Nano-Diamond Synthesis in Strong Magnetic Field

Diamond is one of the five known allotropes of carbon. Diamonds are important due to their esthetic beauty and excellently remarkable properties. Single crystalline diamond has been synthesized by catalytic processes under high temperature and high pressure. Polycrystalline diamond has been prepared by various activated hot filament and plasma chemical vapor deposition methods. Industrial synthesis of diamonds has been limited by the extreme synthetic conditions, purity, crystallinity, size and high cost. Synthetic advancement for future industrial production will require better understanding and exploitation of the mechanism of formation. Current mechanistic uncertainty arises out of limited consideration of atomic scale dynamics. A new comprehensive model by Little addresses atomic scale electronic processes with nonclassical significance of the intermediary states. This new nonclassical, electronic mechanistic perspective identifies the creation, stabilization and condensation of carbon and metal intermediates for pathways from carbon precursors thru solvated carbon and carbides to sp3 carbon condensation as diamond. In order to test these mechanistic ideas and exploit the impact for better diamond synthesis, catalytic carbon condensation has been explored in strong magnetic field in an effort to influence various radicals and high spin metal and carbon intermediates along the pathway for more efficient diamond condensation. In this effort, static magnetic fields in excess of 15 T are observed to direct these carbon and metal intermediary microstates to promote nano-diamond nucleation and growth at atmospheric pressure and temperature of 900°C. The observed nano-diamond formation is consistent with the predicted faster kinetics due to lower potential energies of intermediates along pathways to diamond. The predicted stability of nano-diamond relative to nano-graphite also accounts for the observed nano-diamond in this work. This novel use of static magnetic field for diamond synthesis is compared with advancements since the first synthetics bulk diamond formation by scientists at both ASEA (Sweden) and GE Research Laboratory, Schenectady, NY, 50 years ago. On the basis of this predicted, invented, and intrinsic magnetic influence on the dynamics of carbon condensation and the promise for faster, feasible single crystal diamond formation, this discovery of the use of strong magnetic field for diamond production is asserted a major advancement during this