A comparative study of photocatalytic activity of Na-Ag ion-exchanged glass-ceramics with metallic Ag, semiconductor AgBr, and hybrid Ag-AgBr nanoparticles
Photocatalytic glass-ceramics doped with metallic Ag, semiconductor AgBr, and hybrid metal-semiconductor Ag-AgBr nanostructures were synthesized via low-temperature Na + -Ag + ion exchange. The spectral features of the nanostructures in the silicate glass matrix as well as their photocatalytic perfo...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2023-09, Vol.52 (36), p.12661-12667 |
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| container_end_page | 12667 |
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| container_issue | 36 |
| container_start_page | 12661 |
| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 52 |
| creator | Sgibnev, Y. M Marasanov, D. V Smetanin, I. V Uskov, A. V Kuzmenko, N. K Ignatiev, A. I Nikonorov, N. V Baryshev, A. V |
| description | Photocatalytic glass-ceramics doped with metallic Ag, semiconductor AgBr, and hybrid metal-semiconductor Ag-AgBr nanostructures were synthesized
via
low-temperature Na
+
-Ag
+
ion exchange. The spectral features of the nanostructures in the silicate glass matrix as well as their photocatalytic performance were studied in detail. Glass-ceramics containing hybrid metal-semiconductor nanostructures were shown to possess one order of magnitude higher photocatalytic activity compared to their counterparts with metallic and semiconductor nanostructures. Hybrid metal-semiconductor nanostructures allow enhancement of the net density of photogenerated hot electrons.
Photocatalytic glass-ceramics with various nanostructures were obtained
via
Na
+
-Ag
+
ion exchange. Glass-ceramics with hybrid metal-semiconductor nanostructures possessed an order of magnitude higher photocatalytic activity. |
| doi_str_mv | 10.1039/d3dt01712e |
| format | Article |
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via
low-temperature Na
+
-Ag
+
ion exchange. The spectral features of the nanostructures in the silicate glass matrix as well as their photocatalytic performance were studied in detail. Glass-ceramics containing hybrid metal-semiconductor nanostructures were shown to possess one order of magnitude higher photocatalytic activity compared to their counterparts with metallic and semiconductor nanostructures. Hybrid metal-semiconductor nanostructures allow enhancement of the net density of photogenerated hot electrons.
Photocatalytic glass-ceramics with various nanostructures were obtained
via
Na
+
-Ag
+
ion exchange. Glass-ceramics with hybrid metal-semiconductor nanostructures possessed an order of magnitude higher photocatalytic activity.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/d3dt01712e</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Catalytic activity ; Comparative studies ; Glass ceramics ; Hot electrons ; Ion exchange ; Low temperature ; Nanoparticles ; Nanostructure ; Photocatalysis ; Silver</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2023-09, Vol.52 (36), p.12661-12667</ispartof><rights>Copyright Royal Society of Chemistry 2023</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c273t-7e39d4ef4ec3c23e785b689b3f15d4c67f0d0732068d9156fd011d285822aa913</cites><orcidid>0000-0001-8480-2016 ; 0000-0002-2840-9479</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>Sgibnev, Y. M</creatorcontrib><creatorcontrib>Marasanov, D. V</creatorcontrib><creatorcontrib>Smetanin, I. V</creatorcontrib><creatorcontrib>Uskov, A. V</creatorcontrib><creatorcontrib>Kuzmenko, N. K</creatorcontrib><creatorcontrib>Ignatiev, A. I</creatorcontrib><creatorcontrib>Nikonorov, N. V</creatorcontrib><creatorcontrib>Baryshev, A. V</creatorcontrib><title>A comparative study of photocatalytic activity of Na-Ag ion-exchanged glass-ceramics with metallic Ag, semiconductor AgBr, and hybrid Ag-AgBr nanoparticles</title><title>Dalton transactions : an international journal of inorganic chemistry</title><description>Photocatalytic glass-ceramics doped with metallic Ag, semiconductor AgBr, and hybrid metal-semiconductor Ag-AgBr nanostructures were synthesized
via
low-temperature Na
+
-Ag
+
ion exchange. The spectral features of the nanostructures in the silicate glass matrix as well as their photocatalytic performance were studied in detail. Glass-ceramics containing hybrid metal-semiconductor nanostructures were shown to possess one order of magnitude higher photocatalytic activity compared to their counterparts with metallic and semiconductor nanostructures. Hybrid metal-semiconductor nanostructures allow enhancement of the net density of photogenerated hot electrons.
