Selective adsorption of dihydrogen isotopes on DUT-8 (Ni,Co) monitored by in situ electron paramagnetic resonance
continuous wave electron paramagnetic resonance investigation has been proven as a powerful method by employing paramagnetic Ni -Co pairs as spin probes to follow the isotope-selective gate opening phenomenon on the DUT-8(Ni Co ) framework. This method is very sensitive to detect the phase transitio...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2023-08, Vol.59 (65), p.9884-9887 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Lukman, Muhammad Fernadi Mendt, Matthias Bon, Volodymyr Kaskel, Stefan Pöppl, Andreas |
| description | continuous wave electron paramagnetic resonance investigation has been proven as a powerful method by employing paramagnetic Ni
-Co
pairs as spin probes to follow the isotope-selective gate opening phenomenon on the DUT-8(Ni
Co
) framework. This method is very sensitive to detect the phase transition from the closed pore to the open pore phase in response to D
adsorption in the framework, while no phase transformation has been observed during H
gas adsorption. More interestingly, it is also able to sense local structural changes around the spin probe during the desorption of D
gas. Based on these evidences, the
continuous wave electron paramagnetic resonance method can be implemented as an efficient and non-invasive technique for the detection of dihydrogen isotopes. |
| doi_str_mv | 10.1039/d3cc02938g |
| format | Article |
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-Co
pairs as spin probes to follow the isotope-selective gate opening phenomenon on the DUT-8(Ni
Co
) framework. This method is very sensitive to detect the phase transition from the closed pore to the open pore phase in response to D
adsorption in the framework, while no phase transformation has been observed during H
gas adsorption. More interestingly, it is also able to sense local structural changes around the spin probe during the desorption of D
gas. Based on these evidences, the
continuous wave electron paramagnetic resonance method can be implemented as an efficient and non-invasive technique for the detection of dihydrogen isotopes.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/d3cc02938g</identifier><identifier>PMID: 37493059</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Cobalt ; Continuous radiation ; Electron paramagnetic resonance ; Isotopes ; Phase transitions ; Selective adsorption</subject><ispartof>Chemical communications (Cambridge, England), 2023-08, Vol.59 (65), p.9884-9887</ispartof><rights>Copyright Royal Society of Chemistry 2023</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c310t-37ff0abf27e4f8c3ebad0d190191d1589e2fd17d49aaa2daf6eb97a6e395b20b3</cites><orcidid>0000-0003-2354-2542 ; 0000-0002-9851-5031 ; 0000-0002-2921-2635</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/37493059$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Lukman, Muhammad Fernadi</creatorcontrib><creatorcontrib>Mendt, Matthias</creatorcontrib><creatorcontrib>Bon, Volodymyr</creatorcontrib><creatorcontrib>Kaskel, Stefan</creatorcontrib><creatorcontrib>Pöppl, Andreas</creatorcontrib><title>Selective adsorption of dihydrogen isotopes on DUT-8 (Ni,Co) monitored by in situ electron paramagnetic resonance</title><title>Chemical communications (Cambridge, England)</title><addtitle>Chem Commun (Camb)</addtitle><description>continuous wave electron paramagnetic resonance investigation has been proven as a powerful method by employing paramagnetic Ni
-Co
pairs as spin probes to follow the isotope-selective gate opening phenomenon on the DUT-8(Ni
Co
) framework. This method is very sensitive to detect the phase transition from the closed pore to the open pore phase in response to D
adsorption in the framework, while no phase transformation has been observed during H
gas adsorption. More interestingly, it is also able to sense local structural changes around the spin probe during the desorption of D
gas. Based on these evidences, the
