Halogen-modified metal-organic frameworks for efficient separation of alkane from natural gas
As a rich green energy source, natural gas is widely used in many fields such as the chemical industry, automobile energy, and daily life. However, it is very challenging to separate and recover C 2 H 6 and C 3 H 8 from natural gas. Metal-organic frameworks (MOFs) as an emerging type of multi-pore p...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2023-10, Vol.52 (42), p.15462-15466 |
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| container_title | Dalton transactions : an international journal of inorganic chemistry |
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| creator | Song, Zhirong Zheng, Yanchun Chen, Yiqi Cai, Youlie Wei, Rong-Jia Gao, Junkuo |
| description | As a rich green energy source, natural gas is widely used in many fields such as the chemical industry, automobile energy, and daily life. However, it is very challenging to separate and recover C
2
H
6
and C
3
H
8
from natural gas. Metal-organic frameworks (MOFs) as an emerging type of multi-pore porous materials show huge potential in gas adsorption separation. Herein, we report pillar-layered MOFs, Ni (BDC)(DABCO)
0.5
(DMOF-X), modified by halogen atoms (F, Cl, Br), and investigate their CH
4
/C
2
H
6
/C
3
H
8
separation performance. The experimental results show that DMOF-Cl exhibited a extremely high adsorption capacity for C
3
H
8
and C
2
H
6
. Under the conditions of 298 K and 100 kPa, the adsorption capacities for C
3
H
8
and C
2
H
6
on DMOF-Cl are as high as 6.23 and 4.94 mmol g
−1
, which are superior to the values for most of the porous materials that have been reported. In addition, DMOF-Cl also shows high C
3
H
8
/CH
4
(5: 85, V/V) and C
2
H
6
/CH
4
(10: 85, V/V) separation selectivities, with values of 130.9 and 12.5, respectively. Finally, DMOF-Cl also demonstrated great potential as an adsorbent for separating C
3
H
8
/C
2
H
6
/CH
4
.
Pillar-layered MOFs, Ni (BDC)(DABCO)
0.5
(DMOF-X), modified by halogen atoms (F, Cl, Br), were investigated for CH
4
/C
2
H
6
/C
3
H
8
separation performance. DMOF-Cl demonstrated great potential as an adsorbent for the efficient separation of C
3
H
8
and C
2
H
6
from CH
4
. |
| doi_str_mv | 10.1039/d3dt01554h |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_proquest_miscellaneous_2841023092</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2884078755</sourcerecordid><originalsourceid>FETCH-LOGICAL-c337t-b07533c0876e921a3ca8b7f8e76a83651ef5d96a1c2775cbcfe896c38ce2b1623</originalsourceid><addsrcrecordid>eNpd0UtLxDAQB_Agiu-LdyXgRYRqHk2THmV9rLDgZT1KmaaTtdo2a9Iifnurqyt4moH5MQz_IeSIswvOZH5ZyapnXKn0eYPs8lTrJBcy3Vz3ItshezG-MCYEU2Kb7Eg9TmQudsnTFBq_wC5pfVW7GivaYg9N4sMCutpSF6DFdx9eI3U-UHSutjV2PY24hAB97TvqHYXmFToctW9pB_0QoKELiAdky0ET8fCn7pPH25v5ZJrMHu7uJ1ezxEqp-6RkWklpmdEZ5oKDtGBK7QzqDIzMFEenqjwDboXWypbWockzK41FUfJMyH1yttq7DP5twNgXbR0tNs14lB9iIUzKmZAs_6Kn_-iLH0I3XjcqkzJttFKjOl8pG3yMAV2xDHUL4aPgrPgKvbiW1_Pv0KcjPvlZOZQtVmv6m_IIjlcgRLue_n1NfgISHIZ4</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2884078755</pqid></control><display><type>article</type><title>Halogen-modified metal-organic frameworks for efficient separation of alkane from natural gas</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Song, Zhirong ; Zheng, Yanchun ; Chen, Yiqi ; Cai, Youlie ; Wei, Rong-Jia ; Gao, Junkuo</creator><creatorcontrib>Song, Zhirong ; Zheng, Yanchun ; Chen, Yiqi ; Cai, Youlie ; Wei, Rong-Jia ; Gao, Junkuo</creatorcontrib><description>As a rich green energy source, natural gas is widely used in many fields such as the chemical industry, automobile energy, and daily life. However, it is very challenging to separate and recover C
2
H
6
and C
3
H
8
from natural gas. Metal-organic frameworks (MOFs) as an emerging type of multi-pore porous materials show huge potential in gas adsorption separation. Herein, we report pillar-layered MOFs, Ni (BDC)(DABCO)
0.5
(DMOF-X), modified by halogen atoms (F, Cl, Br), and investigate their CH
4
/C
2
H
6
/C
3
H
8
separation performance. The experimental results show that DMOF-Cl exhibited a extremely high adsorption capacity for C
3
H
8
and C
2
H
6
. Under the conditions of 298 K and 100 kPa, the adsorption capacities for C
3
H
8
and C
2
H
6
on DMOF-Cl are as high as 6.23 and 4.94 mmol g
−1
, which are superior to the values for most of the porous materials that have been reported. In addition, DMOF-Cl also shows high C
3
H
8
/CH
4
(5: 85, V/V) and C
2
H
6
/CH
4
(10: 85, V/V) separation selectivities, with values of 130.9 and 12.5, respectively. Finally, DMOF-Cl also demonstrated great potential as an adsorbent for separating C
3
H
8
/C
2
H
6
/CH
4
.
