Enhancement of the anthracene aqueous solubility by a synergistic effect of alcohols and β-cyclodextrin
The results presented in this paper show that the solubility of anthracene in water increases significantly when β-cyclodextrin and alkanols with carbon numbers from 1 to 4 are added to the solution. The concentrations of the anthracene chosen as a model hydrophobic pollutant were determined using U...
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| Veröffentlicht in: | Fluid phase equilibria 2005-11, Vol.238 (1), p.39-44 |
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| creator | Lubomska, Monika Gierycz, Pawel Rogalski, Marek |
| description | The results presented in this paper show that the solubility of anthracene in water increases significantly when β-cyclodextrin and alkanols with carbon numbers from 1 to 4 are added to the solution. The concentrations of the anthracene chosen as a model hydrophobic pollutant were determined using UV–vis spectroscopy. It has been demonstrated that the solubility of anthracene in a 1.1
wt% β-cyclodextrin solution increases by the factor of 45 or 62 when 4
wt% of methanol or ethanol are added, respectively. Obviously, the increase of anthracene solubility is due both to the solvent effect of the alcohols and to the formation of anthracene–β-cyclodextrin (β-CD) “guest–host” complexes. We propose, to use the solubility enhancement based on the β-cyclodextrin/alcohol effect for improving the availability of hydrocarbon pollutants in the biodegradation processes. |
| doi_str_mv | 10.1016/j.fluid.2005.08.023 |
| format | Article |
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wt% β-cyclodextrin solution increases by the factor of 45 or 62 when 4
wt% of methanol or ethanol are added, respectively. Obviously, the increase of anthracene solubility is due both to the solvent effect of the alcohols and to the formation of anthracene–β-cyclodextrin (β-CD) “guest–host” complexes. We propose, to use the solubility enhancement based on the β-cyclodextrin/alcohol effect for improving the availability of hydrocarbon pollutants in the biodegradation processes.</description><identifier>ISSN: 0378-3812</identifier><identifier>EISSN: 1879-0224</identifier><identifier>DOI: 10.1016/j.fluid.2005.08.023</identifier><identifier>CODEN: FPEQDT</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Binary inclusion complexes ; Biological and medical sciences ; Bioremediation ; Biotechnology ; Chemistry ; Environment and pollution ; Exact sciences and technology ; Fundamental and applied biological sciences. Psychology ; General and physical chemistry ; Industrial applications and implications. Economical aspects ; Miscellaneous ; n-Alcohols ; Solubility ; Solutions ; UV–vis spectroscopy</subject><ispartof>Fluid phase equilibria, 2005-11, Vol.238 (1), p.39-44</ispartof><rights>2005 Elsevier B.V.</rights><rights>2006 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c364t-12e4d81d0993bc1606a767b6b8a57737e1ceef64d1e31017ed159e741e0e0c293</citedby><cites>FETCH-LOGICAL-c364t-12e4d81d0993bc1606a767b6b8a57737e1ceef64d1e31017ed159e741e0e0c293</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.fluid.2005.08.023$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3548,27923,27924,45994</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=17255711$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Lubomska, Monika</creatorcontrib><creatorcontrib>Gierycz, Pawel</creatorcontrib><creatorcontrib>Rogalski, Marek</creatorcontrib><title>Enhancement of the anthracene aqueous solubility by a synergistic effect of alcohols and β-cyclodextrin</title><title>Fluid phase equilibria</title><description>The results presented in this paper show that the solubility of anthracene in water increases significantly when β-cyclodextrin and alkanols with carbon numbers from 1 to 4 are added to the solution. The concentrations of the anthracene chosen as a model hydrophobic pollutant were determined using UV–vis spectroscopy. It has been demonstrated that the solubility of anthracene in a 1.1
wt% β-cyclodextrin solution increases by the factor of 45 or 62 when 4
