Design rules for reversible thermochromic mixtures
The results of a systematic study of the influence of the color developer and the solvent on thermochromic properties of a reversible thermochromic system—crystal violet lactone as dye; propyl gallate, octyl gallate or lauryl gallate as developer; 1-tetradecanol, 1-hexadecanol or 1-octadecanol as so...
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| Veröffentlicht in: | Journal of materials science 2005-02, Vol.40 (3), p.669-676 |
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| container_end_page | 676 |
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| container_title | Journal of materials science |
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| creator | MACLAREN, D. C WHITE, M. A |
| description | The results of a systematic study of the influence of the color developer and the solvent on thermochromic properties of a reversible thermochromic system—crystal violet lactone as dye; propyl gallate, octyl gallate or lauryl gallate as developer; 1-tetradecanol, 1-hexadecanol or 1-octadecanol as solvent—are presented. Thermodynamic analysis of the developer-solvent phase diagrams is used to determine and compare the developer-solvent interactions in the systems, and observed variations in thermochromic properties are correlated with these interactions. The relationship between thermochromic behavior and competing dye-developer and developer-solvent interactions leads us to the first design rules for reversible thermochromic mixtures based on intermolecular interactions. |
| doi_str_mv | 10.1007/s10853-005-6305-x |
| format | Article |
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The relationship between thermochromic behavior and competing dye-developer and developer-solvent interactions leads us to the first design rules for reversible thermochromic mixtures based on intermolecular interactions.</description><identifier>ISSN: 0022-2461</identifier><identifier>EISSN: 1573-4803</identifier><identifier>DOI: 10.1007/s10853-005-6305-x</identifier><identifier>CODEN: JMTSAS</identifier><language>eng</language><publisher>Heidelberg: Springer</publisher><subject>Chemical thermodynamics ; Chemistry ; Color ; Crystal Violet Lactone ; Design engineering ; Developers ; Dyes ; Exact sciences and technology ; Gallates ; General and physical chemistry ; Lactones ; Materials science ; Mixtures ; Phase diagrams ; Solvents ; Thermodynamic properties</subject><ispartof>Journal of materials science, 2005-02, Vol.40 (3), p.669-676</ispartof><rights>2006 INIST-CNRS</rights><rights>Journal of Materials Science is a copyright of Springer, (2005). 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The relationship between thermochromic behavior and competing dye-developer and developer-solvent interactions leads us to the first design rules for reversible thermochromic mixtures based on intermolecular interactions.</description><subject>Chemical thermodynamics</subject><subject>Chemistry</subject><subject>Color</subject><subject>Crystal Violet Lactone</subject><subject>Design engineering</subject><subject>Developers</subject><subject>Dyes</subject><subject>Exact sciences and technology</subject><subject>Gallates</subject><subject>General and physical chemistry</subject><subject>Lactones</subject><subject>Materials science</subject><subject>Mixtures</subject><subject>Phase diagrams</subject><subject>Solvents</subject><subject>Thermodynamic properties</subject><issn>0022-2461</issn><issn>1573-4803</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kV1LwzAUhoMoOKc_wLuCKN5UTz7bXsr8hIE3eh2S9MR1tOtMWpn_3owNBC-EQ87N874kTwg5p3BDAYrbSKGUPAeQueLp2ByQCZUFz0UJ_JBMABjLmVD0mJzEuIQEFoxOCLvH2HyssjC2GDPfhyzgF4bY2BazYYGh690i9F3jsq7ZDGPAeEqOvGkjnu33lLw_PrzNnvP569PL7G6eO66KIa_Bo-TeeMTKWrRcADWyrivPuPKVdRWTaRgoy6kt6oRaK7wxlUDBgfIpudr1rkP_OWIcdNdEh21rVtiPUbNSlFQpkcDrf8GkhtGC0rJM6MUfdNmPYZWeoVm6jipBCpUouqNc6GMM6PU6NJ0J36lKb3XrnW6dLOqtbr1Jmct9s4nOtD6YlWvib1BJVkD6ix-F5n9l</recordid><startdate>20050201</startdate><enddate>20050201</enddate><creator>MACLAREN, D. 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| issn | 0022-2461 1573-4803 |
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| subjects | Chemical thermodynamics Chemistry Color Crystal Violet Lactone Design engineering Developers Dyes Exact sciences and technology Gallates General and physical chemistry Lactones Materials science Mixtures Phase diagrams Solvents Thermodynamic properties |
| title | Design rules for reversible thermochromic mixtures |
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