Pillar-layered MOFs, Ni (BDC)(DABCO)
0.5
(DMOF-X), modified by halogen atoms (F, Cl, Br), were investigated for CH
4
/C
2
H
6
/C
3
H
8
separation performance. DMOF-Cl demonstrated great potential as an adsorbent for the efficient separation of C
3
H
8
and C
2
H
6
from CH
4
.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/d3dt01554h</identifier><identifier>PMID: 37477392</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Adsorption ; Alkanes ; Chemical industry ; Clean energy ; Metal-organic frameworks ; Methane ; Natural gas ; Porous materials ; Separation</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2023-10, Vol.52 (42), p.15462-15466</ispartof><rights>Copyright Royal Society of Chemistry 2023</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c337t-b07533c0876e921a3ca8b7f8e76a83651ef5d96a1c2775cbcfe896c38ce2b1623</citedby><cites>FETCH-LOGICAL-c337t-b07533c0876e921a3ca8b7f8e76a83651ef5d96a1c2775cbcfe896c38ce2b1623</cites><orcidid>0009-0008-1808-0500 ; 0000-0003-3092-1452 ; 0000-0001-9778-4312</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/37477392$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Song, Zhirong</creatorcontrib><creatorcontrib>Zheng, Yanchun</creatorcontrib><creatorcontrib>Chen, Yiqi</creatorcontrib><creatorcontrib>Cai, Youlie</creatorcontrib><creatorcontrib>Wei, Rong-Jia</creatorcontrib><creatorcontrib>Gao, Junkuo</creatorcontrib><title>Halogen-modified metal-organic frameworks for efficient separation of alkane from natural gas</title><title>Dalton transactions : an international journal of inorganic chemistry</title><addtitle>Dalton Trans</addtitle><description>As a rich green energy source, natural gas is widely used in many fields such as the chemical industry, automobile energy, and daily life. However, it is very challenging to separate and recover C
2
H
6
and C
3
H
8
from natural gas. Metal-organic frameworks (MOFs) as an emerging type of multi-pore porous materials show huge potential in gas adsorption separation. Herein, we report pillar-layered MOFs, Ni (BDC)(DABCO)
0.5
(DMOF-X), modified by halogen atoms (F, Cl, Br), and investigate their CH
4
/C
2
H
6
/C
3
H
8
separation performance. The experimental results show that DMOF-Cl exhibited a extremely high adsorption capacity for C
3
H
8
and C
2
H
6
. Under the conditions of 298 K and 100 kPa, the adsorption capacities for C
3
H
8
and C
2
H
6
on DMOF-Cl are as high as 6.23 and 4.94 mmol g
−1
, which are superior to the values for most of the porous materials that have been reported. In addition, DMOF-Cl also shows high C
3
H
8
/CH
4
(5: 85, V/V) and C
2
H
6
/CH
4
(10: 85, V/V) separation selectivities, with values of 130.9 and 12.5, respectively. Finally, DMOF-Cl also demonstrated great potential as an adsorbent for separating C
3
H
8
/C
2
H
6
/CH
4
.
