Densities, isobaric thermal compressibilities and derived thermodynamic properties of the binary systems of cyclohexane with allyl methacrylate, butyl methacrylate, methacrylic acid, and vinyl acetate at t = (298.15 and 308.15) K
Densities of the binary systems of cyclohexane with allyl methacrylate, butyl methacrylate, methacrylic acid, and vinyl acetate have been measured as a function of the composition, at 298.15 and 308.15 K and atmospheric pressure, using an Anton Paar DMA 5000 oscillating U-tube densimeter. The calcul...
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| Veröffentlicht in: | Thermochimica acta 2005-10, Vol.437 (1), p.1-6 |
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| container_title | Thermochimica acta |
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| creator | Wisniak, Jaime Peralta, René D. Infante, Ramiro Cortez, Gladis López, R.G. |
| description | Densities of the binary systems of cyclohexane with allyl methacrylate, butyl methacrylate, methacrylic acid, and vinyl acetate have been measured as a function of the composition, at 298.15 and 308.15
K and atmospheric pressure, using an Anton Paar DMA 5000 oscillating U-tube densimeter. The calculated excess molar volumes were correlated with the Redlich–Kister equation and with a series of Legendre polynomials. The excess molar volumes are positive for the four binaries studied. Within the short temperature range considered here the coefficient of thermal expansion is positive for all the systems studied; it varies only slightly with the nature of the acrylate except for the system cyclohexane
+
vinyl acetate. |
| doi_str_mv | 10.1016/j.tca.2005.06.007 |
| format | Article |
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K and atmospheric pressure, using an Anton Paar DMA 5000 oscillating U-tube densimeter. The calculated excess molar volumes were correlated with the Redlich–Kister equation and with a series of Legendre polynomials. The excess molar volumes are positive for the four binaries studied. Within the short temperature range considered here the coefficient of thermal expansion is positive for all the systems studied; it varies only slightly with the nature of the acrylate except for the system cyclohexane
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K and atmospheric pressure, using an Anton Paar DMA 5000 oscillating U-tube densimeter. The calculated excess molar volumes were correlated with the Redlich–Kister equation and with a series of Legendre polynomials. The excess molar volumes are positive for the four binaries studied. Within the short temperature range considered here the coefficient of thermal expansion is positive for all the systems studied; it varies only slightly with the nature of the acrylate except for the system cyclohexane
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vinyl acetate.</description><subject>Chemical thermodynamics</subject><subject>Chemistry</subject><subject>Cyclohexane</subject><subject>Densities</subject><subject>Exact sciences and technology</subject><subject>Excess molar volumes</subject><subject>General and physical chemistry</subject><subject>Methacrylates</subject><subject>Mixtures</subject><subject>Monomers</subject><subject>Thermodynamic properties</subject><subject>Vinyl acetate</subject><issn>0040-6031</issn><issn>1872-762X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><recordid>eNp9kd2q1DAQx4souB59AO9yoyhs6yTdNlnECzl-4gFvFLwL6WTKZknbNcmu9oF9D7Pdg14IkkAmk9_MZOZfFI85VBx4-2JfJTSVAGgqaCsAeadYcSVFKVvx7W6xAthA2ULN7xcPYtwDABcKVsWvNzRGlxzFNXNx6kxwyNKOwmA8w2k4BIrRdc4vDDOjZZaCO5G9UJOdRzPkmEOYDhQWaOrPb6xzowkzi3NMNCxenNFPO_ppRmI_XNox4_3s2UBpZzDM3iRas-6Y_vH9ueVCBp1dLx85uTGTBilliJnEEnvFnomtqnizADWczefs08PiXm98pEe351Xx9d3bL9cfypvP7z9ev74psW5UKuuuV72FvDem7nmnDBekQCor1AZljZ2lrUApG1HLfgOStp20VKOomxpbW18VTy958zS-HykmPbiI5H3ueDpGLVTDRQMqg_wCYphiDNTrQ3BDHpfmoM-C6r3OguqzoBpanQXNMU9uk5uIxvfBjOji30CZ12bJ_fLCUe705CjoiI5GJOsCYdJ2cv-p8htXM7nG</recordid><startdate>20051015</startdate><enddate>20051015</enddate><creator>Wisniak, Jaime</creator><creator>Peralta, René D.</creator><creator>Infante, Ramiro</creator><creator>Cortez, Gladis</creator><creator>López, R.G.</creator><general>Elsevier B.V</general><general>Elsevier Science</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20051015</creationdate><title>Densities, isobaric thermal compressibilities and derived thermodynamic properties of the binary systems of cyclohexane with allyl methacrylate, butyl methacrylate, methacrylic acid, and vinyl acetate at t = (298.15 and 308.15) K</title><author>Wisniak, Jaime ; Peralta, René D. ; Infante, Ramiro ; Cortez, Gladis ; López, R.G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c358t-3bf8fd0fd04a3f1b8a12e8078d284c73cbde92c775237f407e9b7de3c2353c6d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><topic>Chemical thermodynamics</topic><topic>Chemistry</topic><topic>Cyclohexane</topic><topic>Densities</topic><topic>Exact sciences and technology</topic><topic>Excess molar volumes</topic><topic>General and physical chemistry</topic><topic>Methacrylates</topic><topic>Mixtures</topic><topic>Monomers</topic><topic>Thermodynamic properties</topic><topic>Vinyl acetate</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wisniak, Jaime</creatorcontrib><creatorcontrib>Peralta, René D.</creatorcontrib><creatorcontrib>Infante, Ramiro</creatorcontrib><creatorcontrib>Cortez, Gladis</creatorcontrib><creatorcontrib>López, R.G.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Thermochimica acta</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wisniak, Jaime</au><au>Peralta, René D.</au><au>Infante, Ramiro</au><au>Cortez, Gladis</au><au>López, R.G.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Densities, isobaric thermal compressibilities and derived thermodynamic properties of the binary systems of cyclohexane with allyl methacrylate, butyl methacrylate, methacrylic acid, and vinyl acetate at t = (298.15 and 308.15) K</atitle><jtitle>Thermochimica acta</jtitle><date>2005-10-15</date><risdate>2005</risdate><volume>437</volume><issue>1</issue><spage>1</spage><epage>6</epage><pages>1-6</pages><issn>0040-6031</issn><eissn>1872-762X</eissn><coden>THACAS</coden><abstract>Densities of the binary systems of cyclohexane with allyl methacrylate, butyl methacrylate, methacrylic acid, and vinyl acetate have been measured as a function of the composition, at 298.15 and 308.15
K and atmospheric pressure, using an Anton Paar DMA 5000 oscillating U-tube densimeter. The calculated excess molar volumes were correlated with the Redlich–Kister equation and with a series of Legendre polynomials. The excess molar volumes are positive for the four binaries studied. Within the short temperature range considered here the coefficient of thermal expansion is positive for all the systems studied; it varies only slightly with the nature of the acrylate except for the system cyclohexane
+
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| source | Access via ScienceDirect (Elsevier) |
| subjects | Chemical thermodynamics Chemistry Cyclohexane Densities Exact sciences and technology Excess molar volumes General and physical chemistry Methacrylates Mixtures Monomers Thermodynamic properties Vinyl acetate |
| title | Densities, isobaric thermal compressibilities and derived thermodynamic properties of the binary systems of cyclohexane with allyl methacrylate, butyl methacrylate, methacrylic acid, and vinyl acetate at t = (298.15 and 308.15) K |
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