Atomic structure of nanomaterials: combined X-ray diffraction and EXAFS studies
The structures of Pd nanoparticles and layered MoS2-based nanocomposites prepared by wet routes under mild chemical conditions were studied by a combination of EXAFS spectroscopy and powder X-ray diffraction (XRD). Experimental diffractograms were compared with the patterns calculated for model clus...
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Veröffentlicht in: | Journal of alloys and compounds 2004-11, Vol.382 (1-2), p.46-53 |
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container_title | Journal of alloys and compounds |
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creator | Belyakova, O.A. Zubavichus, Y.V. Neretin, I.S. Golub, A.S. Novikov, Yu.N. Mednikov, E.G. Vargaftik, M.N. Moiseev, I.I. Slovokhotov, Yu.L. |
description | The structures of Pd nanoparticles and layered MoS2-based nanocomposites prepared by wet routes under mild chemical conditions were studied by a combination of EXAFS spectroscopy and powder X-ray diffraction (XRD). Experimental diffractograms were compared with the patterns calculated for model clusters approximating the structure of the nanomaterials. The calculations were performed using a specially designed program, which simulates the XRD patterns of atomic aggregates based on the Debye formula. This combination “XAFS + XRD + modeling” proves to be an efficient tool for a characterization of poorly ordered nanomaterials. |
doi_str_mv | 10.1016/j.jallcom.2004.05.047 |
format | Article |
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Experimental diffractograms were compared with the patterns calculated for model clusters approximating the structure of the nanomaterials. The calculations were performed using a specially designed program, which simulates the XRD patterns of atomic aggregates based on the Debye formula. 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Experimental diffractograms were compared with the patterns calculated for model clusters approximating the structure of the nanomaterials. The calculations were performed using a specially designed program, which simulates the XRD patterns of atomic aggregates based on the Debye formula. This combination “XAFS + XRD + modeling” proves to be an efficient tool for a characterization of poorly ordered nanomaterials.</description><subject>Debye formula</subject><subject>EXAFS</subject><subject>Molybdenum disulfide</subject><subject>Nanostructures</subject><subject>Palladium clusters</subject><subject>X-ray diffraction</subject><issn>0925-8388</issn><issn>1873-4669</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNqFkE9LwzAYh4MoOKcfQcjJW2vSpG3iRcbYVBjsoMJuIc0fyGibmaTCvr0Z293Te3l-D7wPAI8YlRjh5nlf7mXfKz-UFUK0RHWJaHsFZpi1pKBNw6_BDPGqLhhh7BbcxbhHCGFO8AxsF8kPTsGYwqTSFAz0Fo5y9INMJjjZxxeYzZ0bjYa7Isgj1M7aIFVyfoRy1HC1W6w_s2DSzsR7cGPzyDxc7hx8r1dfy_dis337WC42hSKEpaLTXdVh0mDOdNNi3bWWIlzZTkpbNTXiTLYNMxRxnnnFOs5MbStdc4qlpZbMwdPZewj-ZzIxicFFZfpejsZPUVSMUkRansH6DKrgYwzGikNwgwxHgZE45RN7ccknTvkEqkXOl3ev553JX_w6E0RUzozKaBeMSkJ794_hD5YMe6k</recordid><startdate>20041117</startdate><enddate>20041117</enddate><creator>Belyakova, O.A.</creator><creator>Zubavichus, Y.V.</creator><creator>Neretin, I.S.</creator><creator>Golub, A.S.</creator><creator>Novikov, Yu.N.</creator><creator>Mednikov, E.G.</creator><creator>Vargaftik, M.N.</creator><creator>Moiseev, I.I.</creator><creator>Slovokhotov, Yu.L.</creator><general>Elsevier B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SC</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>H8D</scope><scope>JG9</scope><scope>JQ2</scope><scope>L7M</scope><scope>L~C</scope><scope>L~D</scope></search><sort><creationdate>20041117</creationdate><title>Atomic structure of nanomaterials: combined X-ray diffraction and EXAFS studies</title><author>Belyakova, O.A. ; Zubavichus, Y.V. ; Neretin, I.S. ; Golub, A.S. ; Novikov, Yu.N. ; Mednikov, E.G. ; Vargaftik, M.N. ; Moiseev, I.I. ; Slovokhotov, Yu.L.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c338t-bdb2b136198d671db7f4012fbaaf265098a768e4099338c8b98e5f2d5941af4f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><topic>Debye formula</topic><topic>EXAFS</topic><topic>Molybdenum disulfide</topic><topic>Nanostructures</topic><topic>Palladium clusters</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Belyakova, O.A.</creatorcontrib><creatorcontrib>Zubavichus, Y.V.</creatorcontrib><creatorcontrib>Neretin, I.S.</creatorcontrib><creatorcontrib>Golub, A.S.</creatorcontrib><creatorcontrib>Novikov, Yu.N.</creatorcontrib><creatorcontrib>Mednikov, E.G.</creatorcontrib><creatorcontrib>Vargaftik, M.N.</creatorcontrib><creatorcontrib>Moiseev, I.I.</creatorcontrib><creatorcontrib>Slovokhotov, Yu.L.</creatorcontrib><collection>CrossRef</collection><collection>Computer and Information Systems Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Computer and Information Systems Abstracts Academic</collection><collection>Computer and Information Systems Abstracts Professional</collection><jtitle>Journal of alloys and compounds</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Belyakova, O.A.</au><au>Zubavichus, Y.V.</au><au>Neretin, I.S.</au><au>Golub, A.S.</au><au>Novikov, Yu.N.</au><au>Mednikov, E.G.</au><au>Vargaftik, M.N.</au><au>Moiseev, I.I.</au><au>Slovokhotov, Yu.L.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Atomic structure of nanomaterials: combined X-ray diffraction and EXAFS studies</atitle><jtitle>Journal of alloys and compounds</jtitle><date>2004-11-17</date><risdate>2004</risdate><volume>382</volume><issue>1-2</issue><spage>46</spage><epage>53</epage><pages>46-53</pages><issn>0925-8388</issn><eissn>1873-4669</eissn><abstract>The structures of Pd nanoparticles and layered MoS2-based nanocomposites prepared by wet routes under mild chemical conditions were studied by a combination of EXAFS spectroscopy and powder X-ray diffraction (XRD). Experimental diffractograms were compared with the patterns calculated for model clusters approximating the structure of the nanomaterials. The calculations were performed using a specially designed program, which simulates the XRD patterns of atomic aggregates based on the Debye formula. This combination “XAFS + XRD + modeling” proves to be an efficient tool for a characterization of poorly ordered nanomaterials.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.jallcom.2004.05.047</doi><tpages>8</tpages></addata></record> |
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subjects | Debye formula EXAFS Molybdenum disulfide Nanostructures Palladium clusters X-ray diffraction |
title | Atomic structure of nanomaterials: combined X-ray diffraction and EXAFS studies |
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