A manganese dioxide nanoparticle–bimetallic metal organic framework composite for selective and sensitive detection of vitamin D3 in human plasma
For the first time a metal organic framework nanomaterial has been developed comprising manganese dioxide nanoparticle and iron and zinc metal ions interlinked with each other via terephthalic acid. The framework shape was identified as an elongated hexagonal nanorod (TEM) with varying functional gr...
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| Veröffentlicht in: | Mikrochimica acta (1966) 2023-09, Vol.190 (9), p.345-345, Article 345 |
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| container_title | Mikrochimica acta (1966) |
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| creator | Lokesh Kumar, S Kumar, Sanjit Tetala, Kishore K. R. |
| description | For the first time a metal organic framework nanomaterial has been developed comprising manganese dioxide nanoparticle and iron and zinc metal ions interlinked with each other via terephthalic acid. The framework shape was identified as an elongated hexagonal nanorod (TEM) with varying functional groups (FT-IR) and diffraction patterns (XRD). The framework nanocomposite as such in aqueous acidic electrolyte solution has displayed an excellent conductivity (redox behavior) and surface excess (3.08 × 10
−8
cm
−2
). Under the optimized conditions (0.1 M H
2
SO
4
as electrolyte, 50 mV/s scan rate, +1.26 V (vs Ag/AgCl)), the metal organic framework coated electrode has selectively identified vitamin D
3
(VD
3
) in the presence of various other interfering molecules and displayed excellent limit of detection (1.9 ng mL
−1
). The developed sensor has been applied to the determination of VD
3
in extracted human plasma samples (RSD of 0.3–2.6 % and recovery of 96–102 %), and the obtained VD3 values are similar to HPLC-UV method.
Graphical abstract |
| doi_str_mv | 10.1007/s00604-023-05904-x |
| format | Article |
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−8
cm
−2
). Under the optimized conditions (0.1 M H
2
SO
4
as electrolyte, 50 mV/s scan rate, +1.26 V (vs Ag/AgCl)), the metal organic framework coated electrode has selectively identified vitamin D
3
(VD
3
) in the presence of various other interfering molecules and displayed excellent limit of detection (1.9 ng mL
−1
). The developed sensor has been applied to the determination of VD
3
in extracted human plasma samples (RSD of 0.3–2.6 % and recovery of 96–102 %), and the obtained VD3 values are similar to HPLC-UV method.
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−8
cm
−2
). Under the optimized conditions (0.1 M H
2
SO
4
as electrolyte, 50 mV/s scan rate, +1.26 V (vs Ag/AgCl)), the metal organic framework coated electrode has selectively identified vitamin D
3
(VD
3
) in the presence of various other interfering molecules and displayed excellent limit of detection (1.9 ng mL
−1
). The developed sensor has been applied to the determination of VD
3
in extracted human plasma samples (RSD of 0.3–2.6 % and recovery of 96–102 %), and the obtained VD3 values are similar to HPLC-UV method.
Graphical abstract</description><subject>Analytical Chemistry</subject><subject>Bimetals</subject><subject>Blood plasma</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Coated electrodes</subject><subject>Diffraction patterns</subject><subject>Electrolytes</subject><subject>Functional groups</subject><subject>Manganese dioxide</subject><subject>Metal-organic frameworks</subject><subject>Microengineering</subject><subject>Nanochemistry</subject><subject>Nanocomposites</subject><subject>Nanomaterials</subject><subject>Nanoparticles</subject><subject>Nanorods</subject><subject>Nanotechnology</subject><subject>Original Paper</subject><subject>Sulfuric acid</subject><subject>Terephthalic acid</subject><issn>0026-3672</issn><issn>1436-5073</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp9kU1uFDEQhS0EEkPCBVhZYsOmSfmn7ellFAiJFIkNWVs17urg0G03dk8YdtwhN-QkeGaQIrFgY9ezv1cq1WPsjYD3AsCeFQADugGpGmi7Wu2esZXQyjQtWPWcrQCkaZSx8iV7Vco9gLBG6hV7POcTxjuMVIj3Ie1CTzxiTDPmJfiRfv963ISJFhzH4Pmh4ClXQ1VDxol-pPyN-zTNqYSF-JAyLzSSX8IDcYx9VbH-7FVPy_49RZ4G_hAWnELkHxSv59dtHYPPI5YJT9mLAcdCr__eJ-z28uOXi6vm5vOn64vzm8arVi6Nt2hagYMWHoXsbCc0tZ60RqU7NKiIerMWvQUi0_cbqAbUcmONtq1tvTph745955y-b6ksbgrF0zjWbaRtcXKtTSfX0OmKvv0HvU_bHOt0B6pVYg17Sh4pn1MpmQY35zBh_ukEuH1O7piTqzm5Q05uV03qaCoVjneUn1r_x_UH9k2aPQ</recordid><startdate>20230901</startdate><enddate>20230901</enddate><creator>Lokesh Kumar, S</creator><creator>Kumar, Sanjit</creator><creator>Tetala, Kishore K. R.