Comparative Study between 2‐Furonitrile and 2‐Cyanopyridine as Dehydrants in Direct Synthesis of Dialkyl Carbonates from CO2 and Alcohols over Cerium Oxide Catalyst

The shift of equilibrium by removing water with nitrile dehydrants is crucial for CeO2‐catalyzed synthesis of dialkyl carbonates from CO2 and alcohols. Two nitriles – 2‐cyanopyridine and 2‐furonitrile – were previously found as effective dehydrants, yet their detailed comparison as well as explorati...

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Veröffentlicht in:	ChemSusChem 2023-12, Vol.16 (24), p.e202300768-n/a
Hauptverfasser:	Sun, Wen, Li, Peilang, Yabushita, Mizuho, Nakagawa, Yoshinao, Wang, Yuqi, Nakayama, Akira, Tomishige, Keiichi
Format:	Artikel
Sprache:	eng
Schlagworte:	Alcohol Alcohols Carbon dioxide carbon dioxide fixation Carbonates Catalysts cerium oxide Cerium oxides Chemical synthesis Comparative studies Density functional theory heterogeneous catalysis Nitriles non-reductive CO2 transformation organic carbonate
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