Thermal oxidation of nonstabilized and stabilized polymers and chemiluminescence
The chemiluminescence under isothermal and nonisothermal conditions accompanying the oxidation of some polymers (polyolefins, polyamides, and polysaccharides) has been examined from the viewpoint of its relationship with the rate of oxidation. The chemical structure of a given type of polymer plays...
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| Veröffentlicht in: | Journal of polymer science. Part A, Polymer chemistry Polymer chemistry, 2004-02, Vol.42 (3), p.648-660 |
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| container_title | Journal of polymer science. Part A, Polymer chemistry |
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| creator | MATISOVA-RYCHLA, L RYCHLY, J |
| description | The chemiluminescence under isothermal and nonisothermal conditions accompanying the oxidation of some polymers (polyolefins, polyamides, and polysaccharides) has been examined from the viewpoint of its relationship with the rate of oxidation. The chemical structure of a given type of polymer plays a decisive role in the resulting shape of the chemiluminescence curves. In the presence of an antioxidant, the inhibition periods of oxidation are shifted to longer times and/or higher temperatures. This shift is directly proportional to the type and concentration of stabilizer. Attention has also been paid to the impact of the average molar mass on the oxidizability of the macromolecular material. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 648–660, 2004
The chemiluminescence under isothermal and nonisothermal conditions accompanying the oxidation of some polymers (polyolefins, polyamides, and polysaccharides) has been examined from the viewpoint of its relationship with the rate of oxidation. The position and applicability of the chemiluminescence method, among other approaches, to the investigation of polymer thermal oxidation is shown to the right. |
| doi_str_mv | 10.1002/pola.10847 |
| format | Article |
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The chemiluminescence under isothermal and nonisothermal conditions accompanying the oxidation of some polymers (polyolefins, polyamides, and polysaccharides) has been examined from the viewpoint of its relationship with the rate of oxidation. The position and applicability of the chemiluminescence method, among other approaches, to the investigation of polymer thermal oxidation is shown to the right.</description><identifier>ISSN: 0887-624X</identifier><identifier>EISSN: 1099-0518</identifier><identifier>DOI: 10.1002/pola.10847</identifier><identifier>CODEN: JPLCAT</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Applied sciences ; Chemical reactions and properties ; chemiluminescence ; Degradation ; Exact sciences and technology ; kinetics ; Organic polymers ; Physicochemistry of polymers ; polyamide-66 ; polyolefins ; pullulan ; thermooxidative stability</subject><ispartof>Journal of polymer science. Part A, Polymer chemistry, 2004-02, Vol.42 (3), p.648-660</ispartof><rights>Copyright © 2003 Wiley Periodicals, Inc.</rights><rights>2004 INIST-CNRS</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3727-aff1a790b09de32cf728903305b3bac1c2253e1ac1f89da3a8125ad51efad43d3</citedby><cites>FETCH-LOGICAL-c3727-aff1a790b09de32cf728903305b3bac1c2253e1ac1f89da3a8125ad51efad43d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fpola.10847$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fpola.10847$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>309,310,314,780,784,789,790,1417,23930,23931,25140,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=15477838$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>MATISOVA-RYCHLA, L</creatorcontrib><creatorcontrib>RYCHLY, J</creatorcontrib><title>Thermal oxidation of nonstabilized and stabilized polymers and chemiluminescence</title><title>Journal of polymer science. Part A, Polymer chemistry</title><addtitle>J. Polym. Sci. A Polym. Chem</addtitle><description>The chemiluminescence under isothermal and nonisothermal conditions accompanying the oxidation of some polymers (polyolefins, polyamides, and polysaccharides) has been examined from the viewpoint of its relationship with the rate of oxidation. The chemical structure of a given type of polymer plays a decisive role in the resulting shape of the chemiluminescence curves. In the presence of an antioxidant, the inhibition periods of oxidation are shifted to longer times and/or higher temperatures. This shift is directly proportional to the type and concentration of stabilizer. Attention has also been paid to the impact of the average molar mass on the oxidizability of the macromolecular material. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 648–660, 2004
