Kinetics for the Reactions of Ar+, O2 +, and NO+ with Isoprene (2-Methyl-1,3-butadiene) as a Function of Temperature (300–500 K)

Rate constants and product branching fractions were measured for reactions of Ar+, O2 +, and NO+ with isoprene (2-methyl-1,3-butadiene C5H8) as a function of temperature. The rate constants are large (∼2 × 10–9 cm3 s–1) and increase with temperature, exceeding the ion-dipole/induced dipole capture r...

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Veröffentlicht in:The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2023-08, Vol.127 (34), p.7221-7227
Hauptverfasser: Lewis, Tucker W. R., Long, Bryan A., Eyet, Nicole, Shuman, Nicholas S., Ard, Shaun G., Viggiano, Albert A.
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Sprache:eng
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