X‑ray Spectroscopic Study of the Electronic Structure of a Trigonal High-Spin Fe(IV)O Complex Modeling Non-Heme Enzyme Intermediates and Their Reactivity

Fe K-edge X-ray absorption spectroscopy (XAS) has long been used for the study of high-valent iron intermediates in biological and artificial catalysts. 4p-mixing into the 3d orbitals complicates the pre-edge analysis but when correctly understood via 1s2p resonant inelastic X-ray scattering and Fe...

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Veröffentlicht in:	Journal of the American Chemical Society 2023-08, Vol.145 (34), p.18977-18991
Hauptverfasser:	Braun, Augustin, Gee, Leland B., Mara, Michael W., Hill, Ethan A., Kroll, Thomas, Nordlund, Dennis, Sokaras, Dimosthenis, Glatzel, Pieter, Hedman, Britt, Hodgson, Keith O., Borovik, A. S., Baker, Michael L., Solomon, Edward I.
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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