Photocatalytic glass-ceramics with various nanostructures were obtained
via
Na
+
-Ag
+
ion exchange. Glass-ceramics with hybrid metal-semiconductor nanostructures possessed an order of magnitude higher photocatalytic activity.</description><subject>Catalytic activity</subject><subject>Comparative studies</subject><subject>Glass ceramics</subject><subject>Hot electrons</subject><subject>Ion exchange</subject><subject>Low temperature</subject><subject>Nanoparticles</subject><subject>Nanostructure</subject><subject>Photocatalysis</subject><subject>Silver</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNpdkUtLAzEUhQdRsFY37oWAG5GO5jGvLGtbH1B0U9dDmtxpU2YmNcmo_S3-WdNWFFzdyznffcCJonOCbwhm_FYx5THJCYWDqEeSPI85Zcnhb0-z4-jEuRXGlOKU9qKvIZKmWQsrvH4H5HynNshUaL003kjhRb3xWiIhg639znoW8XCBtGlj-JRL0S5AoUUtnIslWNFo6dCH9kvUQJiuw_BwMUAOgmFa1UlvbFDu7ACJVqHlZm61CkK81VArWhOeCSdrcKfRUSVqB2c_tR-93k9mo8d4-vLwNBpOY0lz5uMcGFcJVAlIJimDvEjnWcHnrCKpSmSWV1jhnFGcFYqTNKsUJkTRIi0oFYIT1o-u9nvX1rx14HzZaCehrkULpnPlFuVFgTMa0Mt_6Mp0tg3fBSpLOS8I3lLXe0pa45yFqlxb3Qi7KQkutzmVYzae7XKaBPhiD1snf7m_HNk3XhGQIw</recordid><startdate>20230919</startdate><enddate>20230919</enddate><creator>Sgibnev, Y. M</creator><creator>Marasanov, D. V</creator><creator>Smetanin, I. V</creator><creator>Uskov, A. V</creator><creator>Kuzmenko, N. K</creator><creator>Ignatiev, A. I</creator><creator>Nikonorov, N. V</creator><creator>Baryshev, A. V</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-8480-2016</orcidid><orcidid>https://orcid.org/0000-0002-2840-9479</orcidid></search><sort><creationdate>20230919</creationdate><title>A comparative study of photocatalytic activity of Na-Ag ion-exchanged glass-ceramics with metallic Ag, semiconductor AgBr, and hybrid Ag-AgBr nanoparticles</title><author>Sgibnev, Y. M ; Marasanov, D. V ; Smetanin, I. V ; Uskov, A. V ; Kuzmenko, N. K ; Ignatiev, A. I ; Nikonorov, N. V ; Baryshev, A. V</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c273t-7e39d4ef4ec3c23e785b689b3f15d4c67f0d0732068d9156fd011d285822aa913</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Catalytic activity</topic><topic>Comparative studies</topic><topic>Glass ceramics</topic><topic>Hot electrons</topic><topic>Ion exchange</topic><topic>Low temperature</topic><topic>Nanoparticles</topic><topic>Nanostructure</topic><topic>Photocatalysis</topic><topic>Silver</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sgibnev, Y. M</creatorcontrib><creatorcontrib>Marasanov, D. V</creatorcontrib><creatorcontrib>Smetanin, I. V</creatorcontrib><creatorcontrib>Uskov, A. V</creatorcontrib><creatorcontrib>Kuzmenko, N. K</creatorcontrib><creatorcontrib>Ignatiev, A. I</creatorcontrib><creatorcontrib>Nikonorov, N. V</creatorcontrib><creatorcontrib>Baryshev, A. V</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sgibnev, Y. M</au><au>Marasanov, D. V</au><au>Smetanin, I. V</au><au>Uskov, A. V</au><au>Kuzmenko, N. K</au><au>Ignatiev, A. I</au><au>Nikonorov, N. V</au><au>Baryshev, A. V</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A comparative study of photocatalytic activity of Na-Ag ion-exchanged glass-ceramics with metallic Ag, semiconductor AgBr, and hybrid Ag-AgBr nanoparticles</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><date>2023-09-19</date><risdate>2023</risdate><volume>52</volume><issue>36</issue><spage>12661</spage><epage>12667</epage><pages>12661-12667</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>Photocatalytic glass-ceramics doped with metallic Ag, semiconductor AgBr, and hybrid metal-semiconductor Ag-AgBr nanostructures were synthesized
via
low-temperature Na
+
-Ag
+
ion exchange. The spectral features of the nanostructures in the silicate glass matrix as well as their photocatalytic performance were studied in detail. Glass-ceramics containing hybrid metal-semiconductor nanostructures were shown to possess one order of magnitude higher photocatalytic activity compared to their counterparts with metallic and semiconductor nanostructures. Hybrid metal-semiconductor nanostructures allow enhancement of the net density of photogenerated hot electrons.
Photocatalytic glass-ceramics with various nanostructures were obtained
via
Na
+
-Ag
+
ion exchange. Glass-ceramics with hybrid metal-semiconductor nanostructures possessed an order of magnitude higher photocatalytic activity.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d3dt01712e</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0001-8480-2016</orcidid><orcidid>https://orcid.org/0000-0002-2840-9479</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2023-09, Vol.52 (36), p.12661-12667 |
| issn | 1477-9226 1477-9234 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_2858988062 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Catalytic activity Comparative studies Glass ceramics Hot electrons Ion exchange Low temperature Nanoparticles Nanostructure Photocatalysis Silver |
| title | A comparative study of photocatalytic activity of Na-Ag ion-exchanged glass-ceramics with metallic Ag, semiconductor AgBr, and hybrid Ag-AgBr nanoparticles |
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