</creator><general>Springer Vienna</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>K9.</scope><scope>7X8</scope></search><sort><creationdate>20230901</creationdate><title>A manganese dioxide nanoparticle–bimetallic metal organic framework composite for selective and sensitive detection of vitamin D3 in human plasma</title><author>Lokesh Kumar, S ; Kumar, Sanjit ; Tetala, Kishore K. R.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c352t-c7a651af41ca1297914e5ce44a349a6a3eed681d70ee6ddb0c7aa42b7647575c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Analytical Chemistry</topic><topic>Bimetals</topic><topic>Blood plasma</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Coated electrodes</topic><topic>Diffraction patterns</topic><topic>Electrolytes</topic><topic>Functional groups</topic><topic>Manganese dioxide</topic><topic>Metal-organic frameworks</topic><topic>Microengineering</topic><topic>Nanochemistry</topic><topic>Nanocomposites</topic><topic>Nanomaterials</topic><topic>Nanoparticles</topic><topic>Nanorods</topic><topic>Nanotechnology</topic><topic>Original Paper</topic><topic>Sulfuric acid</topic><topic>Terephthalic acid</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lokesh Kumar, S</creatorcontrib><creatorcontrib>Kumar, Sanjit</creatorcontrib><creatorcontrib>Tetala, Kishore K. R.</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Mikrochimica acta (1966)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lokesh Kumar, S</au><au>Kumar, Sanjit</au><au>Tetala, Kishore K. R.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A manganese dioxide nanoparticle–bimetallic metal organic framework composite for selective and sensitive detection of vitamin D3 in human plasma</atitle><jtitle>Mikrochimica acta (1966)</jtitle><stitle>Microchim Acta</stitle><date>2023-09-01</date><risdate>2023</risdate><volume>190</volume><issue>9</issue><spage>345</spage><epage>345</epage><pages>345-345</pages><artnum>345</artnum><issn>0026-3672</issn><eissn>1436-5073</eissn><abstract>For the first time a metal organic framework nanomaterial has been developed comprising manganese dioxide nanoparticle and iron and zinc metal ions interlinked with each other via terephthalic acid. The framework shape was identified as an elongated hexagonal nanorod (TEM) with varying functional groups (FT-IR) and diffraction patterns (XRD). The framework nanocomposite as such in aqueous acidic electrolyte solution has displayed an excellent conductivity (redox behavior) and surface excess (3.08 × 10
−8
cm
−2
). Under the optimized conditions (0.1 M H
2
SO
4
as electrolyte, 50 mV/s scan rate, +1.26 V (vs Ag/AgCl)), the metal organic framework coated electrode has selectively identified vitamin D
3
(VD
3
) in the presence of various other interfering molecules and displayed excellent limit of detection (1.9 ng mL
−1
). The developed sensor has been applied to the determination of VD
3
in extracted human plasma samples (RSD of 0.3–2.6 % and recovery of 96–102 %), and the obtained VD3 values are similar to HPLC-UV method.
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| ispartof | Mikrochimica acta (1966), 2023-09, Vol.190 (9), p.345-345, Article 345 |
| issn | 0026-3672 1436-5073 |
| language | eng |
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| source | SpringerNature Journals |
| subjects | Analytical Chemistry Bimetals Blood plasma Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Coated electrodes Diffraction patterns Electrolytes Functional groups Manganese dioxide Metal-organic frameworks Microengineering Nanochemistry Nanocomposites Nanomaterials Nanoparticles Nanorods Nanotechnology Original Paper Sulfuric acid Terephthalic acid |
| title | A manganese dioxide nanoparticle–bimetallic metal organic framework composite for selective and sensitive detection of vitamin D3 in human plasma |
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