Synthesis and characterization of poly(terphenylenevinylene) derivatives containing alkoxy substituents and (or) phenyl pendant group
The blue electroluminescent polymers, poly(terphenylenevinylene) derivatives that have advantages of PPP and PPV, were prepared by Suzuki coupling reaction. The structure and properties of the polymers were analyzed by various spectroscopic methods. Poly(MHTPPV) and poly(TPPV) with phenyl pendant gr...
Gespeichert in:
| Veröffentlicht in: | Polymer (Guilford) 2004-04, Vol.45 (8), p.2525-2532 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 2532 |
|---|---|
| container_issue | 8 |
| container_start_page | 2525 |
| container_title | Polymer (Guilford) |
| container_volume | 45 |
| creator | Kim, Yun-Hi Ahn, Jun-Hwan Shin, Dong-Cheol Kwon, Soon-Ki |
| description | The blue electroluminescent polymers, poly(terphenylenevinylene) derivatives that have advantages of PPP and PPV, were prepared by Suzuki coupling reaction. The structure and properties of the polymers were analyzed by various spectroscopic methods. Poly(MHTPPV) and poly(TPPV) with phenyl pendant group in a vinyl bridge showed blue shifted absorption spectra, large band gap and enhanced thermal stability as compared with that of poly(MHTPV). The PL spectra of the films of the polymers showed maximum peaks at 450–460 nm, which are pure blue emissions. The blue electroluminescence
(λ
max
=450–460
nm)
was obtained with the turn on voltage of 8–10 V, when the simple light-emitting diodes of ITO/polymer/Al were fabricated. The excimer emission due to interchain interaction was reduced by the introduction of substituents into the vinyl bridge and (or) the main chain. |
| doi_str_mv | 10.1016/j.polymer.2004.02.032 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_28420449</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0032386104001570</els_id><sourcerecordid>28420449</sourcerecordid><originalsourceid>FETCH-LOGICAL-c399t-d01c871430570e2bbb6adc764f2d1a5872fa69f21514662490ff3df7777d34633</originalsourceid><addsrcrecordid>eNqNkc1q3DAUhU1podOkj1DQpiVZ2NGfZXtVSugfBLJouxYa6SqjqUdyJXmIs-97V4MHumy1uXD57ndAp6reENwQTMTNvpnCuBwgNhRj3mDaYEafVRvSd6ymdCDPqw0uq5r1grysXqW0xxjTlvJN9fvb4vMOkktIeYP0TkWlM0T3pLILHgWLTvKrspp24JcRPBzdOq-RKeCxgEdISAeflfPOPyA1_gyPC0rzNmWXZ_B5tV-FeI1WDZrAG-Uzeohhni6rF1aNCV6f50X149PH77df6rv7z19vP9zVmg1Drg0muu8IZ7jtMNDtdiuU0Z3glhqi2r6jVonBUtISLgTlA7aWGduVZxgXjF1U71bvFMOvGVKWB5c0jKPyEOYkac8p5nz4H7BEtLyA7QrqGFKKYOUU3UHFRRIsT-3IvTy3I0_tSExlqaLcvT0HqKTVaKPy2qW_x60gtKO4cO9XDsq3HF2xJO3AazAugs7SBPePpD_E0Kun</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>28414654</pqid></control><display><type>article</type><title>Synthesis and characterization of poly(terphenylenevinylene) derivatives containing alkoxy substituents and (or) phenyl pendant group</title><source>Elsevier ScienceDirect Journals Complete</source><creator>Kim, Yun-Hi ; Ahn, Jun-Hwan ; Shin, Dong-Cheol ; Kwon, Soon-Ki</creator><creatorcontrib>Kim, Yun-Hi ; Ahn, Jun-Hwan ; Shin, Dong-Cheol ; Kwon, Soon-Ki</creatorcontrib><description>The blue electroluminescent polymers, poly(terphenylenevinylene) derivatives that have advantages of PPP and PPV, were prepared by Suzuki coupling reaction. The structure and properties of the polymers were analyzed by various spectroscopic methods. Poly(MHTPPV) and poly(TPPV) with phenyl pendant group in a vinyl bridge showed blue shifted absorption spectra, large band gap and enhanced thermal stability as compared with that of poly(MHTPV). The PL spectra of the films of the polymers showed maximum peaks at 450–460 nm, which are pure blue emissions. The blue electroluminescence
(λ
max
=450–460
nm)
