Preparation of SOFC anode composites by spray pyrolysis
Lowering the SOFC working temperature would also be greatly attractive, but low temperature working SOFCs require high-performance anodes. The cermet SOFC anodes, which are composed of nickel and samarium doped ceria, were prepared by spray pyrolysis (SP), because SP produces spherical particles wit...
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Veröffentlicht in: | Journal of the European Ceramic Society 2006, Vol.26 (4), p.593-597 |
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container_title | Journal of the European Ceramic Society |
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creator | Suda, Seiichi Itagaki, Mikio Node, Eri Takahashi, Seiji Kawano, Mitsunobu Yoshida, Hiroyuki Inagaki, Toru |
description | Lowering the SOFC working temperature would also be greatly attractive, but low temperature working SOFCs require high-performance anodes. The cermet SOFC anodes, which are composed of nickel and samarium doped ceria, were prepared by spray pyrolysis (SP), because SP produces spherical particles with small size distributions. SP-derived particles of NiO, SDC, and NiO/SDC composite had a round shape and comprised nanometer-sized primary grains. The cermet anodes were prepared by using SP-derived NiO/SDC composite particles or mixing SP-derived NiO and SDC particles. The anode prepared with the composite particles showed higher SOFC cell performance than that with the mixed ones. The composite particles had high surface areas and a capsule-type form. The outer shell would be composed of SDC and the inner core was NiO. The capsule-type composite particles would depress aggregation of Ni or NiO during reduction from NiO to Ni metals, and this depression would enhance SOFC anode performance. |
doi_str_mv | 10.1016/j.jeurceramsoc.2005.07.038 |
format | Article |
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The cermet SOFC anodes, which are composed of nickel and samarium doped ceria, were prepared by spray pyrolysis (SP), because SP produces spherical particles with small size distributions. SP-derived particles of NiO, SDC, and NiO/SDC composite had a round shape and comprised nanometer-sized primary grains. The cermet anodes were prepared by using SP-derived NiO/SDC composite particles or mixing SP-derived NiO and SDC particles. The anode prepared with the composite particles showed higher SOFC cell performance than that with the mixed ones. The composite particles had high surface areas and a capsule-type form. The outer shell would be composed of SDC and the inner core was NiO. The capsule-type composite particles would depress aggregation of Ni or NiO during reduction from NiO to Ni metals, and this depression would enhance SOFC anode performance.</description><identifier>ISSN: 0955-2219</identifier><identifier>EISSN: 1873-619X</identifier><identifier>DOI: 10.1016/j.jeurceramsoc.2005.07.038</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>Applied sciences ; Building materials. Ceramics. Glasses ; CeO 2 ; Ceramic industries ; Cermets, ceramic and refractory composites ; Chemical industry and chemicals ; Composites ; Cross-disciplinary physics: materials science; rheology ; Electrical properties ; Electrotechnical and electronic ceramics ; Energy ; Energy. 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The cermet SOFC anodes, which are composed of nickel and samarium doped ceria, were prepared by spray pyrolysis (SP), because SP produces spherical particles with small size distributions. SP-derived particles of NiO, SDC, and NiO/SDC composite had a round shape and comprised nanometer-sized primary grains. The cermet anodes were prepared by using SP-derived NiO/SDC composite particles or mixing SP-derived NiO and SDC particles. The anode prepared with the composite particles showed higher SOFC cell performance than that with the mixed ones. The composite particles had high surface areas and a capsule-type form. The outer shell would be composed of SDC and the inner core was NiO. The capsule-type composite particles would depress aggregation of Ni or NiO during reduction from NiO to Ni metals, and this depression would enhance SOFC anode performance.</description><subject>Applied sciences</subject><subject>Building materials. Ceramics. Glasses</subject><subject>CeO 2</subject><subject>Ceramic industries</subject><subject>Cermets, ceramic and refractory composites</subject><subject>Chemical industry and chemicals</subject><subject>Composites</subject><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>Electrical properties</subject><subject>Electrotechnical and electronic ceramics</subject><subject>Energy</subject><subject>Energy. Thermal use of fuels</subject><subject>Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc</subject><subject>Exact sciences and technology</subject><subject>Fuel cells</subject><subject>Materials science</subject><subject>Other materials</subject><subject>Physics</subject><subject>Powders-chemical preparation</subject><subject>Specific materials</subject><subject>Technical ceramics</subject><issn>0955-2219</issn><issn>1873-619X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><recordid>eNqNkE1LxDAURYMoOI7-hyLorjVp-pG4k9FRYWAEFdyF9PUVMnSamtcR-u_tMIIuXb3NefdyD2OXgieCi-Jmk2xwFwCD3ZKHJOU8T3iZcKmO2EyoUsaF0B_HbMZ1nsdpKvQpOyPacC5KrvWMlS8Bexvs4HwX-SZ6XS8Xke18jRH4be_JDUhRNUbUBztG_Rh8O5Kjc3bS2Jbw4ufO2fvy4W3xFK_Wj8-Lu1UMmU6HuGgyCSIXBSpRiwLSGgTPc2sRNJSZbGSjtAWeVRJ0wRsoVVVJtLWsQChRyDm7PuT2wX_ukAazdQTYtrZDvyOTqiLVOlMTeHsAIXiigI3pg9vaMBrBzd6V2Zi_rszeleGlmVxNz1c_LZbAtk2wHTj6TShzpbnKJu7-wOE0-cthMAQOO8DaBYTB1N79p-4brRmHIA</recordid><startdate>2006</startdate><enddate>2006</enddate><creator>Suda, Seiichi</creator><creator>Itagaki, Mikio</creator><creator>Node, Eri</creator><creator>Takahashi, Seiji</creator><creator>Kawano, Mitsunobu</creator><creator>Yoshida, Hiroyuki</creator><creator>Inagaki, Toru</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>7SP</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>2006</creationdate><title>Preparation of SOFC anode composites by spray pyrolysis</title><author>Suda, Seiichi ; Itagaki, Mikio ; Node, Eri ; Takahashi, Seiji ; Kawano, Mitsunobu ; Yoshida, Hiroyuki ; Inagaki, Toru</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c492t-6f43c1516e81d16c2dc1055aaec9c743f3f89ac04b3c960fc78bb3ead3bc18163</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2006</creationdate><topic>Applied sciences</topic><topic>Building materials. 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The cermet SOFC anodes, which are composed of nickel and samarium doped ceria, were prepared by spray pyrolysis (SP), because SP produces spherical particles with small size distributions. SP-derived particles of NiO, SDC, and NiO/SDC composite had a round shape and comprised nanometer-sized primary grains. The cermet anodes were prepared by using SP-derived NiO/SDC composite particles or mixing SP-derived NiO and SDC particles. The anode prepared with the composite particles showed higher SOFC cell performance than that with the mixed ones. The composite particles had high surface areas and a capsule-type form. The outer shell would be composed of SDC and the inner core was NiO. The capsule-type composite particles would depress aggregation of Ni or NiO during reduction from NiO to Ni metals, and this depression would enhance SOFC anode performance.</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.jeurceramsoc.2005.07.038</doi><tpages>5</tpages></addata></record> |
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subjects | Applied sciences Building materials. Ceramics. Glasses CeO 2 Ceramic industries Cermets, ceramic and refractory composites Chemical industry and chemicals Composites Cross-disciplinary physics: materials science rheology Electrical properties Electrotechnical and electronic ceramics Energy Energy. Thermal use of fuels Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc Exact sciences and technology Fuel cells Materials science Other materials Physics Powders-chemical preparation Specific materials Technical ceramics |
title | Preparation of SOFC anode composites by spray pyrolysis |
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