Pillar-layered MOFs, Ni (BDC)(DABCO)
0.5
(DMOF-X), modified by halogen atoms (F, Cl, Br), were investigated for CH
4
/C
2
H
6
/C
3
H
8
separation performance. DMOF-Cl demonstrated great potential as an adsorbent for the efficient separation of C
3
H
8
and C
2
H
6
from CH
4
.</description><subject>Adsorption</subject><subject>Alkanes</subject><subject>Chemical industry</subject><subject>Clean energy</subject><subject>Metal-organic frameworks</subject><subject>Methane</subject><subject>Natural gas</subject><subject>Porous materials</subject><subject>Separation</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNpd0UtLxDAQB_Agiu-LdyXgRYRqHk2THmV9rLDgZT1KmaaTtdo2a9Iifnurqyt4moH5MQz_IeSIswvOZH5ZyapnXKn0eYPs8lTrJBcy3Vz3ItshezG-MCYEU2Kb7Eg9TmQudsnTFBq_wC5pfVW7GivaYg9N4sMCutpSF6DFdx9eI3U-UHSutjV2PY24hAB97TvqHYXmFToctW9pB_0QoKELiAdky0ET8fCn7pPH25v5ZJrMHu7uJ1ezxEqp-6RkWklpmdEZ5oKDtGBK7QzqDIzMFEenqjwDboXWypbWockzK41FUfJMyH1yttq7DP5twNgXbR0tNs14lB9iIUzKmZAs_6Kn_-iLH0I3XjcqkzJttFKjOl8pG3yMAV2xDHUL4aPgrPgKvbiW1_Pv0KcjPvlZOZQtVmv6m_IIjlcgRLue_n1NfgISHIZ4</recordid><startdate>20231031</startdate><enddate>20231031</enddate><creator>Song, Zhirong</creator><creator>Zheng, Yanchun</creator><creator>Chen, Yiqi</creator><creator>Cai, Youlie</creator><creator>Wei, Rong-Jia</creator><creator>Gao, Junkuo</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0009-0008-1808-0500</orcidid><orcidid>https://orcid.org/0000-0003-3092-1452</orcidid><orcidid>https://orcid.org/0000-0001-9778-4312</orcidid></search><sort><creationdate>20231031</creationdate><title>Halogen-modified metal-organic frameworks for efficient separation of alkane from natural gas</title><author>Song, Zhirong ; Zheng, Yanchun ; Chen, Yiqi ; Cai, Youlie ; Wei, Rong-Jia ; Gao, Junkuo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c337t-b07533c0876e921a3ca8b7f8e76a83651ef5d96a1c2775cbcfe896c38ce2b1623</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Adsorption</topic><topic>Alkanes</topic><topic>Chemical industry</topic><topic>Clean energy</topic><topic>Metal-organic frameworks</topic><topic>Methane</topic><topic>Natural gas</topic><topic>Porous materials</topic><topic>Separation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Song, Zhirong</creatorcontrib><creatorcontrib>Zheng, Yanchun</creatorcontrib><creatorcontrib>Chen, Yiqi</creatorcontrib><creatorcontrib>Cai, Youlie</creatorcontrib><creatorcontrib>Wei, Rong-Jia</creatorcontrib><creatorcontrib>Gao, Junkuo</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Song, Zhirong</au><au>Zheng, Yanchun</au><au>Chen, Yiqi</au><au>Cai, Youlie</au><au>Wei, Rong-Jia</au><au>Gao, Junkuo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Halogen-modified metal-organic frameworks for efficient separation of alkane from natural gas</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><addtitle>Dalton Trans</addtitle><date>2023-10-31</date><risdate>2023</risdate><volume>52</volume><issue>42</issue><spage>15462</spage><epage>15466</epage><pages>15462-15466</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>As a rich green energy source, natural gas is widely used in many fields such as the chemical industry, automobile energy, and daily life. However, it is very challenging to separate and recover C
2
H
6
and C
3
H
8
from natural gas. Metal-organic frameworks (MOFs) as an emerging type of multi-pore porous materials show huge potential in gas adsorption separation. Herein, we report pillar-layered MOFs, Ni (BDC)(DABCO)
0.5
(DMOF-X), modified by halogen atoms (F, Cl, Br), and investigate their CH
4
/C
2
H
6
/C
3
H
8
separation performance. The experimental results show that DMOF-Cl exhibited a extremely high adsorption capacity for C
3
H
8
and C
2
H
6
. Under the conditions of 298 K and 100 kPa, the adsorption capacities for C
3
H
8
and C
2
H
6
on DMOF-Cl are as high as 6.23 and 4.94 mmol g
−1
, which are superior to the values for most of the porous materials that have been reported. In addition, DMOF-Cl also shows high C
3
H
8
/CH
4
(5: 85, V/V) and C
2
H
6
/CH
4
(10: 85, V/V) separation selectivities, with values of 130.9 and 12.5, respectively. Finally, DMOF-Cl also demonstrated great potential as an adsorbent for separating C
3
H
8
/C
2
H
6
/CH
4
.
Pillar-layered MOFs, Ni (BDC)(DABCO)
0.5
(DMOF-X), modified by halogen atoms (F, Cl, Br), were investigated for CH
4
/C
2
H
6
/C
3
H
8
separation performance. DMOF-Cl demonstrated great potential as an adsorbent for the efficient separation of C
3
H
8
and C
2
H
6
from CH
4
.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>37477392</pmid><doi>10.1039/d3dt01554h</doi><tpages>5</tpages><orcidid>https://orcid.org/0009-0008-1808-0500</orcidid><orcidid>https://orcid.org/0000-0003-3092-1452</orcidid><orcidid>https://orcid.org/0000-0001-9778-4312</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2023-10, Vol.52 (42), p.15462-15466 |
| issn | 1477-9226 1477-9234 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_2841023092 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Adsorption Alkanes Chemical industry Clean energy Metal-organic frameworks Methane Natural gas Porous materials Separation |
| title | Halogen-modified metal-organic frameworks for efficient separation of alkane from natural gas |
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