Stereoselective Construction of Acyclic β,β-Disubstituted Enesulfinamides via Conjugate Addition of Organocuprates to α‑Substituted α,β-Unsaturated N‑Sulfinyl Ketimines

In the presence of boron trifluoride, conjugate addition of organocuprates to α-substituted α,β-unsaturated N-tert-butanesulfinyl ketimines provides facile access to acyclic β,β-disubstituted enesulfinamides with high ratios of geometric isomers. Diverse and challenging to synthesize, multisubstitut...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Organic letters 2023-07, Vol.25 (29), p.5536-5541
Hauptverfasser:	Yisimayili, Nuermaimaiti, Zhu, Chong-Lin, Liu, Tao, Yao, Yun, Lu, Chong-Dao
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!