Eu(III) transfer in single N,N,N’,N’-tetraoctyldiglycolamide-impregnated polymer-coated silica particle using fluorescence microspectroscopy: transfer mechanism and effect of polymer crosslinking degree
A microcapillary manipulation system combined with fluorescence microspectroscopy enabled us to analyze mass transfer in a single particle. In this study, we revealed the Eu(III) distribution in a single diglycolamide-derivative extractant (TODGA)-impregnated polymer-coated silica particle. The reac...
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| Veröffentlicht in: | Analytical sciences 2023-11, Vol.39 (11), p.1929-1936 |
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| container_end_page | 1936 |
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| container_issue | 11 |
| container_start_page | 1929 |
| container_title | Analytical sciences |
| container_volume | 39 |
| creator | Miyagawa, Akihisa Takahashi, Takumi Kuzure, Yoshiaki Iwamoto, Hibiki Arai, Tsuyoshi Nagatomo, Shigenori Watanabe, Sou Sano, Yuichi Nakatani, Kiyoharu |
| description | A microcapillary manipulation system combined with fluorescence microspectroscopy enabled us to analyze mass transfer in a single particle. In this study, we revealed the Eu(III) distribution in a single diglycolamide-derivative extractant (TODGA)-impregnated polymer-coated silica particle. The reaction of Eu(III) with two TODGA molecules in the polymer layer was the rate-limiting process, which was revealed by the relationship between the rate constants (
k
1
and
k
-1
) and concentrations of Eu(III) and HNO
3
. The decrease in the crosslinking degree of the polymer layer caused an increase in only
k
-1
. This indicates that hydrophilic environments at lower crosslinking degrees enhance the stability of the charged Eu(III) species such as Eu
3+
, Eu(NO
3
)
2+
, and Eu(NO
3
)
2
+
.
Graphical abstract |
| doi_str_mv | 10.1007/s44211-023-00402-9 |
| format | Article |
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k
1
and
k
-1
) and concentrations of Eu(III) and HNO
3
. The decrease in the crosslinking degree of the polymer layer caused an increase in only
k
-1
. This indicates that hydrophilic environments at lower crosslinking degrees enhance the stability of the charged Eu(III) species such as Eu
3+
, Eu(NO
3
)
2+
, and Eu(NO
3
)
2
+
.
Graphical abstract</description><identifier>ISSN: 0910-6340</identifier><identifier>EISSN: 1348-2246</identifier><identifier>DOI: 10.1007/s44211-023-00402-9</identifier><identifier>PMID: 37555916</identifier><language>eng</language><publisher>Singapore: Springer Nature Singapore</publisher><subject>Analytical Chemistry ; Chemistry ; Chemistry and Materials Science ; Original Paper</subject><ispartof>Analytical sciences, 2023-11, Vol.39 (11), p.1929-1936</ispartof><rights>The Author(s), under exclusive licence to The Japan Society for Analytical Chemistry 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><rights>2023. The Author(s), under exclusive licence to The Japan Society for Analytical Chemistry.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c342t-749d85b6fae5c4207e967706d894c7a7448f3b58b02533edeec9d1031becb0a63</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s44211-023-00402-9$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s44211-023-00402-9$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/37555916$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Miyagawa, Akihisa</creatorcontrib><creatorcontrib>Takahashi, Takumi</creatorcontrib><creatorcontrib>Kuzure, Yoshiaki</creatorcontrib><creatorcontrib>Iwamoto, Hibiki</creatorcontrib><creatorcontrib>Arai, Tsuyoshi</creatorcontrib><creatorcontrib>Nagatomo, Shigenori</creatorcontrib><creatorcontrib>Watanabe, Sou</creatorcontrib><creatorcontrib>Sano, Yuichi</creatorcontrib><creatorcontrib>Nakatani, Kiyoharu</creatorcontrib><title>Eu(III) transfer in single N,N,N’,N’-tetraoctyldiglycolamide-impregnated polymer-coated silica particle using fluorescence microspectroscopy: transfer mechanism and effect of polymer crosslinking degree</title><title>Analytical sciences</title><addtitle>ANAL. SCI</addtitle><addtitle>Anal Sci</addtitle><description>A microcapillary manipulation system combined with fluorescence microspectroscopy enabled us to analyze mass transfer in a single particle. In this study, we revealed the Eu(III) distribution in a single diglycolamide-derivative extractant (TODGA)-impregnated polymer-coated silica particle. The reaction of Eu(III) with two TODGA molecules in the polymer layer was the rate-limiting process, which was revealed by the relationship between the rate constants (
k
1
and
k
-1
) and concentrations of Eu(III) and HNO
3
. The decrease in the crosslinking degree of the polymer layer caused an increase in only
k
-1
. This indicates that hydrophilic environments at lower crosslinking degrees enhance the stability of the charged Eu(III) species such as Eu
3+
, Eu(NO
3
)
2+
, and Eu(NO
3
)
2
+
.
