Achiral 2‐pyridone and 4‐aminopyridine act as chiral inducers of asymmetric autocatalysis with amplification of enantiomeric excess via the formation of chiral crystals

Enantiomorphous crystals of achiral 2‐pyridone and 4‐aminopyridine served as sources of chirality, to induce the asymmetric autocatalysis of 5‐pyrimidyl alkanol during the asymmetric addition of diisopropylzinc to the corresponding pyrimidine‐5‐carbaldehyde, that is, the Soai reaction. Following a s...

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Veröffentlicht in:	Chirality (New York, N.Y.) N.Y.), 2024-01, Vol.36 (1), p.e23617-n/a
Hauptverfasser:	Matsumoto, Arimasa, Tateishi, Daisuke, Nakajima, Tsuyoshi, Kurosaki, Shiori, Ogawa, Tomohiro, Kawasaki, Tsuneomi, Soai, Kenso
Format:	Artikel
Sprache:	eng
Schlagworte:	5‐pyrimidyl alkanol aminopyridine amplification of ee asymmetric autocatalysis chiral crystal homochirality origin of chirality pyridone pyrimidine‐5‐carbaldehyde Soai reaction
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