A study on corrosion characterization of plasma oxidized 65/35 brass with various frequencies

Brasses are the most widely used copper-based alloys because of the good corrosion resistance, formability, high strength and excellent hot-working properties. However, dezincification occurs when one or more components of an alloy are more susceptible to corrosion than the rest and, as a result, ar...

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Veröffentlicht in:Surface & coatings technology 2005-10, Vol.200 (1-4), p.77-82
Hauptverfasser: Park, Chang-Gyu, Kim, Jung-Gu, Chung, Yun-Mo, Han, Jeon-Geon, Ahn, Seung-Ho, Lee, Chang-Hee
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container_end_page 82
container_issue 1-4
container_start_page 77
container_title Surface & coatings technology
container_volume 200
creator Park, Chang-Gyu
Kim, Jung-Gu
Chung, Yun-Mo
Han, Jeon-Geon
Ahn, Seung-Ho
Lee, Chang-Hee
description Brasses are the most widely used copper-based alloys because of the good corrosion resistance, formability, high strength and excellent hot-working properties. However, dezincification occurs when one or more components of an alloy are more susceptible to corrosion than the rest and, as a result, are preferentially dissolved. In order to enhance the corrosion resistance, the brasses were exposed to pulsed DC oxygen plasma with various frequencies. The corrosion behavior of plasma oxidized brasses (POBs) with various pulse frequencies was investigated by electrochemical methods (potentiodynamic polarization test, electrochemical impedance spectroscopy) and surface analyses (X-ray diffraction, scanning electron microscopy). Particular attention was paid to the effects of pulse frequency on the corrosion properties of POBs. From the results of electrochemical test, it was found that the oxidized brass under the condition of 1.5 Torr oxygen pressure and 20 kHz frequency was effective in improving corrosion resistance. This was attributed to the protective oxidized layer (ZnO).
doi_str_mv 10.1016/j.surfcoat.2005.02.152
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However, dezincification occurs when one or more components of an alloy are more susceptible to corrosion than the rest and, as a result, are preferentially dissolved. In order to enhance the corrosion resistance, the brasses were exposed to pulsed DC oxygen plasma with various frequencies. The corrosion behavior of plasma oxidized brasses (POBs) with various pulse frequencies was investigated by electrochemical methods (potentiodynamic polarization test, electrochemical impedance spectroscopy) and surface analyses (X-ray diffraction, scanning electron microscopy). Particular attention was paid to the effects of pulse frequency on the corrosion properties of POBs. From the results of electrochemical test, it was found that the oxidized brass under the condition of 1.5 Torr oxygen pressure and 20 kHz frequency was effective in improving corrosion resistance. 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source Elsevier ScienceDirect Journals Complete
subjects Applied sciences
Corrosion
Corrosion environments
Corrosion test
Cross-disciplinary physics: materials science
rheology
Dezincification
EIS
Exact sciences and technology
Materials science
Metals. Metallurgy
Other topics in materials science
Physics
Plasma oxidized brass
Production techniques
SEM
Surface treatment
XRD
title A study on corrosion characterization of plasma oxidized 65/35 brass with various frequencies
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