Metal ion assistant transformation strategy to synthesize catechol-based metal–organic frameworks from Ti3C2Tx precursors

This work first exploits the feasibility of metal ion assistant transformation strategy to synthesize 3D catechol-based MOFs using 2D MXene as metal precursors, which exhibit obvious originality and universality in the field of transform synthesis. The unique synergetic transformation mechanism invo...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Science bulletin 2023-10, Vol.68 (19), p.2180-2189
Hauptverfasser: Wang, Weikang, Bai, Yan, Yang, Pin, Yuan, Shuai, Li, Feiyang, Zhao, Weiwei, Jin, Beibei, Zhang, Xuan, Liu, Shujuan, Yuan, Daqiang, Zhao, Qiang
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 2189
container_issue 19
container_start_page 2180
container_title Science bulletin
container_volume 68
creator Wang, Weikang
Bai, Yan
Yang, Pin
Yuan, Shuai
Li, Feiyang
Zhao, Weiwei
Jin, Beibei
Zhang, Xuan
Liu, Shujuan
Yuan, Daqiang
Zhao, Qiang
description This work first exploits the feasibility of metal ion assistant transformation strategy to synthesize 3D catechol-based MOFs using 2D MXene as metal precursors, which exhibit obvious originality and universality in the field of transform synthesis. The unique synergetic transformation mechanism involves the electron transfer from Ti3C2Tx to electrostatically adsorbed Cu2+ ion for redox reaction, subsequent Ti–C bond rupture for Ti4+ ion release, and the continuous chelation coordination between Ti4+/Cu2+ and HHTP. It motivates further works to utilize the electron transfer to provide a bridge for the conversion of MXene to MOFs and serve as a key step for the release of transition metal ions. [Display omitted] Chemical transformation strategy is capable of fabricating nanomaterials with well-defined structures and fascinating performance via controllable crystallization kinetics in the phase transformation. V2CTx MXene has been used as precursors to fabricate vanadium porphyrin metal–organic frameworks (V-PMOFs) via the coordination of deprotonated carboxylic acid ligands. However, the rational and in-depth exploration of synthesis mechanism with the aim of enriching the variety of MXene (i.e., Ti3C2Tx) and organic ligands (i.e., catechol-based) to design new MOFs is rarely reported. Herein, we have first developed a metal ion assistant transformation strategy to synthesize three-dimensional catechol-based TiCu-HHTP (HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene) MOFs with a non-interpenetrating SrSi2 (srs) framework using two-dimensional Ti3C2Tx as precursors. The unique synergetic transformation mechanism involves the electron transfer from Ti3C2Tx to electrostatically adsorbed Cu2+ ion for redox reaction, the subsequent Ti–C bond rupture for Ti4+ ion release, and the continuous chelation coordination between Ti4+/Cu2+ and HHTP. Ti3C2Tx precursors and auxiliary metal ion could be rationally substituted by V2CTx and Mn+ (e.g., Ni2+, Co2+, Mn2+, and Zn2+), respectively. This strategy lays the foundation for the design and synthesis of innovative and multifarious MOFs derived from MXene or other unconventional metal precursors.
doi_str_mv 10.1016/j.scib.2023.07.038
format Article
fullrecord <record><control><sourceid>proquest_elsev</sourceid><recordid>TN_cdi_proquest_miscellaneous_2848845690</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S2095927323004875</els_id><sourcerecordid>2848845690</sourcerecordid><originalsourceid>FETCH-LOGICAL-e241t-55624a90150c09dedb4d0f8c8a5763d5a7de16a38a47ec3385472a300d2451173</originalsourceid><addsrcrecordid>eNo9kE1uFDEQhVuISERJLpCVl2y6Kf-13RIbNAKClIjNZG157JrEQ3c7uDxAyIY7cENOQreCWNWrek9Ppa9pLjl0HHj_5tBRSLtOgJAdmA6kfdGcChh0OwjLX_7XRr5qLogOAMDVIBSY0-bpBqsfWcoz80SJqp8rq8XPtM9l8nU1aNkr3j2ymhk9zvUeKf1EFpZjuM9ju_OEkU1r0Z9fv3O583MKbF_8hN9z-UKLzBPbJrkR2x_soWA4FsqFzpuTvR8JL_7Ns-b2w_vt5qq9_vzx0-bddYtC8dpq3QvlB-AaAgwR405F2NtgvTa9jNqbiLz30nplMEhptTLCS4AolObcyLPm9XPvQ8lfj0jVTYkCjqOfMR_JCausVbofYIm-fY7i8s-3hMUtaHEOGNPydnUxJ8fBrdjdYfV2bsXuwLgFu_wL13t61A</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2848845690</pqid></control><display><type>article</type><title>Metal ion assistant transformation strategy to synthesize catechol-based metal–organic