Exceptional Microscale Plasticity in Amorphous Aluminum Oxide at Room Temperature

Oxide glasses are an elementary group of materials in modern society, but brittleness limits their wider usability at room temperature. As an exception to the rule, amorphous aluminum oxide (a‐Al2O3) is a rare diatomic glassy material exhibiting significant nanoscale plasticity at room temperature. Here, it is shown experimentally that the room temperature plasticity of a‐Al2O3 extends to the microscale and high strain rates using in situ micropillar compression. All tested a‐Al2O3 micropillars deform without fracture at up to 50% strain via a combined mechanism of viscous creep and shear band slip propagation. Large‐scale molecular dynamics simulations align with the main experimental observations and verify the plasticity mechanism at the atomic scale. The experimental strain rates reach magnitudes typical for impact loading scenarios, such as hammer forging, with strain rates up to the order of 1 000 s−1, and the total a‐Al2O3 sample volume exhibiting significant low‐temperature plasticity without fracture is expanded by 5 orders of magnitude from previous observations. The discovery is consistent with the theoretical prediction that the plasticity observed in a‐Al2O3 can extend to macroscopic bulk scale and suggests that amorphous oxides show significant potential to be used as light, high‐strength, and damage‐tolerant engineering materials. Plasticity in ceramics, including oxide glasses, is difficult to achieve and typically occurs only at high temperatures. Amorphous aluminum oxide (a‐Al2O3) makes an exception to the rule by showing substantial ductility at room temperature. The microscale compression samples (micropillars with 2.25–11 µm diameter) are shown to deform without fracture even under fast impact loading resembling for example hammer forging.