.1016/j.scriptamat.2005.07.043