frameworks from Ti3C2Tx precursors</title><source>Alma/SFX Local Collection</source><creator>Wang, Weikang ; Bai, Yan ; Yang, Pin ; Yuan, Shuai ; Li, Feiyang ; Zhao, Weiwei ; Jin, Beibei ; Zhang, Xuan ; Liu, Shujuan ; Yuan, Daqiang ; Zhao, Qiang</creator><creatorcontrib>Wang, Weikang ; Bai, Yan ; Yang, Pin ; Yuan, Shuai ; Li, Feiyang ; Zhao, Weiwei ; Jin, Beibei ; Zhang, Xuan ; Liu, Shujuan ; Yuan, Daqiang ; Zhao, Qiang</creatorcontrib><description>This work first exploits the feasibility of metal ion assistant transformation strategy to synthesize 3D catechol-based MOFs using 2D MXene as metal precursors, which exhibit obvious originality and universality in the field of transform synthesis. The unique synergetic transformation mechanism involves the electron transfer from Ti3C2Tx to electrostatically adsorbed Cu2+ ion for redox reaction, subsequent Ti–C bond rupture for Ti4+ ion release, and the continuous chelation coordination between Ti4+/Cu2+ and HHTP. It motivates further works to utilize the electron transfer to provide a bridge for the conversion of MXene to MOFs and serve as a key step for the release of transition metal ions. [Display omitted] Chemical transformation strategy is capable of fabricating nanomaterials with well-defined structures and fascinating performance via controllable crystallization kinetics in the phase transformation. V2CTx MXene has been used as precursors to fabricate vanadium porphyrin metal–organic frameworks (V-PMOFs) via the coordination of deprotonated carboxylic acid ligands. However, the rational and in-depth exploration of synthesis mechanism with the aim of enriching the variety of MXene (i.e., Ti3C2Tx) and organic ligands (i.e., catechol-based) to design new MOFs is rarely reported. Herein, we have first developed a metal ion assistant transformation strategy to synthesize three-dimensional catechol-based TiCu-HHTP (HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene) MOFs with a non-interpenetrating SrSi2 (srs) framework using two-dimensional Ti3C2Tx as precursors. The unique synergetic transformation mechanism involves the electron transfer from Ti3C2Tx to electrostatically adsorbed Cu2+ ion for redox reaction, the subsequent Ti–C bond rupture for Ti4+ ion release, and the continuous chelation coordination between Ti4+/Cu2+ and HHTP. Ti3C2Tx precursors and auxiliary metal ion could be rationally substituted by V2CTx and Mn+ (e.g., Ni2+, Co2+, Mn2+, and Zn2+), respectively. This strategy lays the foundation for the design and synthesis of innovative and multifarious MOFs derived from MXene or other unconventional metal precursors.</description><identifier>ISSN: 2095-9273</identifier><identifier>EISSN: 2095-9281</identifier><identifier>DOI: 10.1016/j.scib.2023.07.038</identifier><language>eng</language><publisher>Elsevier B.V</publisher><subject>Electron transfer ; Insoluble metal precursors ; Metal ion assistant transformation strategy ; Metal–organic frameworks ; MXene</subject><ispartof>Science bulletin, 2023-10, Vol.68 (19), p.2180-2189</ispartof><rights>2023 Science China Press</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,781,785,27929,27930</link.rule.ids></links><search><creatorcontrib>Wang, Weikang</creatorcontrib><creatorcontrib>Bai, Yan</creatorcontrib><creatorcontrib>Yang, Pin</creatorcontrib><creatorcontrib>Yuan, Shuai</creatorcontrib><creatorcontrib>Li, Feiyang</creatorcontrib><creatorcontrib>Zhao, Weiwei</creatorcontrib><creatorcontrib>Jin, Beibei</creatorcontrib><creatorcontrib>Zhang, Xuan</creatorcontrib><creatorcontrib>Liu, Shujuan</creatorcontrib><creatorcontrib>Yuan, Daqiang</creatorcontrib><creatorcontrib>Zhao, Qiang</creatorcontrib><title>Metal ion assistant transformation strategy to synthesize catechol-based metal–organic frameworks from Ti3C2Tx precursors</title><title>Science bulletin</title><description>This work first exploits the feasibility of metal ion assistant transformation strategy to synthesize 3D catechol-based MOFs using 2D MXene as metal precursors, which exhibit obvious originality and universality in the field of transform synthesis. The unique synergetic transformation mechanism involves the electron transfer from Ti3C2Tx to electrostatically adsorbed Cu2+ ion