wt% of methanol or ethanol are added, respectively. Obviously, the increase of anthracene solubility is due both to the solvent effect of the alcohols and to the formation of anthracene–β-cyclodextrin (β-CD) “guest–host” complexes. We propose, to use the solubility enhancement based on the β-cyclodextrin/alcohol effect for improving the availability of hydrocarbon pollutants in the biodegradation processes.</description><subject>Binary inclusion complexes</subject><subject>Biological and medical sciences</subject><subject>Bioremediation</subject><subject>Biotechnology</subject><subject>Chemistry</subject><subject>Environment and pollution</subject><subject>Exact sciences and technology</subject><subject>Fundamental and applied biological sciences. Psychology</subject><subject>General and physical chemistry</subject><subject>Industrial applications and implications. Economical aspects</subject><subject>Miscellaneous</subject><subject>n-Alcohols</subject><subject>Solubility</subject><subject>Solutions</subject><subject>UV–vis spectroscopy</subject><issn>0378-3812</issn><issn>1879-0224</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><recordid>eNp9kMFO3DAQhq2qlbqFPgEXX9pb0rGdxM6BA0JAKyH1Us6WY0-IV96Y2tmKvBYPwjPhZZG49TRz-P9_5v8IOWNQM2Ddj209hr13NQdoa1A1cPGBbJiSfQWcNx_JBoRUlVCMfyZfct4CAGs7viHT1TyZ2eIO54XGkS4TUjMvUzIW57L-3WPcZ5pj2A8--GWlw0oNzeuM6d7nxVuK44j21WyCjVMMuSQ4-vxU2dWG6PBxSX4-JZ9GEzJ-fZsn5O766s_lz-r2982vy4vbyoquWSrGsXGKOeh7MVjWQWdkJ4duUKaVUkhkFnHsGsdQlOoSHWt7lA1DQLC8Fyfk-zH3IcXyfF70zmeLIZj50ERz1aqm5VCE4ii0KeaccNQPye9MWjUDfaCqt_qVqj5Q1aB0oVpc397iTbYmjKnA8_ndKnnbSsaK7vyow9L1n8eks_VYQDufCi3tov_vnRd58ZB1</recordid><startdate>20051125</startdate><enddate>20051125</enddate><creator>Lubomska, Monika</creator><creator>Gierycz, Pawel</creator><creator>Rogalski, Marek</creator><general>Elsevier B.V</general><general>Elsevier Science</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>FR3</scope><scope>KR7</scope><scope>L7M</scope></search><sort><creationdate>20051125</creationdate><title>Enhancement of the anthracene aqueous solubility by a synergistic effect of alcohols and β-cyclodextrin</title><author>Lubomska, Monika ; Gierycz, Pawel ; Rogalski, Marek</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c364t-12e4d81d0993bc1606a767b6b8a57737e1ceef64d1e31017ed159e741e0e0c293</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><topic>Binary inclusion complexes</topic><topic>Biological and medical sciences</topic><topic>Bioremediation</topic><topic>Biotechnology</topic><topic>Chemistry</topic><topic>Environment and pollution</topic><topic>Exact sciences and technology</topic><topic>Fundamental and applied biological sciences. Psychology</topic><topic>General and physical chemistry</topic><topic>Industrial applications and implications. Economical aspects</topic><topic>Miscellaneous</topic><topic>n-Alcohols</topic><topic>Solubility</topic><topic>Solutions</topic><topic>UV–vis spectroscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lubomska, Monika</creatorcontrib><creatorcontrib>Gierycz, Pawel</creatorcontrib><creatorcontrib>Rogalski, Marek</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Fluid phase equilibria</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lubomska, Monika</au><au>Gierycz, Pawel</au><au>Rogalski, Marek</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Enhancement of the anthracene aqueous solubility by a synergistic effect of alcohols and β-cyclodextrin</atitle><jtitle>Fluid phase equilibria</jtitle><date>2005-11-25</date><risdate>2005</risdate><volume>238</volume><issue>1</issue><spage>39</spage><epage>44</epage><pages>39-44</pages><issn>0378-3812</issn><eissn>1879-0224</eissn><coden>FPEQDT</coden><abstract>The results presented in this paper show that the solubility of anthracene in water increases significantly when β-cyclodextrin and alkanols with carbon numbers from 1 to 4 are added to the solution. The concentrations of the anthracene chosen as a model hydrophobic pollutant were determined using UV–vis spectroscopy. It has been demonstrated that the solubility of anthracene in a 1.1
wt% β-cyclodextrin solution increases by the factor of 45 or 62 when 4
wt% of methanol or ethanol are added, respectively. Obviously, the increase of anthracene solubility is due both to the solvent effect of the alcohols and to the formation of anthracene–β-cyclodextrin (β-CD) “guest–host” complexes. We propose, to use the solubility enhancement based on the β-cyclodextrin/alcohol effect for improving the availability of hydrocarbon pollutants in the biodegradation processes.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.fluid.2005.08.023</doi><tpages>6</tpages></addata></record> |
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| ispartof | Fluid phase equilibria, 2005-11, Vol.238 (1), p.39-44 |
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| language | eng |
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| source | Elsevier ScienceDirect Journals Complete |
| subjects | Binary inclusion complexes Biological and medical sciences Bioremediation Biotechnology Chemistry Environment and pollution Exact sciences and technology Fundamental and applied biological sciences. Psychology General and physical chemistry Industrial applications and implications. Economical aspects Miscellaneous n-Alcohols Solubility Solutions UV–vis spectroscopy |
| title | Enhancement of the anthracene aqueous solubility by a synergistic effect of alcohols and β-cyclodextrin |
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