Thiacalix[4]arene-protected alkynyl Agn (n = 9, 18) nanoclusters: syntheses, structural characterizations, photocurrent responses and fluorescence properties
Two thiacalix[4]arene-protected silver(i) alkynyl nanoclusters, [Na2(H2O)2][Ag9(TC4A)(tBuC≡C)4(CH3OH)2(SbF6)0.5(OH)2.5]·3.5H2O·CH3OH (1, abbreviated as Ag9) and [Ag9(TC4A)(tBuC≡C)4(CF3COO)]2·4CH3OH (2, abbreviated as Ag18), were synthesized by the reaction of [tBuC≡CAg]n, p-tert-butylthiacalix[4]are...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2023-09, Vol.52 (37), p.13405-13412 |
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| container_title | Dalton transactions : an international journal of inorganic chemistry |
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| creator | Wen-Xuan Xie Chun-Hui, Xue Liu, Meng Zhou, Kun Hui-Hao, Gu Jiu-Yu Ji Bao-Kuan, Chen Liu, Na Yan-Feng, Bi |
| description | Two thiacalix[4]arene-protected silver(i) alkynyl nanoclusters, [Na2(H2O)2][Ag9(TC4A)(tBuC≡C)4(CH3OH)2(SbF6)0.5(OH)2.5]·3.5H2O·CH3OH (1, abbreviated as Ag9) and [Ag9(TC4A)(tBuC≡C)4(CF3COO)]2·4CH3OH (2, abbreviated as Ag18), were synthesized by the reaction of [tBuC≡CAg]n, p-tert-butylthiacalix[4]arene (H4TC4A), NaBH4, and AgSbF6 or CF3COOAg in the mixed solvent of methanol-trichloromethane-toluene under solvothermal conditions, respectively. Driven by SbF6− and CF3COO− with different coordination properties, the structural unit [Ag9(TC4A)(tBuC≡C)4]+ in both the compounds migrated in different modes, accompanied by distinct Ag⋯Ag distances. Ag9 and Ag18 exhibit similar UV-Vis absorption and diffuse reflection spectra along with contrary tendency between photocurrent responses and solid-state fluorescence. The solution stability of Ag9 and Ag18 was demonstrated by 1H NMR and MALDI-TOF mass spectrometry. The fluorescence responses of Ag9 and Ag18 towards different organic molecules were also investigated, which indicated that the polarity of solvent has a certain effect on the emission intensities of Ag9 and Ag18. This study provides a positive guide for the controlled synthesis and further study of the structure–activity relationship of thiacalix[4]arene-protected silver alkynyl nanoclusters. |
| doi_str_mv | 10.1039/d3dt02285d |
| format | Article |
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Driven by SbF6− and CF3COO− with different coordination properties, the structural unit [Ag9(TC4A)(tBuC≡C)4]+ in both the compounds migrated in different modes, accompanied by distinct Ag⋯Ag distances. Ag9 and Ag18 exhibit similar UV-Vis absorption and diffuse reflection spectra along with contrary tendency between photocurrent responses and solid-state fluorescence. The solution stability of Ag9 and Ag18 was demonstrated by 1H NMR and MALDI-TOF mass spectrometry. The fluorescence responses of Ag9 and Ag18 towards different organic molecules were also investigated, which indicated that the polarity of solvent has a certain effect on the emission intensities of Ag9 and Ag18. This study provides a positive guide for the controlled synthesis and further study of the structure–activity relationship of thiacalix[4]arene-protected silver alkynyl nanoclusters.