Time-, space- and energy-resolved in situ characterization of catalysts by X-ray absorption spectroscopy

A setup for dispersive X-ray absorption spectroscopy (XAS) with spatial, temporal and energy resolution is presented. Through investigation of a Mo/HZSM-5 catalyst during the dehydroaromatization of methane we observed a reduction gradient along the packed bed. Our new method represents an unprecede...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2023-10, Vol.59 (81), p.12120-12123
Hauptverfasser: Peters, Stefan, Kunkel, Benny, Cakir, Cafer Tufan, Kabelitz, Anke, Witte, Steffen, Bernstein, Thomas, Bartling, Stephan, Radtke, Martin, Emmerling, Franziska, Abdel-Mageed, Ali Mohamed, Wohlrab, Sebastian, Guilherme Buzanich, Ana
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container_end_page 12123
container_issue 81
container_start_page 12120
container_title Chemical communications (Cambridge, England)
container_volume 59
creator Peters, Stefan
Kunkel, Benny
Cakir, Cafer Tufan
Kabelitz, Anke
Witte, Steffen
Bernstein, Thomas
Bartling, Stephan
Radtke, Martin
Emmerling, Franziska
Abdel-Mageed, Ali Mohamed
Wohlrab, Sebastian
Guilherme Buzanich, Ana
description A setup for dispersive X-ray absorption spectroscopy (XAS) with spatial, temporal and energy resolution is presented. Through investigation of a Mo/HZSM-5 catalyst during the dehydroaromatization of methane we observed a reduction gradient along the packed bed. Our new method represents an unprecedented addition to the analytical toolbox for characterizations.
doi_str_mv 10.1039/d3cc03277a
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Absorption spectroscopy
Catalysts
Energy resolution
Packed beds
X ray absorption
title Time-, space- and energy-resolved in situ characterization of catalysts by X-ray absorption spectroscopy
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