Synthesis and characterization of poly(o- and m-amino benzyl amine) and the copolymers with aniline. Study with Cu(II)
Poly(o‐amino benzyl amine), poly(m‐amino benzyl amine), and the copolymers with aniline were synthesized in 10−4M HCl by using ammonium persulfate as oxidizing agent. The copolymers were synthesized at various feed mole fractions of comonomer diamine and characterized by elemental analysis, FTIR, 1H...
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| Veröffentlicht in: | Journal of applied polymer science 2004-04, Vol.92 (1), p.31-36 |
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| container_title | Journal of applied polymer science |
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| creator | Rivas, Bernabé L. Sánchez, Christian O. |
| description | Poly(o‐amino benzyl amine), poly(m‐amino benzyl amine), and the copolymers with aniline were synthesized in 10−4M HCl by using ammonium persulfate as oxidizing agent. The copolymers were synthesized at various feed mole fractions of comonomer diamine and characterized by elemental analysis, FTIR, 1H‐NMR spectroscopy, and electrical conductivity. The polymerization yield depended on the substituent position in the aromatic ring. Copper ion was incorporated in the polymers and the amount depended on the side groups position in the aromatic ring. The thermal stability increased when copper ions and aniline units were incorporated in the polymers. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 31–36, 2004 |
| doi_str_mv | 10.1002/app.13630 |
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Study with Cu(II)</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>Poly(o‐amino benzyl amine), poly(m‐amino benzyl amine), and the copolymers with aniline were synthesized in 10−4M HCl by using ammonium persulfate as oxidizing agent. The copolymers were synthesized at various feed mole fractions of comonomer diamine and characterized by elemental analysis, FTIR, 1H‐NMR spectroscopy, and electrical conductivity. The polymerization yield depended on the substituent position in the aromatic ring. Copper ion was incorporated in the polymers and the amount depended on the side groups position in the aromatic ring. The thermal stability increased when copper ions and aniline units were incorporated in the polymers. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 31–36, 2004</description><subject>Applied sciences</subject><subject>copolymerization</subject><subject>Exact sciences and technology</subject><subject>infrared spectroscopy</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polymers with particular properties</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>supports</subject><subject>thermal properties</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNp1kEtvEzEUhS0EEqGw4B94A2oWk_oxfsyyCrREKlCpoEpsrBuPrRjmVXtCmf56nEyBFSvL93znWxyEXlOyooSwMxiGFeWSkydoQUmlilIy_RQtckYLXVXiOXqR0ndCKBVELtDPm6kbdy6FhKGrsd1BBDu6GB5gDH2He4-HvplO--KYtwW0oevx1nUPU4MPH7c8JlmCbX9gWxcTvg_jLt9Dk4EVvhn39TTf1vvTzWb5Ej3z0CT36vE9QV8v3n9ZfyiuPl9u1udXheVSkqL2omI1VCCVYiXbeqkdsWRbK6VL8DWArhgIzZkvPdM1ha3QSlZSMGJdRfgJejt7h9jf7V0aTRuSdU0Dnev3yTDNteKizOByBm3sU4rOmyGGFuJkKDGHZU1e1hyXzeybRykkC42P0NmQ_hWEqGjeN3NnM3cfGjf9X2jOr6__mIu5EdLofv1tQPxhpOJKmNtPl-Yj-fauvLjVRvHfOCyWdg</recordid><startdate>20040405</startdate><enddate>20040405</enddate><creator>Rivas, Bernabé L.</creator><creator>Sánchez, Christian O.</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20040405</creationdate><title>Synthesis and characterization of poly(o- and m-amino benzyl amine) and the copolymers with aniline. 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Study with Cu(II)</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2004-04-05</date><risdate>2004</risdate><volume>92</volume><issue>1</issue><spage>31</spage><epage>36</epage><pages>31-36</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>Poly(o‐amino benzyl amine), poly(m‐amino benzyl amine), and the copolymers with aniline were synthesized in 10−4M HCl by using ammonium persulfate as oxidizing agent. The copolymers were synthesized at various feed mole fractions of comonomer diamine and characterized by elemental analysis, FTIR, 1H‐NMR spectroscopy, and electrical conductivity. The polymerization yield depended on the substituent position in the aromatic ring. Copper ion was incorporated in the polymers and the amount depended on the side groups position in the aromatic ring. 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| subjects | Applied sciences copolymerization Exact sciences and technology infrared spectroscopy Organic polymers Physicochemistry of polymers Polymers with particular properties Preparation, kinetics, thermodynamics, mechanism and catalysts supports thermal properties |
| title | Synthesis and characterization of poly(o- and m-amino benzyl amine) and the copolymers with aniline. Study with Cu(II) |
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