Development of CO-resistive catalysts for the one-step amination of dodecyl alcohol to N, N-dimethyldodecylamine, and effect of carbon monoxide on activity of Cu/Ni-based catalysts

Dodecyl aldehyde is the intermediate in the one-step amination of dodecyl alcohol and dimethylamine (HNMe 2) to the corresponding tertiary amine, N, N-dimethyldodecylamine (RNMe 2). Carbon monoxide (CO) generated by the decarbonylation of dodecyl aldehyde, significantly poisons the Cu/Ni-based collo...

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Veröffentlicht in:	Applied catalysis. A, General General, 2005-05, Vol.286 (1), p.120-127
Hauptverfasser:	Kimura, Hiroshi, Ishikawa, Kouzo, Nishino, Kenji, Nomura, Seiji
Format:	Artikel
Sprache:	eng
Schlagworte:	Amination Carbon monoxide Catalysis Catalyst poison Chemistry CO-resistive catalyst Cu/Ni/Ba Exact sciences and technology General and physical chemistry Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
Online-Zugang:	Volltext
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