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/d3dt02285d</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Chemical synthesis ; Chloroform ; Emission analysis ; Fluorescence ; Mass spectrometry ; Nanoclusters ; NMR ; Nuclear magnetic resonance ; Organic chemistry ; Photoelectric effect ; Photoelectric emission ; Silver ; Solvents ; Toluene</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2023-09, Vol.52 (37), p.13405-13412</ispartof><rights>Copyright Royal Society of Chemistry 2023</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Wen-Xuan Xie</creatorcontrib><creatorcontrib>Chun-Hui, Xue</creatorcontrib><creatorcontrib>Liu, Meng</creatorcontrib><creatorcontrib>Zhou, Kun</creatorcontrib><creatorcontrib>Hui-Hao, Gu</creatorcontrib><creatorcontrib>Jiu-Yu Ji</creatorcontrib><creatorcontrib>Bao-Kuan, Chen</creatorcontrib><creatorcontrib>Liu, Na</creatorcontrib><creatorcontrib>Yan-Feng, Bi</creatorcontrib><title>Thiacalix[4]arene-protected alkynyl Agn (n = 9, 18) nanoclusters: syntheses, structural characterizations, photocurrent responses and fluorescence properties</title><title>Dalton transactions : an international journal of inorganic chemistry</title><description>Two thiacalix[4]arene-protected silver(i) alkynyl nanoclusters, [Na2(H2O)2][Ag9(TC4A)(tBuC≡C)4(CH3OH)2(SbF6)0.5(OH)2.5]·3.5H2O·CH3OH (1, abbreviated as Ag9) and [Ag9(TC4A)(tBuC≡C)4(CF3COO)]2·4CH3OH (2, abbreviated as Ag18), were synthesized by the reaction of [tBuC≡CAg]n, p-tert-butylthiacalix[4]arene (H4TC4A), NaBH4, and AgSbF6 or CF3COOAg in the mixed solvent of methanol-trichloromethane-toluene under solvothermal conditions, respectively. Driven by SbF6− and CF3COO− with different coordination properties, the structural unit [Ag9(TC4A)(tBuC≡C)4]+ in both the compounds migrated in different modes, accompanied by distinct Ag⋯Ag distances. Ag9 and Ag18 exhibit similar UV-Vis absorption and diffuse reflection spectra along with contrary tendency between photocurrent responses and solid-state fluorescence. The solution stability of Ag9 and Ag18 was demonstrated by 1H NMR and MALDI-TOF mass spectrometry. The fluorescence responses of Ag9 and Ag18 towards different organic molecules were also investigated, which indicated that the polarity of solvent has a certain effect on the emission intensities of Ag9 and Ag18. This study provides a positive guide for the controlled synthesis and further study of the structure–activity relationship of thiacalix[4]arene-protected silver alkynyl nanoclusters.</description><subject>Chemical synthesis</subject><subject>Chloroform</subject><subject>Emission analysis</subject><subject>Fluorescence</subject><subject>Mass spectrometry</subject><subject>Nanoclusters</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Organic chemistry</subject><subject>Photoelectric effect</subject><subject>Photoelectric emission</subject><subject>Silver</subject><subject>Solvents</subject><subject>Toluene</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNpdjs1KAzEUhQdRsFY3PkHAjUJHk8xMJhFclOIfFNx0J1LuJLd2asyMSQas7-K7GlFcuLqXcz7OOVl2zOg5o4W6MIWJlHNZmZ1sxMq6zhUvyt2_n4v97CCEDU0Qrfgo-1ysW9Bg2_fH8gk8Osx730XUEQ0B-7J1W0umz46cOnJF1IQweUYcuE7bIUT04ZKErYtrDBgmJEQ_6Dh4sESvwUNK8e0HxLZzye3XXez04FNLJB5Dn1QMBJwhKzt0SdHoNJI0oEcfWwyH2d4KbMCj3zvOFjfXi9ldPn-4vZ9N53nPmYi5VrI2tShW0tCmLKmU1KAooKFMAKsrbBpelkxVQhmx0gC0EpqDpExyXqtinJ3-xKbmtwFDXL62aYu14LAbwpJLUdSiUqJO6Mk_dNMN3qVx35SsSk6VKr4A2vB6xg</recordid><startdate>20230926</startdate><enddate>20230926</enddate><creator>Wen-Xuan Xie</creator><creator>Chun-Hui, Xue</creator><creator>Liu, Meng</creator><creator>Zhou, Kun</creator><creator>Hui-Hao, Gu</creator><creator>Jiu-Yu Ji</creator><creator>Bao-Kuan, Chen</creator><creator>Liu, Na</creator><creator>Yan-Feng, Bi</creator><general>Royal Society of Chemistry</general><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope></search><sort><creationdate>20230926</creationdate><title>Thiacalix[4]arene-protected alkynyl Agn (n = 9, 18) nanoclusters: syntheses, structural characterizations, photocurrent responses and fluorescence properties</title><author>Wen-Xuan Xie ; Chun-Hui, Xue ; Liu, Meng ; Zhou, Kun ; Hui-Hao, Gu ; Jiu-Yu Ji ; Bao-Kuan, Chen ; Liu, Na ; Yan-Feng, Bi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p216t-c987d763f8d0b440880de63ab016a175ebb24419569d6fcaa056c2a801822793</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Chemical synthesis</topic><topic>Chloroform</topic><topic>Emission analysis</topic><topic>Fluorescence</topic><topic>Mass spectrometry</topic><topic>Nanoclusters</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Organic chemistry</topic><topic>Photoelectric effect</topic><topic>Photoelectric emission</topic><topic>Silver</topic><topic>Solvents</topic><topic>Toluene</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wen-Xuan Xie</creatorcontrib><creatorcontrib>Chun-Hui, Xue</creatorcontrib><creatorcontrib>Liu, Meng</creatorcontrib><creatorcontrib>Zhou, Kun</creatorcontrib><creatorcontrib>Hui-Hao, Gu</creatorcontrib><creatorcontrib>Jiu-Yu Ji</creatorcontrib><creatorcontrib>Bao-Kuan, Chen</creatorcontrib><creatorcontrib>Liu, Na</creatorcontrib><creatorcontrib>Yan-Feng, Bi</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wen-Xuan Xie</au><au>Chun-Hui, Xue</au><au>Liu, Meng</au><au>Zhou, Kun</au><au>Hui-Hao, Gu</au><au>Jiu-Yu Ji</au><au>Bao-Kuan, Chen</au><au>Liu, Na</au><au>Yan-Feng, Bi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thiacalix[4]arene-protected alkynyl Agn (n = 9, 18) nanoclusters: syntheses, structural characterizations, photocurrent responses and fluorescence properties</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><date>2023-09-26</date><risdate>2023</risdate><volume>52</volume><issue>37</issue><spage>13405</spage><epage>13412</epage><pages>13405-13412</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>Two thiacalix[4]arene-protected silver(i) alkynyl nanoclusters, [Na2(H2O)2][Ag9(TC4A)(tBuC≡C)4(CH3OH)2(SbF6)0.5(OH)2.5]·3.5H2O·CH3OH (1, abbreviated as Ag9) and [Ag9(TC4A)(tBuC≡C)4(CF3COO)]2·4CH3OH (2, abbreviated as Ag18), were synthesized by the reaction of [tBuC≡CAg]n, p-tert-butylthiacalix[4]arene (H4TC4A), NaBH4, and AgSbF6 or CF3COOAg in the mixed solvent of methanol-trichloromethane-toluene under solvothermal conditions, respectively. Driven by SbF6− and CF3COO− with different coordination properties, the structural unit [Ag9(TC4A)(tBuC≡C)4]+ in both the compounds migrated in different modes, accompanied by distinct Ag⋯Ag distances. Ag9 and Ag18 exhibit similar UV-Vis absorption and diffuse reflection spectra along with contrary tendency between photocurrent responses and solid-state fluorescence. The solution stability of Ag9 and Ag18 was demonstrated by 1H NMR and MALDI-TOF mass spectrometry. The fluorescence responses of Ag9 and Ag18 towards different organic molecules were also investigated, which indicated that the polarity of solvent has a certain effect on the emission intensities of Ag9 and Ag18. This study provides a positive guide for the controlled synthesis and further study of the structure–activity relationship of thiacalix[4]arene-protected silver alkynyl nanoclusters.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d3dt02285d</doi><tpages>8</tpages></addata></record> |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Chemical synthesis Chloroform Emission analysis Fluorescence Mass spectrometry Nanoclusters NMR Nuclear magnetic resonance Organic chemistry Photoelectric effect Photoelectric emission Silver Solvents Toluene |
| title | Thiacalix[4]arene-protected alkynyl Agn (n = 9, 18) nanoclusters: syntheses, structural characterizations, photocurrent responses and fluorescence properties |
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