Graphical abstract</description><subject>Analytical Chemistry</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Original Paper</subject><issn>0910-6340</issn><issn>1348-2246</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp9kU2OFSEUhYnR2M_WDTgwDNtElL_6c9bptPqSjk50TCi4VdJSUELVoGZuw025CFci771unRkSbgjfOdzLQeg5o68Zpc2bLCVnjFAuCKWSctI9QDsmZEs4l_VDtKMdo6QWkp6hJznfUsp4y_ljdCaaqqo6Vu_Qr-v1Yr_fv8RL0iEPkLALOLswesAfX5X1-8fP40YWKEg0y-atG_1moteTs0DcNCcYg17A4jn6bYJETDwes_POaDzrtDhTDNeDMR78GhNkA8EAnpxJMc9gllJMnLe3_zqZwHzVweUJ62AxDEOhcBzuX8EHZfYufDu4WhgTwFP0aNA-w7O7eo6-vLv-fPWB3Hx6v7-6vCFGSL6QRna2rfp60FAZyWkDXd00tLZtJ02jGynbQfRV21NeCQEWwHSWUcF6MD3VtThHFyffOcXvK-RFTa5M5L0OENeseCvLT3d1TQvKT-ix3QSDmpObdNoUo-qQozrlqEqO6pij6oroxZ3_2k9g_0rugyuAOAG5XIURkrqNawpl5v_Z_gEf8rA0</recordid><startdate>20231101</startdate><enddate>20231101</enddate><creator>Miyagawa, Akihisa</creator><creator>Takahashi, Takumi</creator><creator>Kuzure, Yoshiaki</creator><creator>Iwamoto, Hibiki</creator><creator>Arai, Tsuyoshi</creator><creator>Nagatomo, Shigenori</creator><creator>Watanabe, Sou</creator><creator>Sano, Yuichi</creator><creator>Nakatani, Kiyoharu</creator><general>Springer Nature Singapore</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20231101</creationdate><title>Eu(III) transfer in single N,N,N’,N’-tetraoctyldiglycolamide-impregnated polymer-coated silica particle using fluorescence microspectroscopy: transfer mechanism and effect of polymer crosslinking degree</title><author>Miyagawa, Akihisa ; Takahashi, Takumi ; Kuzure, Yoshiaki ; Iwamoto, Hibiki ; Arai, Tsuyoshi ; Nagatomo, Shigenori ; Watanabe, Sou ; Sano, Yuichi ; Nakatani, Kiyoharu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c342t-749d85b6fae5c4207e967706d894c7a7448f3b58b02533edeec9d1031becb0a63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Analytical Chemistry</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Original Paper</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Miyagawa, Akihisa</creatorcontrib><creatorcontrib>Takahashi, Takumi</creatorcontrib><creatorcontrib>Kuzure, Yoshiaki</creatorcontrib><creatorcontrib>Iwamoto, Hibiki</creatorcontrib><creatorcontrib>Arai, Tsuyoshi</creatorcontrib><creatorcontrib>Nagatomo, Shigenori</creatorcontrib><creatorcontrib>Watanabe, Sou</creatorcontrib><creatorcontrib>Sano, Yuichi</creatorcontrib><creatorcontrib>Nakatani, Kiyoharu</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Analytical sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Miyagawa, Akihisa</au><au>Takahashi, Takumi</au><au>Kuzure, Yoshiaki</au><au>Iwamoto, Hibiki</au><au>Arai, Tsuyoshi</au><au>Nagatomo, Shigenori</au><au>Watanabe, Sou</au><au>Sano, Yuichi</au><au>Nakatani, Kiyoharu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Eu(III) transfer in single N,N,N’,N’-tetraoctyldiglycolamide-impregnated polymer-coated silica particle using fluorescence microspectroscopy: transfer mechanism and effect of polymer crosslinking degree</atitle><jtitle>Analytical sciences</jtitle><stitle>ANAL. SCI</stitle><addtitle>Anal Sci</addtitle><date>2023-11-01</date><risdate>2023</risdate><volume>39</volume><issue>11</issue><spage>1929</spage><epage>1936</epage><pages>1929-1936</pages><issn>0910-6340</issn><eissn>1348-2246</eissn><abstract>A microcapillary manipulation system combined with fluorescence microspectroscopy enabled us to analyze mass transfer in a single particle. In this study, we revealed the Eu(III) distribution in a single diglycolamide-derivative extractant (TODGA)-impregnated polymer-coated silica particle. The reaction of Eu(III) with two TODGA molecules in the polymer layer was the rate-limiting process, which was revealed by the relationship between the rate constants (
k
1
and
k
-1
) and concentrations of Eu(III) and HNO
3
. The decrease in the crosslinking degree of the polymer layer caused an increase in only
k
-1
. This indicates that hydrophilic environments at lower crosslinking degrees enhance the stability of the charged Eu(III) species such as Eu
3+
, Eu(NO
3
)
2+
, and Eu(NO
3
)
2
+
.
Graphical abstract</abstract><cop>Singapore</cop><pub>Springer Nature Singapore</pub><pmid>37555916</pmid><doi>10.1007/s44211-023-00402-9</doi><tpages>8</tpages><oa>free_for_read</oa></addata></record> |
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| source | Freely Accessible Japanese Titles - check A-Z of ejournals; Springer Nature - Complete Springer Journals; Free E-Journal (出版社公開部分のみ） |
| subjects | Analytical Chemistry Chemistry Chemistry and Materials Science Original Paper |
| title | Eu(III) transfer in single N,N,N’,N’-tetraoctyldiglycolamide-impregnated polymer-coated silica particle using fluorescence microspectroscopy: transfer mechanism and effect of polymer crosslinking degree |
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