The chemiluminescence under isothermal and nonisothermal conditions accompanying the oxidation of some polymers (polyolefins, polyamides, and polysaccharides) has been examined from the viewpoint of its relationship with the rate of oxidation. The position and applicability of the chemiluminescence method, among other approaches, to the investigation of polymer thermal oxidation is shown to the right.</description><subject>Applied sciences</subject><subject>Chemical reactions and properties</subject><subject>chemiluminescence</subject><subject>Degradation</subject><subject>Exact sciences and technology</subject><subject>kinetics</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>polyamide-66</subject><subject>polyolefins</subject><subject>pullulan</subject><subject>thermooxidative stability</subject><issn>0887-624X</issn><issn>1099-0518</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNp9kMtOwzAURC0EEqWw4QuygQVSwI-kdpYFQUFEtBJFsLNuHFs1OEmxW9Hy9aQPHitWHl-fmWsNQscEnxOM6cW0cdAqkfAd1CE4y2KcErGLOlgIHvdo8rKPDkJ4xbh9S0UHjcYT7StwUbOwJcxsU0eNieqmDjMorLOfuoygLqM_13bHstI-rOdqoivr5pWtdVC6VvoQ7RlwQR9tzy56urkeX93G-XBwd9XPY8U45TEYQ4BnuMBZqRlVhlORYcZwWrACFFGUpkyTVhmRlcBAEJpCmRJtoExYybrodJM79c37XIeZrGz7A-eg1s08SCqSBDOStODZBlS-CcFrI6feVuCXkmC5Kk2uSpPr0lr4ZJsKQYEzHmplw68jTTgXTLQc2XAf1unlP4lyNMz739nxxmPDTC9-PODfZI8znsrnh4G8x4-CXVIsc_YFhVKM4A</recordid><startdate>20040201</startdate><enddate>20040201</enddate><creator>MATISOVA-RYCHLA, L</creator><creator>RYCHLY, J</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SE</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20040201</creationdate><title>Thermal oxidation of nonstabilized and stabilized polymers and chemiluminescence</title><author>MATISOVA-RYCHLA, L ; RYCHLY, J</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3727-aff1a790b09de32cf728903305b3bac1c2253e1ac1f89da3a8125ad51efad43d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><topic>Applied sciences</topic><topic>Chemical reactions and properties</topic><topic>chemiluminescence</topic><topic>Degradation</topic><topic>Exact sciences and technology</topic><topic>kinetics</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>polyamide-66</topic><topic>polyolefins</topic><topic>pullulan</topic><topic>thermooxidative stability</topic><toplevel>online_resources</toplevel><creatorcontrib>MATISOVA-RYCHLA, L</creatorcontrib><creatorcontrib>RYCHLY, J</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Corrosion Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of polymer science. Part A, Polymer chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>MATISOVA-RYCHLA, L</au><au>RYCHLY, J</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thermal oxidation of nonstabilized and stabilized polymers and chemiluminescence</atitle><jtitle>Journal of polymer science. Part A, Polymer chemistry</jtitle><addtitle>J. Polym. Sci. A Polym. Chem</addtitle><date>2004-02-01</date><risdate>2004</risdate><volume>42</volume><issue>3</issue><spage>648</spage><epage>660</epage><pages>648-660</pages><issn>0887-624X</issn><eissn>1099-0518</eissn><coden>JPLCAT</coden><abstract>The chemiluminescence under isothermal and nonisothermal conditions accompanying the oxidation of some polymers (polyolefins, polyamides, and polysaccharides) has been examined from the viewpoint of its relationship with the rate of oxidation. The chemical structure of a given type of polymer plays a decisive role in the resulting shape of the chemiluminescence curves. In the presence of an antioxidant, the inhibition periods of oxidation are shifted to longer times and/or higher temperatures. This shift is directly proportional to the type and concentration of stabilizer. Attention has also been paid to the impact of the average molar mass on the oxidizability of the macromolecular material. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 648–660, 2004
The chemiluminescence under isothermal and nonisothermal conditions accompanying the oxidation of some polymers (polyolefins, polyamides, and polysaccharides) has been examined from the viewpoint of its relationship with the rate of oxidation. The position and applicability of the chemiluminescence method, among other approaches, to the investigation of polymer thermal oxidation is shown to the right.</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/pola.10847</doi><tpages>13</tpages></addata></record> |
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| issn | 0887-624X 1099-0518 |
| language | eng |
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| source | Wiley Journals |
| subjects | Applied sciences Chemical reactions and properties chemiluminescence Degradation Exact sciences and technology kinetics Organic polymers Physicochemistry of polymers polyamide-66 polyolefins pullulan thermooxidative stability |
| title | Thermal oxidation of nonstabilized and stabilized polymers and chemiluminescence |
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