Asymmetric Intramolecular Hydroalkylation of Internal Olefin with Cycloalkanone to Directly Access Polycyclic Systems

An asymmetric intramolecular hydroalkylation of unactivated internal olefins with tethered cyclic ketones was realized by the cooperative catalysis of a newly designed chiral amine (SPD‐NH2) and PdII complex, providing straightforward access to either bridged or fused bicyclic systems containing thr...

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Veröffentlicht in:	Angewandte Chemie International Edition 2023-09, Vol.62 (39), p.e202308858-n/a
Hauptverfasser:	Wang, Ai‐Fang, Tian, Jin‐Miao, Zhao, Xiao‐Jing, Li, Zi‐Hao, Zhang, Ye, Lu, Ka, Wang, Hong, Zhang, Shu‐Yu, Tu, Yong‐Qiang, Ding, Tong‐Mei, Xie, Yu‐Yang
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes Asymmetry Catalysis Catalysts Chain branching Cooperative Catalysis Density functional theory Enantiomers Hydroalkylation Ketones Polycyclic Systems SPD-NH2 Stereoselectivity Steric hindrance Substrates Terpenes Unactivated Olefins
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