for redox reaction, subsequent Ti–C bond rupture for Ti4+ ion release, and the continuous chelation coordination between Ti4+/Cu2+ and HHTP. It motivates further works to utilize the electron transfer to provide a bridge for the conversion of MXene to MOFs and serve as a key step for the release of transition metal ions. [Display omitted] Chemical transformation strategy is capable of fabricating nanomaterials with well-defined structures and fascinating performance via controllable crystallization kinetics in the phase transformation. V2CTx MXene has been used as precursors to fabricate vanadium porphyrin metal–organic frameworks (V-PMOFs) via the coordination of deprotonated carboxylic acid ligands. However, the rational and in-depth exploration of synthesis mechanism with the aim of enriching the variety of MXene (i.e., Ti3C2Tx) and organic ligands (i.e., catechol-based) to design new MOFs is rarely reported. Herein, we have first developed a metal ion assistant transformation strategy to synthesize three-dimensional catechol-based TiCu-HHTP (HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene) MOFs with a non-interpenetrating SrSi2 (srs) framework using two-dimensional Ti3C2Tx as precursors. The unique synergetic transformation mechanism involves the electron transfer from Ti3C2Tx to electrostatically adsorbed Cu2+ ion for redox reaction, the subsequent Ti–C bond rupture for Ti4+ ion release, and the continuous chelation coordination between Ti4+/Cu2+ and HHTP. Ti3C2Tx precursors and auxiliary metal ion could be rationally substituted by V2CTx and Mn+ (e.g., Ni2+, Co2+, Mn2+, and Zn2+), respectively. This strategy lays the foundation for the design and synthesis of innovative and multifarious MOFs derived from MXene or other unconventional metal precursors.</description><subject>Electron transfer</subject><subject>Insoluble metal precursors</subject><subject>Metal ion assistant transformation strategy</subject><subject>Metal–organic frameworks</subject><subject>MXene</subject><issn>2095-9273</issn><issn>2095-9281</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNo9kE1uFDEQhVuISERJLpCVl2y6Kf-13RIbNAKClIjNZG157JrEQ3c7uDxAyIY7cENOQreCWNWrek9Ppa9pLjl0HHj_5tBRSLtOgJAdmA6kfdGcChh0OwjLX_7XRr5qLogOAMDVIBSY0-bpBqsfWcoz80SJqp8rq8XPtM9l8nU1aNkr3j2ymhk9zvUeKf1EFpZjuM9ju_OEkU1r0Z9fv3O583MKbF_8hN9z-UKLzBPbJrkR2x_soWA4FsqFzpuTvR8JL_7Ns-b2w_vt5qq9_vzx0-bddYtC8dpq3QvlB-AaAgwR405F2NtgvTa9jNqbiLz30nplMEhptTLCS4AolObcyLPm9XPvQ8lfj0jVTYkCjqOfMR_JCausVbofYIm-fY7i8s-3hMUtaHEOGNPydnUxJ8fBrdjdYfV2bsXuwLgFu_wL13t61A</recordid><startdate>20231015</startdate><enddate>20231015</enddate><creator>Wang, Weikang</creator><creator>Bai, Yan</creator><creator>Yang, Pin</creator><creator>Yuan, Shuai</creator><creator>Li, Feiyang</creator><creator>Zhao, Weiwei</creator><creator>Jin, Beibei</creator><creator>Zhang, Xuan</creator><creator>Liu, Shujuan</creator><creator>Yuan, Daqiang</creator><creator>Zhao, Qiang</creator><general>Elsevier B.V</general><scope>7X8</scope></search><sort><creationdate>20231015</creationdate><title>Metal ion assistant transformation strategy to synthesize catechol-based metal–organic frameworks from Ti3C2Tx precursors</title><author>Wang, Weikang ; Bai, Yan ; Yang, Pin ; Yuan, Shuai ; Li, Feiyang ; Zhao, Weiwei ; Jin, Beibei ; Zhang, Xuan ; Liu, Shujuan ; Yuan, Daqiang ; Zhao, Qiang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-e241t-55624a90150c09dedb4d0f8c8a5763d5a7de16a38a47ec3385472a300d2451173</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Electron transfer</topic><topic>Insoluble metal precursors</topic><topic>Metal ion assistant transformation strategy</topic><topic>Metal–organic frameworks</topic><topic>MXene</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Weikang</creatorcontrib><creatorcontrib>Bai, Yan</creatorcontrib><creatorcontrib>Yang, Pin</creatorcontrib><creatorcontrib>Yuan, Shuai</creatorcontrib><creatorcontrib>Li, Feiyang</creatorcontrib><creatorcontrib>Zhao, Weiwei</creatorcontrib><creatorcontrib>Jin, Beibei</creatorcontrib><creatorcontrib>Zhang, Xuan</creatorcontrib><creatorcontrib>Liu, Shujuan</creatorcontrib><creatorcontrib>Yuan, Daqiang</creatorcontrib><creatorcontrib>Zhao, Qiang</creatorcontrib><collection>MEDLINE - Academic</collection><jtitle>Science bulletin</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Weikang</au><au>Bai, Yan</au><au>Yang, Pin</au><au>Yuan, Shuai</au><au>Li, Feiyang</au><au>Zhao, Weiwei</au><au>Jin, Beibei</au><au>Zhang, Xuan</au><au>Liu, Shujuan</au><au>Yuan, Daqiang</au><au>Zhao, Qiang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Metal ion assistant transformation strategy to synthesize catechol-based metal–organic frameworks from Ti3C2Tx precursors</atitle><jtitle>Science bulletin</jtitle><date>2023-10-15</date><risdate>2023</risdate><volume>68</volume><issue>19</issue><spage>2180</spage><epage>2189</epage><pages>2180-2189</pages><issn>2095-9273</issn><eissn>2095-9281</eissn><abstract>This work first exploits the feasibility of metal ion assistant transformation strategy to synthesize 3D catechol-based MOFs using 2D MXene as metal precursors, which exhibit obvious originality and universality in the field of transform synthesis. The unique synergetic transformation mechanism involves the electron transfer from Ti3C2Tx to electrostatically adsorbed Cu2+ ion for redox reaction, subsequent Ti–C bond rupture for Ti4+ ion release, and the continuous chelation coordination between Ti4+/Cu2+ and HHTP. It motivates further works to utilize the electron transfer to provide a bridge for the conversion of MXene to MOFs and serve as a key step for the release of transition metal ions. [Display omitted] Chemical transformation strategy is capable of fabricating nanomaterials with well-defined structures and fascinating performance via controllable crystallization kinetics in the phase transformation. V2CTx MXene has been used as precursors to fabricate vanadium porphyrin metal–organic frameworks (V-PMOFs) via the coordination of deprotonated carboxylic acid ligands. However, the rational and in-depth exploration of synthesis mechanism with the aim of enriching the variety of MXene (i.e., Ti3C2Tx) and organic ligands (i.e., catechol-based) to design new MOFs is rarely reported. Herein, we have first developed a metal ion assistant transformation strategy to synthesize three-dimensional catechol-based TiCu-HHTP (HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene) MOFs with a non-interpenetrating SrSi2 (srs) framework using two-dimensional Ti3C2Tx as precursors. The unique synergetic transformation mechanism involves the electron transfer from Ti3C2Tx to electrostatically adsorbed Cu2+ ion for redox reaction, the subsequent Ti–C bond rupture for Ti4+ ion release, and the continuous chelation coordination between Ti4+/Cu2+ and HHTP. Ti3C2Tx precursors and auxiliary metal ion could be rationally substituted by V2CTx and Mn+ (e.g., Ni2+, Co2+, Mn2+, and Zn2+), respectively. This strategy lays the foundation for the design and synthesis of innovative and multifarious MOFs derived from MXene or other unconventional metal precursors.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.scib.2023.07.038</doi><tpages>10</tpages></addata></record>
fulltext fulltext
identifier ISSN: 2095-9273
ispartof Science bulletin, 2023-10, Vol.68 (19), p.2180-2189
issn 2095-9273
2095-9281
language eng
recordid cdi_proquest_miscellaneous_2848845690
source Alma/SFX Local Collection
subjects Electron transfer
Insoluble metal precursors
Metal ion assistant transformation strategy
Metal–organic frameworks
MXene
title Metal ion assistant transformation strategy to synthesize catechol-based metal–organic frameworks from Ti3C2Tx precursors
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-14T17%3A16%3A43IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_elsev&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Metal%20ion%20assistant%20transformation%20strategy%20to%20synthesize%20catechol-based%20metal%E2%80%93organic%20frameworks%20from%20Ti3C2Tx%20precursors&rft.jtitle=Science%20bulletin&rft.au=Wang,%20Weikang&rft.date=2023-10-15&rft.volume=68&rft.issue=19&rft.spage=2180&rft.epage=2189&rft.pages=2180-2189&rft.issn=2095-9273&rft.eissn=2095-9281&rft_id=info:doi/10.1016/j.scib.2023.07.038&rft_dat=%3Cproquest_elsev%3E2848845690%3C/proquest_elsev%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2848845690&rft_id=info:pmid/&rft_els_id=S2095927323004875&rfr_iscdi=true