1,4-bis(5-decyl-2,2′-bithien-5-yl)benzene as new stable organic semiconductor for high performance thin film transistors

The efficient synthesis of 1,4-bis(5-decyl-2,2′-bithien-5-yl)benzene, leading to “electronic-grade” pure semiconducting organic material, was elaborated. Cyclovoltamperometry measurements showed high oxidation stability of the thiophene-phenylene oligomer as compared to corresponding oligothiophenes...

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Veröffentlicht in:Synthetic metals 2005-03, Vol.149 (2), p.231-235
Hauptverfasser: Ponomarenko, Sergei A., Kirchmeyer, Stephan, Halik, Marcus, Klauk, Hagen, Zschieschang, Ute, Schmid, Günter, Karbach, Alexander, Drechsler, Doris, Alpatova, Ninel M.
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container_end_page 235
container_issue 2
container_start_page 231
container_title Synthetic metals
container_volume 149
creator Ponomarenko, Sergei A.
Kirchmeyer, Stephan
Halik, Marcus
Klauk, Hagen
Zschieschang, Ute
Schmid, Günter
Karbach, Alexander
Drechsler, Doris
Alpatova, Ninel M.
description The efficient synthesis of 1,4-bis(5-decyl-2,2′-bithien-5-yl)benzene, leading to “electronic-grade” pure semiconducting organic material, was elaborated. Cyclovoltamperometry measurements showed high oxidation stability of the thiophene-phenylene oligomer as compared to corresponding oligothiophenes. OTFT and integrated circuits, based on the synthesized oligomer, showed the mobilities as large as 0.3 cm 2/Vs, on/off current ratios as large as 10 5, and signal delays as low as 300 μs (measured with ring oscillators). AFM measurements confirmed improved morphology of the oligomer films obtained by vacuum evaporation on room temperature substrates.
doi_str_mv 10.1016/j.synthmet.2005.01.007
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subjects Organic field-effect transistors
Organic semiconductors
Oxidative stability
Thiophene-phenylene oligomers
title 1,4-bis(5-decyl-2,2′-bithien-5-yl)benzene as new stable organic semiconductor for high performance thin film transistors
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