Restricted chain segment mobility in poly(amide) 6/clay nanocomposites evidenced by quasi-isothermal crystallization
Modulated temperature differential scanning calorimetry is used to explore the interactions between a poly(amide) 6 matrix and various types of clay reinforcement. During quasi-isothermal crystallization of the polymer/clay nanocomposites, an excess contribution is observed in the recorded heat capa...
Gespeichert in:
| Veröffentlicht in: | Polymer (Guilford) 2006-01, Vol.47 (3), p.826-835 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 835 |
|---|---|
| container_issue | 3 |
| container_start_page | 826 |
| container_title | Polymer (Guilford) |
| container_volume | 47 |
| creator | Miltner, Hans E. Assche, Guy Van Pozsgay, András Pukánszky, Béla Mele, Bruno Van |
| description | Modulated temperature differential scanning calorimetry is used to explore the interactions between a poly(amide) 6 matrix and various types of clay reinforcement. During quasi-isothermal crystallization of the polymer/clay nanocomposites, an excess contribution is observed in the recorded heat capacity signal, due to reversible melting and crystallization. It is proposed that the magnitude of this excess contribution can be used to qualify the polymer/clay interfacial interaction, as it is directly linked to the segmental mobility of the polymer chains in the interphase region, where both the crystalline and amorphous polymer fractions are affected. It is shown that the interfacial interaction strongly depends on the type of clay filler used. These interactions play a key role in the development of specific material properties for the different types of nanocomposites. A simple interphase model for the poly(amide) 6/clay nanocomposites is proposed. |
| doi_str_mv | 10.1016/j.polymer.2005.12.014 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_28678245</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S003238610501757X</els_id><sourcerecordid>28678245</sourcerecordid><originalsourceid>FETCH-LOGICAL-c370t-e67f914b794cf7a779d163d1b12dd20409d2e7aee3a489ebf56e84cf4677d7f73</originalsourceid><addsrcrecordid>eNqFkE1r3DAQhkVJoZu0P6GgS0J6sCPJsmWfQgjpBwQKpT2LsTRutMjWRtIG3F9fbXchx54GZp55h3kI-chZzRnvbrb1Lvh1xlgLxtqai5px-YZseK-aSoiBn5ENY42omr7j78h5SlvGmGiF3JD8A1OOzmS01DyBW2jC3zMumc5hdN7llZbeIf8aZmfxE-1ujIeVLrAEE-ZdSC5jovhShospKeNKn_eQXOVSyE8YZ_DUxDVl8N79gezC8p68ncAn_HCqF-TX54ef91-rx-9fvt3fPVamUSxX2Klp4HJUgzSTAqUGy7vG8pELawWTbLACFSA2IPsBx6ntsC-o7JSyalLNBbk65u5ieN6XR_XskkHvYcGwT1r0neqFbAvYHkETQ0oRJ72Lboa4as70wbHe6pNjfXCsudDFcdm7PB2AZMBPERbj0uuykqxn8sDdHjks3764kpKM-6fLRTRZ2-D-c-kv7PaYOQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>28678245</pqid></control><display><type>article</type><title>Restricted chain segment mobility in poly(amide) 6/clay nanocomposites evidenced by quasi-isothermal crystallization</title><source>Elsevier ScienceDirect Journals</source><creator>Miltner, Hans E. ; Assche, Guy Van ; Pozsgay, András ; Pukánszky, Béla ; Mele, Bruno Van</creator><creatorcontrib>Miltner, Hans E. ; Assche, Guy Van ; Pozsgay, András ; Pukánszky, Béla ; Mele, Bruno Van</creatorcontrib><description>Modulated temperature differential scanning calorimetry is used to explore the interactions between a poly(amide) 6 matrix and various types of clay reinforcement. During quasi-isothermal crystallization of the polymer/clay nanocomposites, an excess contribution is observed in the recorded heat capacity signal, due to reversible melting and crystallization. It is proposed that the magnitude of this excess contribution can be used to qualify the polymer/clay interfacial interaction, as it is directly linked to the segmental mobility of the polymer chains in the interphase region, where both the crystalline and amorphous polymer fractions are affected. It is shown that the interfacial interaction strongly depends on the type of clay filler used. These interactions play a key role in the development of specific material properties for the different types of nanocomposites. A simple interphase model for the poly(amide) 6/clay nanocomposites is proposed.