Photodissociation dynamics of SO2 between 193 and 201 nm
The nonadiabatic interactions between the C̃ state and neighboring electronic states of SO2 have attracted much attention; however, the predissociation mechanisms are not yet completely understood. In this work, the predissociation dynamics of SO2 via its C̃ state have been investigated at λ = 193–2...
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Veröffentlicht in: | The Journal of chemical physics 2023-07, Vol.159 (2) |
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creator | Luo, Zijie Zhang, Zhaoxue Yang, Shuaikang Zhao, Yarui Li, Zhenxing He, Zhigang Chang, Yao Che, Li Yuan, Kaijun Yang, Xueming |
description | The nonadiabatic interactions between the C̃ state and neighboring electronic states of SO2 have attracted much attention; however, the predissociation mechanisms are not yet completely understood. In this work, the predissociation dynamics of SO2 via its C̃ state have been investigated at λ = 193–201 nm by using the time-sliced velocity map ion imaging technique. The translational energy distributions and the branching ratios of the O(3PJ=2,1,0) spin–orbit products at six photolysis wavelengths have been acquired. The SO(3Σ−) product population gradually decreases in v = 0 and increases in v = 2 as the photolysis wavelength decreases. The branching ratios of O(3P J=2,1,0) products are almost similar at most wavelengths, except at 194.8 nm. Our data suggest that the predissociation between 193 and 201 nm is via an avoided crossing between the C̃ state and the repulsive triplet 23A′ state. The state-to-state dynamical pictures shown in this work provide a rigorous test of the potential energy surfaces (PESs) of the SO2 and the nonadiabatic couplings between these PESs. |
doi_str_mv | 10.1063/5.0157095 |
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In this work, the predissociation dynamics of SO2 via its C̃ state have been investigated at λ = 193–201 nm by using the time-sliced velocity map ion imaging technique. The translational energy distributions and the branching ratios of the O(3PJ=2,1,0) spin–orbit products at six photolysis wavelengths have been acquired. The SO(3Σ−) product population gradually decreases in v = 0 and increases in v = 2 as the photolysis wavelength decreases. The branching ratios of O(3P J=2,1,0) products are almost similar at most wavelengths, except at 194.8 nm. Our data suggest that the predissociation between 193 and 201 nm is via an avoided crossing between the C̃ state and the repulsive triplet 23A′ state. The state-to-state dynamical pictures shown in this work provide a rigorous test of the potential energy surfaces (PESs) of the SO2 and the nonadiabatic couplings between these PESs.</description><identifier>ISSN: 0021-9606</identifier><identifier>EISSN: 1089-7690</identifier><identifier>DOI: 10.1063/5.0157095</identifier><identifier>PMID: 37439466</identifier><identifier>CODEN: JCPSA6</identifier><language>eng</language><publisher>United States: American Institute of Physics</publisher><subject>Couplings ; Electron states ; Imaging techniques ; Photodissociation ; Photolysis ; Potential energy ; Wavelengths</subject><ispartof>The Journal of chemical physics, 2023-07, Vol.159 (2)</ispartof><rights>Author(s)</rights><rights>2023 Author(s). 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In this work, the predissociation dynamics of SO2 via its C̃ state have been investigated at λ = 193–201 nm by using the time-sliced velocity map ion imaging technique. The translational energy distributions and the branching ratios of the O(3PJ=2,1,0) spin–orbit products at six photolysis wavelengths have been acquired. The SO(3Σ−) product population gradually decreases in v = 0 and increases in v = 2 as the photolysis wavelength decreases. The branching ratios of O(3P J=2,1,0) products are almost similar at most wavelengths, except at 194.8 nm. Our data suggest that the predissociation between 193 and 201 nm is via an avoided crossing between the C̃ state and the repulsive triplet 23A′ state. 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In this work, the predissociation dynamics of SO2 via its C̃ state have been investigated at λ = 193–201 nm by using the time-sliced velocity map ion imaging technique. The translational energy distributions and the branching ratios of the O(3PJ=2,1,0) spin–orbit products at six photolysis wavelengths have been acquired. The SO(3Σ−) product population gradually decreases in v = 0 and increases in v = 2 as the photolysis wavelength decreases. The branching ratios of O(3P J=2,1,0) products are almost similar at most wavelengths, except at 194.8 nm. Our data suggest that the predissociation between 193 and 201 nm is via an avoided crossing between the C̃ state and the repulsive triplet 23A′ state. 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subjects | Couplings Electron states Imaging techniques Photodissociation Photolysis Potential energy Wavelengths |
title | Photodissociation dynamics of SO2 between 193 and 201 nm |
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