Hydrogen storage performance of Ti–V-based BCC phase alloys with various Fe content

The effect of Fe content on hydrogen storage characteristics of Ti–10Cr–18Mn–(32− x)V– xFe ( x = 0, 2, 3, 4, 5) alloys has been investigated at 353 K. The X-ray diffraction (XRD) patterns and scanning electron microscopy (SEM) images of the alloys present BCC and C14 two-phase structures for all of...

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Veröffentlicht in:Journal of alloys and compounds 2005-05, Vol.393 (1), p.128-134
Hauptverfasser: Yu, X.B., Feng, S.L., Wu, Z., Xia, B.J., Xu, N.X.
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container_end_page 134
container_issue 1
container_start_page 128
container_title Journal of alloys and compounds
container_volume 393
creator Yu, X.B.
Feng, S.L.
Wu, Z.
Xia, B.J.
Xu, N.X.
description The effect of Fe content on hydrogen storage characteristics of Ti–10Cr–18Mn–(32− x)V– xFe ( x = 0, 2, 3, 4, 5) alloys has been investigated at 353 K. The X-ray diffraction (XRD) patterns and scanning electron microscopy (SEM) images of the alloys present BCC and C14 two-phase structures for all of the Fe-containing alloys. With the increasing Fe content, the lattice parameters of the BCC phase decrease, which results in an increase of the hydrogen desorption plateau pressure of the alloys. Among the studied alloys, Ti–10Cr–18Mn–27V–5Fe alloy exhibits the smallest PCT plateau slope and a more suitable plateau pressure (0.1 MPa < P equ
doi_str_mv 10.1016/j.jallcom.2004.09.058
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The X-ray diffraction (XRD) patterns and scanning electron microscopy (SEM) images of the alloys present BCC and C14 two-phase structures for all of the Fe-containing alloys. With the increasing Fe content, the lattice parameters of the BCC phase decrease, which results in an increase of the hydrogen desorption plateau pressure of the alloys. Among the studied alloys, Ti–10Cr–18Mn–27V–5Fe alloy exhibits the smallest PCT plateau slope and a more suitable plateau pressure (0.1 MPa &lt; P equ &lt;1 MPa). The maximum and effective capacities of the alloy are 3.32 wt.% and 2.26 wt.%, respectively, which are higher than other reported Fe-containing BCC phase alloys. 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subjects Exact sciences and technology
Hydrogen storage
Phase structure
Physics
Ti–V-based BCC alloys
title Hydrogen storage performance of Ti–V-based BCC phase alloys with various Fe content
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