Aspects of the crosslinking of polyethylene with vinyl silane
The crosslinking reaction of low‐density polyethylene with vinyl triethoxysilane was studied in great detail. The effects of a wide range of concentrations (0–27.33 phr silane and 0–1.25 phr benzoyl peroxide) on the mechanical properties, hot‐set testing, gel contents, and burning behaviors of the r...
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Veröffentlicht in: | Journal of applied polymer science 2004-06, Vol.92 (6), p.3796-3803 |
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description | The crosslinking reaction of low‐density polyethylene with vinyl triethoxysilane was studied in great detail. The effects of a wide range of concentrations (0–27.33 phr silane and 0–1.25 phr benzoyl peroxide) on the mechanical properties, hot‐set testing, gel contents, and burning behaviors of the resulting crosslinked polyethylene were studied. The effect of variations in the concentration of silane was found to be a dictating parameter for all these properties. Moreover, at or above a certain threshold concentration of silane (4.56 phr), samples not only qualified for hot‐set testing but also showed other properties at an optimum level. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 3796–3803, 2004 |
doi_str_mv | 10.1002/app.20381 |
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The effects of a wide range of concentrations (0–27.33 phr silane and 0–1.25 phr benzoyl peroxide) on the mechanical properties, hot‐set testing, gel contents, and burning behaviors of the resulting crosslinked polyethylene were studied. The effect of variations in the concentration of silane was found to be a dictating parameter for all these properties. Moreover, at or above a certain threshold concentration of silane (4.56 phr), samples not only qualified for hot‐set testing but also showed other properties at an optimum level. © 2004 Wiley Periodicals, Inc. 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Appl. Polym. Sci</addtitle><description>The crosslinking reaction of low‐density polyethylene with vinyl triethoxysilane was studied in great detail. The effects of a wide range of concentrations (0–27.33 phr silane and 0–1.25 phr benzoyl peroxide) on the mechanical properties, hot‐set testing, gel contents, and burning behaviors of the resulting crosslinked polyethylene were studied. The effect of variations in the concentration of silane was found to be a dictating parameter for all these properties. Moreover, at or above a certain threshold concentration of silane (4.56 phr), samples not only qualified for hot‐set testing but also showed other properties at an optimum level. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 3796–3803, 2004</description><subject>Applied sciences</subject><subject>crosslinking</subject><subject>Exact sciences and technology</subject><subject>flame retardance</subject><subject>mechanical properties</subject><subject>Physicochemistry of polymers</subject><subject>Polymer industry, paints, wood</subject><subject>Technology of polymers</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNp1kL1OwzAURi0EEqUw8AZZQGJIa-fHsQeGqoIWUUGFQB0t17mmpiYJcUrJ25M0BSYmS9fnO7r3Q-ic4AHBOBjKohgEOGTkAPUI5okf0YAdol7zR3zGeXyMTpx7w5iQGNMeuh65AlTlvFx71Qo8VebOWZOtTfbazorc1lCtagsZeFtTrbxPk9XWc8bKDE7RkZbWwdn-7aOX25vn8dSfPU7uxqOZr0JKiZ_GHGKlkiVdpiyKcSDDQDJIZcCxkpxwmtBIY5JqrSWP2FJKkpAUR1ynCoCHfXTZeYsy_9iAq8S7cQpsu0O-cSJgIWUxZw141YG7O0rQoijNuyxrQbBoCxJNQWJXUMNe7KXSKWl1KTNl3F8gppxFUcsNO25rLNT_C8VoPv8x-13CuAq-fhOyXAuahEksFg8TsZiP76dPCyxo-A1XH4Qn</recordid><startdate>20040615</startdate><enddate>20040615</enddate><creator>Shah, Gul Bali</creator><creator>Fuzail, Mohammad</creator><creator>Anwar, Jamil</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20040615</creationdate><title>Aspects of the crosslinking of polyethylene with vinyl silane</title><author>Shah, Gul Bali ; Fuzail, Mohammad ; Anwar, Jamil</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3661-d59e5cc7b6bd84502a32a8eda290ca9196764f01dfffa948baa171d049fdcee93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><topic>Applied sciences</topic><topic>crosslinking</topic><topic>Exact sciences and technology</topic><topic>flame retardance</topic><topic>mechanical properties</topic><topic>Physicochemistry of polymers</topic><topic>Polymer industry, paints, wood</topic><topic>Technology of polymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shah, Gul Bali</creatorcontrib><creatorcontrib>Fuzail, Mohammad</creatorcontrib><creatorcontrib>Anwar, Jamil</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shah, Gul Bali</au><au>Fuzail, Mohammad</au><au>Anwar, Jamil</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Aspects of the crosslinking of polyethylene with vinyl silane</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2004-06-15</date><risdate>2004</risdate><volume>92</volume><issue>6</issue><spage>3796</spage><epage>3803</epage><pages>3796-3803</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>The crosslinking reaction of low‐density polyethylene with vinyl triethoxysilane was studied in great detail. The effects of a wide range of concentrations (0–27.33 phr silane and 0–1.25 phr benzoyl peroxide) on the mechanical properties, hot‐set testing, gel contents, and burning behaviors of the resulting crosslinked polyethylene were studied. The effect of variations in the concentration of silane was found to be a dictating parameter for all these properties. Moreover, at or above a certain threshold concentration of silane (4.56 phr), samples not only qualified for hot‐set testing but also showed other properties at an optimum level. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 3796–3803, 2004</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.20381</doi><tpages>8</tpages></addata></record> |
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subjects | Applied sciences crosslinking Exact sciences and technology flame retardance mechanical properties Physicochemistry of polymers Polymer industry, paints, wood Technology of polymers |
title | Aspects of the crosslinking of polyethylene with vinyl silane |
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