was obtained with the turn on voltage of 8–10 V, when the simple light-emitting diodes of ITO/polymer/Al were fabricated. The excimer emission due to interchain interaction was reduced by the introduction of substituents into the vinyl bridge and (or) the main chain.</description><identifier>ISSN: 0032-3861</identifier><identifier>EISSN: 1873-2291</identifier><identifier>DOI: 10.1016/j.polymer.2004.02.032</identifier><identifier>CODEN: POLMAG</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>Applied sciences ; Electroluminescence ; Exact sciences and technology ; Light emitting diode ; Organic polymers ; Physicochemistry of polymers ; Poly(terphenylenevinylene) ; Polymers with particular properties ; Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><ispartof>Polymer (Guilford), 2004-04, Vol.45 (8), p.2525-2532</ispartof><rights>2004 Elsevier Ltd</rights><rights>2004 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c399t-d01c871430570e2bbb6adc764f2d1a5872fa69f21514662490ff3df7777d34633</citedby><cites>FETCH-LOGICAL-c399t-d01c871430570e2bbb6adc764f2d1a5872fa69f21514662490ff3df7777d34633</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0032386104001570$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=15612720$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Kim, Yun-Hi</creatorcontrib><creatorcontrib>Ahn, Jun-Hwan</creatorcontrib><creatorcontrib>Shin, Dong-Cheol</creatorcontrib><creatorcontrib>Kwon, Soon-Ki</creatorcontrib><title>Synthesis and characterization of poly(terphenylenevinylene) derivatives containing alkoxy substituents and (or) phenyl pendant group</title><title>Polymer (Guilford)</title><description>The blue electroluminescent polymers, poly(terphenylenevinylene) derivatives that have advantages of PPP and PPV, were prepared by Suzuki coupling reaction. The structure and properties of the polymers were analyzed by various spectroscopic methods. Poly(MHTPPV) and poly(TPPV) with phenyl pendant group in a vinyl bridge showed blue shifted absorption spectra, large band gap and enhanced thermal stability as compared with that of poly(MHTPV). The PL spectra of the films of the polymers showed maximum peaks at 450–460 nm, which are pure blue emissions. The blue electroluminescence
(λ
max
=450–460
nm)
was obtained with the turn on voltage of 8–10 V, when the simple light-emitting diodes of ITO/polymer/Al were fabricated. The excimer emission due to interchain interaction was reduced by the introduction of substituents into the vinyl bridge and (or) the main chain.</description><subject>Applied sciences</subject><subject>Electroluminescence</subject><subject>Exact sciences and technology</subject><subject>Light emitting diode</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Poly(terphenylenevinylene)</subject><subject>Polymers with particular properties</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><issn>0032-3861</issn><issn>1873-2291</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNqNkc1q3DAUhU1podOkj1DQpiVZ2NGfZXtVSugfBLJouxYa6SqjqUdyJXmIs-97V4MHumy1uXD57ndAp6reENwQTMTNvpnCuBwgNhRj3mDaYEafVRvSd6ymdCDPqw0uq5r1grysXqW0xxjTlvJN9fvb4vMOkktIeYP0TkWlM0T3pLILHgWLTvKrspp24JcRPBzdOq-RKeCxgEdISAeflfPOPyA1_gyPC0rzNmWXZ_B5tV-FeI1WDZrAG-Uzeohhni6rF1aNCV6f50X149PH77df6rv7z19vP9zVmg1Drg0muu8IZ7jtMNDtdiuU0Z3glhqi2r6jVonBUtISLgTlA7aWGduVZxgXjF1U71bvFMOvGVKWB5c0jKPyEOYkac8p5nz4H7BEtLyA7QrqGFKKYOUU3UHFRRIsT-3IvTy3I0_tSExlqaLcvT0HqKTVaKPy2qW_x60gtKO4cO9XDsq3HF2xJO3AazAugs7SBPePpD_E0Kun</recordid><startdate>20040413</startdate><enddate>20040413</enddate><creator>Kim, Yun-Hi</creator><creator>Ahn, Jun-Hwan</creator><creator>Shin, Dong-Cheol</creator><creator>Kwon, Soon-Ki</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>7SR</scope><scope>JG9</scope></search><sort><creationdate>20040413</creationdate><title>Synthesis and characterization of poly(terphenylenevinylene) derivatives containing alkoxy substituents and (or) phenyl pendant group</title><author>Kim, Yun-Hi ; Ahn, Jun-Hwan ; Shin, Dong-Cheol ; Kwon, Soon-Ki</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c399t-d01c871430570e2bbb6adc764f2d1a5872fa69f21514662490ff3df7777d34633</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><topic>Applied sciences</topic><topic>Electroluminescence</topic><topic>Exact sciences and technology</topic><topic>Light emitting diode</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Poly(terphenylenevinylene)</topic><topic>Polymers with particular properties</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kim, Yun-Hi</creatorcontrib><creatorcontrib>Ahn, Jun-Hwan</creatorcontrib><creatorcontrib>Shin, Dong-Cheol</creatorcontrib><creatorcontrib>Kwon, Soon-Ki</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Engineered Materials Abstracts</collection><collection>Materials Research Database</collection><jtitle>Polymer (Guilford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kim, Yun-Hi</au><au>Ahn, Jun-Hwan</au><au>Shin, Dong-Cheol</au><au>Kwon, Soon-Ki</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and characterization of poly(terphenylenevinylene) derivatives containing alkoxy substituents and (or) phenyl pendant group</atitle><jtitle>Polymer (Guilford)</jtitle><date>2004-04-13</date><risdate>2004</risdate><volume>45</volume><issue>8</issue><spage>2525</spage><epage>2532</epage><pages>2525-2532</pages><issn>0032-3861</issn><eissn>1873-2291</eissn><coden>POLMAG</coden><abstract>The blue electroluminescent polymers, poly(terphenylenevinylene) derivatives that have advantages of PPP and PPV, were prepared by Suzuki coupling reaction. The structure and properties of the polymers were analyzed by various spectroscopic methods. Poly(MHTPPV) and poly(TPPV) with phenyl pendant group in a vinyl bridge showed blue shifted absorption spectra, large band gap and enhanced thermal stability as compared with that of poly(MHTPV). The PL spectra of the films of the polymers showed maximum peaks at 450–460 nm, which are pure blue emissions. The blue electroluminescence
(λ
max
=450–460
nm)
was obtained with the turn on voltage of 8–10 V, when the simple light-emitting diodes of ITO/polymer/Al were fabricated. The excimer emission due to interchain interaction was reduced by the introduction of substituents into the vinyl bridge and (or) the main chain.</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.polymer.2004.02.032</doi><tpages>8</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0032-3861 |
| ispartof | Polymer (Guilford), 2004-04, Vol.45 (8), p.2525-2532 |
| issn | 0032-3861 1873-2291 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_28420449 |
| source | Elsevier ScienceDirect Journals Complete |
| subjects | Applied sciences Electroluminescence Exact sciences and technology Light emitting diode Organic polymers Physicochemistry of polymers Poly(terphenylenevinylene) Polymers with particular properties Preparation, kinetics, thermodynamics, mechanism and catalysts |
| title | Synthesis and characterization of poly(terphenylenevinylene) derivatives containing alkoxy substituents and (or) phenyl pendant group |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-07T16%3A29%3A02IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20and%20characterization%20of%20poly(terphenylenevinylene)%20derivatives%20containing%20alkoxy%20substituents%20and%20(or)%20phenyl%20pendant%20group&rft.jtitle=Polymer%20(Guilford)&rft.au=Kim,%20Yun-Hi&rft.date=2004-04-13&rft.volume=45&rft.issue=8&rft.spage=2525&rft.epage=2532&rft.pages=2525-2532&rft.issn=0032-3861&rft.eissn=1873-2291&rft.coden=POLMAG&rft_id=info:doi/10.1016/j.polymer.2004.02.032&rft_dat=%3Cproquest_cross%3E28420449%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=28414654&rft_id=info:pmid/&rft_els_id=S0032386104001570&rfr_iscdi=true |