</description><identifier>ISSN: 0032-3861</identifier><identifier>EISSN: 1873-2291</identifier><identifier>DOI: 10.1016/j.polymer.2005.12.014</identifier><identifier>CODEN: POLMAG</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>Applied sciences ; Composites ; Exact sciences and technology ; Forms of application and semi-finished materials ; Interphase ; Modulated temperature differential scanning calorimetry ; Polymer industry, paints, wood ; Polymer/clay nanocomposites ; Technology of polymers</subject><ispartof>Polymer (Guilford), 2006-01, Vol.47 (3), p.826-835</ispartof><rights>2005 Elsevier Ltd</rights><rights>2006 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c370t-e67f914b794cf7a779d163d1b12dd20409d2e7aee3a489ebf56e84cf4677d7f73</citedby><cites>FETCH-LOGICAL-c370t-e67f914b794cf7a779d163d1b12dd20409d2e7aee3a489ebf56e84cf4677d7f73</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S003238610501757X$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=17408044$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Miltner, Hans E.</creatorcontrib><creatorcontrib>Assche, Guy Van</creatorcontrib><creatorcontrib>Pozsgay, András</creatorcontrib><creatorcontrib>Pukánszky, Béla</creatorcontrib><creatorcontrib>Mele, Bruno Van</creatorcontrib><title>Restricted chain segment mobility in poly(amide) 6/clay nanocomposites evidenced by quasi-isothermal crystallization</title><title>Polymer (Guilford)</title><description>Modulated temperature differential scanning calorimetry is used to explore the interactions between a poly(amide) 6 matrix and various types of clay reinforcement. During quasi-isothermal crystallization of the polymer/clay nanocomposites, an excess contribution is observed in the recorded heat capacity signal, due to reversible melting and crystallization. It is proposed that the magnitude of this excess contribution can be used to qualify the polymer/clay interfacial interaction, as it is directly linked to the segmental mobility of the polymer chains in the interphase region, where both the crystalline and amorphous polymer fractions are affected. It is shown that the interfacial interaction strongly depends on the type of clay filler used. These interactions play a key role in the development of specific material properties for the different types of nanocomposites. A simple interphase model for the poly(amide) 6/clay nanocomposites is proposed.</description><subject>Applied sciences</subject><subject>Composites</subject><subject>Exact sciences and technology</subject><subject>Forms of application and semi-finished materials</subject><subject>Interphase</subject><subject>Modulated temperature differential scanning calorimetry</subject><subject>Polymer industry, paints, wood</subject><subject>Polymer/clay nanocomposites</subject><subject>Technology of polymers</subject><issn>0032-3861</issn><issn>1873-2291</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><recordid>eNqFkE1r3DAQhkVJoZu0P6GgS0J6sCPJsmWfQgjpBwQKpT2LsTRutMjWRtIG3F9fbXchx54GZp55h3kI-chZzRnvbrb1Lvh1xlgLxtqai5px-YZseK-aSoiBn5ENY42omr7j78h5SlvGmGiF3JD8A1OOzmS01DyBW2jC3zMumc5hdN7llZbeIf8aZmfxE-1ujIeVLrAEE-ZdSC5jovhShospKeNKn_eQXOVSyE8YZ_DUxDVl8N79gezC8p68ncAn_HCqF-TX54ef91-rx-9fvt3fPVamUSxX2Klp4HJUgzSTAqUGy7vG8pELawWTbLACFSA2IPsBx6ntsC-o7JSyalLNBbk65u5ieN6XR_XskkHvYcGwT1r0neqFbAvYHkETQ0oRJ72Lboa4as70wbHe6pNjfXCsudDFcdm7PB2AZMBPERbj0uuykqxn8sDdHjks3764kpKM-6fLRTRZ2-D-c-kv7PaYOQ</recordid><startdate>20060125</startdate><enddate>20060125</enddate><creator>Miltner, Hans E.