Triplet Generation Through Singlet Fission in Metal-Organic Framework: An Alternative Route to Inefficient Singlet-Triplet Intersystem Crossing

High quantum yield triplets, populated by initially prepared excited singlets, are desired for various energy conversion schemes in solid working compositions like porous MOFs. However, a large disparity in the distribution of the excitonic center of mass, singlet-triplet intersystem crossing (ISC)...

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Veröffentlicht in:	Angewandte Chemie International Edition 2023-09, Vol.62 (38), p.e202305323-e202305323
Hauptverfasser:	Surendran Rajasree, Sreehari, Yu, Jierui, Fry, H Christopher, Anderson, Ryther, Xu, Wenqian, Krishnan, Riya, Duan, Jiaxin, Goswami, Subhadip, A Gómez-Gualdrón, Diego, Deria, Pravas
Format:	Artikel
Sprache:	eng
Schlagworte:	Atmospheric chemistry Coupling crystalline assembly Energy conversion Fission Heavy metals inhibited ISC Metal ions Metal-organic frameworks Photochemicals singlet fission Triplets Zirconium Zr-MOF
Online-Zugang:	Volltext
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