continuous wave electron paramagnetic resonance method can be implemented as an efficient and non-invasive technique for the detection of dihydrogen isotopes.</description><subject>Cobalt</subject><subject>Continuous radiation</subject><subject>Electron paramagnetic resonance</subject><subject>Isotopes</subject><subject>Phase transitions</subject><subject>Selective adsorption</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNpd0ctKxDAUBuAgiuNt4wNIwM0oVpOmnTZLqVcQXajgrqTJyRiZJp2kFebtzVx0YTYJ5OPnXBA6puSSEsavFJOSpJyV0y20R9kkS_Ks_NhevnOeFCzLR2g_hC8SD83LXTRiRcYZyfkemr_CDGRvvgELFZzveuMsdhor87lQ3k3BYhNc7zoIOP7cvL8lJR4_m4vKneHWWdM7Dwo3C2wsDqYf8CrQR9sJL1oxtdAbiT0EZ4WVcIh2tJgFONrcB-j97vatekieXu4fq-unRDJK-oQVWhPR6LSATJeSQSMUUZQTyqmKXXBItaKFyrgQIlVCT6DhhZgA43mTkoYdoPE6t_NuPkDo69YECbOZsOCGUKdllmZ5WtAi0tN_9MsN3sbqlio6NiFlVOdrJb0LwYOuO29a4Rc1JfVyEfUNq6rVIu4jPtlEDk0L6o_-Tp79AEE3hCM</recordid><startdate>20230810</startdate><enddate>20230810</enddate><creator>Lukman, Muhammad Fernadi</creator><creator>Mendt, Matthias</creator><creator>Bon, Volodymyr</creator><creator>Kaskel, Stefan</creator><creator>Pöppl, Andreas</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-2354-2542</orcidid><orcidid>https://orcid.org/0000-0002-9851-5031</orcidid><orcidid>https://orcid.org/0000-0002-2921-2635</orcidid></search><sort><creationdate>20230810</creationdate><title>Selective adsorption of dihydrogen isotopes on DUT-8 (Ni,Co) monitored by in situ electron paramagnetic resonance</title><author>Lukman, Muhammad Fernadi ; Mendt, Matthias ; Bon, Volodymyr ; Kaskel, Stefan ; Pöppl, Andreas</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c310t-37ff0abf27e4f8c3ebad0d190191d1589e2fd17d49aaa2daf6eb97a6e395b20b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Cobalt</topic><topic>Continuous radiation</topic><topic>Electron paramagnetic resonance</topic><topic>Isotopes</topic><topic>Phase transitions</topic><topic>Selective adsorption</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lukman, Muhammad Fernadi</creatorcontrib><creatorcontrib>Mendt, Matthias</creatorcontrib><creatorcontrib>Bon, Volodymyr</creatorcontrib><creatorcontrib>Kaskel, Stefan</creatorcontrib><creatorcontrib>Pöppl, Andreas</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lukman, Muhammad Fernadi</au><au>Mendt, Matthias</au><au>Bon, Volodymyr</au><au>Kaskel, Stefan</au><au>Pöppl, Andreas</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Selective adsorption of dihydrogen isotopes on DUT-8 (Ni,Co) monitored by in situ electron paramagnetic resonance</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2023-08-10</date><risdate>2023</risdate><volume>59</volume><issue>65</issue><spage>9884</spage><epage>9887</epage><pages>9884-9887</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>continuous wave electron paramagnetic resonance investigation has been proven as a powerful method by employing paramagnetic Ni
-Co
pairs as spin probes to follow the isotope-selective gate opening phenomenon on the DUT-8(Ni
Co
) framework. This method is very sensitive to detect the phase transition from the closed pore to the open pore phase in response to D
adsorption in the framework, while no phase transformation has been observed during H
gas adsorption. More interestingly, it is also able to sense local structural changes around the spin probe during the desorption of D
gas. Based on these evidences, the
continuous wave electron paramagnetic resonance method can be implemented as an efficient and non-invasive technique for the detection of dihydrogen isotopes.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>37493059</pmid><doi>10.1039/d3cc02938g</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0003-2354-2542</orcidid><orcidid>https://orcid.org/0000-0002-9851-5031</orcidid><orcidid>https://orcid.org/0000-0002-2921-2635</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2023-08, Vol.59 (65), p.9884-9887 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_proquest_miscellaneous_2842452717 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Cobalt Continuous radiation Electron paramagnetic resonance Isotopes Phase transitions Selective adsorption |
| title | Selective adsorption of dihydrogen isotopes on DUT-8 (Ni,Co) monitored by in situ electron paramagnetic resonance |
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