</creator><creator>Assche, Guy Van</creator><creator>Pozsgay, András</creator><creator>Pukánszky, Béla</creator><creator>Mele, Bruno Van</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>JG9</scope></search><sort><creationdate>20060125</creationdate><title>Restricted chain segment mobility in poly(amide) 6/clay nanocomposites evidenced by quasi-isothermal crystallization</title><author>Miltner, Hans E. ; Assche, Guy Van ; Pozsgay, András ; Pukánszky, Béla ; Mele, Bruno Van</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c370t-e67f914b794cf7a779d163d1b12dd20409d2e7aee3a489ebf56e84cf4677d7f73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2006</creationdate><topic>Applied sciences</topic><topic>Composites</topic><topic>Exact sciences and technology</topic><topic>Forms of application and semi-finished materials</topic><topic>Interphase</topic><topic>Modulated temperature differential scanning calorimetry</topic><topic>Polymer industry, paints, wood</topic><topic>Polymer/clay nanocomposites</topic><topic>Technology of polymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Miltner, Hans E.</creatorcontrib><creatorcontrib>Assche, Guy Van</creatorcontrib><creatorcontrib>Pozsgay, András</creatorcontrib><creatorcontrib>Pukánszky, Béla</creatorcontrib><creatorcontrib>Mele, Bruno Van</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymer (Guilford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Miltner, Hans E.</au><au>Assche, Guy Van</au><au>Pozsgay, András</au><au>Pukánszky, Béla</au><au>Mele, Bruno Van</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Restricted chain segment mobility in poly(amide) 6/clay nanocomposites evidenced by quasi-isothermal crystallization</atitle><jtitle>Polymer (Guilford)</jtitle><date>2006-01-25</date><risdate>2006</risdate><volume>47</volume><issue>3</issue><spage>826</spage><epage>835</epage><pages>826-835</pages><issn>0032-3861</issn><eissn>1873-2291</eissn><coden>POLMAG</coden><abstract>Modulated temperature differential scanning calorimetry is used to explore the interactions between a poly(amide) 6 matrix and various types of clay reinforcement. During quasi-isothermal crystallization of the polymer/clay nanocomposites, an excess contribution is observed in the recorded heat capacity signal, due to reversible melting and crystallization. It is proposed that the magnitude of this excess contribution can be used to qualify the polymer/clay interfacial interaction, as it is directly linked to the segmental mobility of the polymer chains in the interphase region, where both the crystalline and amorphous polymer fractions are affected. It is shown that the interfacial interaction strongly depends on the type of clay filler used. These interactions play a key role in the development of specific material properties for the different types of nanocomposites. A simple interphase model for the poly(amide) 6/clay nanocomposites is proposed.</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.polymer.2005.12.014</doi><tpages>10</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0032-3861 |
| ispartof | Polymer (Guilford), 2006-01, Vol.47 (3), p.826-835 |
| issn | 0032-3861 1873-2291 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_28678245 |
| source | Elsevier ScienceDirect Journals |
| subjects | Applied sciences Composites Exact sciences and technology Forms of application and semi-finished materials Interphase Modulated temperature differential scanning calorimetry Polymer industry, paints, wood Polymer/clay nanocomposites Technology of polymers |
| title | Restricted chain segment mobility in poly(amide) 6/clay nanocomposites evidenced by quasi-isothermal crystallization |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-07T19%3A54%3A16IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Restricted%20chain%20segment%20mobility%20in%20poly(amide)%206/clay%20nanocomposites%20evidenced%20by%20quasi-isothermal%20crystallization&rft.jtitle=Polymer%20(Guilford)&rft.au=Miltner,%20Hans%20E.&rft.date=2006-01-25&rft.volume=47&rft.issue=3&rft.spage=826&rft.epage=835&rft.pages=826-835&rft.issn=0032-3861&rft.eissn=1873-2291&rft.coden=POLMAG&rft_id=info:doi/10.1016/j.polymer.2005.12.014&rft_dat=%3Cproquest_cross%3E28678245%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=28678245&rft_id=info:pmid/&rft_els_id=S003238610501757X&rfr_iscdi=true |