Schlenk-type Equilibria of Grignard-analogous Arylberyllium Complexes: Steric Effects

The presence of complex Schlenk equilibria is a central property of synthetically invaluable Grignard reagents substantially affecting their reactivity and selectivity in chemical transformations. In this work, we systematically studied the steric effects of aryl substituents on the Schlenk-type equ...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Chemistry : a European journal 2023-10, Vol.29 (60), p.e202302222
Hauptverfasser:	Helling, Christoph, Jones, Cameron
Format:	Artikel
Sprache:	eng
Schlagworte:	Aromatic compounds Bromides Chemistry Congeners Equilibrium NMR Nuclear magnetic resonance Reagents Steric effects Temperature dependence
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!