Hydrothermally synthesized Ag-TiO2 nanofibers (NFs) for photocatalytic dye degradation and antibacterial activity
This work successfully utilised eco-friendly green synthesis to produce Ag–TiO2 nanofibers (NFs). As pollution and energy limitations have become global issues, there is an ongoing need to develop more effective catalysts through straightforward and environmentally friendly methods. The Ag–TiO2 nano...
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Veröffentlicht in: | Chemosphere (Oxford) 2023-04, Vol.321, p.138077-138077, Article 138077 |
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creator | Aravind, M. Amalanathan, M. Aslam, Sadia Noor, Arsh E Jini, D. Majeed, Saadat Velusamy, P. Alothman, Asma A. Alshgari, Razan A. Saleh Mushab, Mohammed Sheikh Sillanpaa, Mika |
description | This work successfully utilised eco-friendly green synthesis to produce Ag–TiO2 nanofibers (NFs). As pollution and energy limitations have become global issues, there is an ongoing need to develop more effective catalysts through straightforward and environmentally friendly methods. The Ag–TiO2 nanofibers (NFs) XRD pattern exhibits an anatase TiO2 and FCC crystal structure of Ag nanoparticles. The SEM investigation revealed a nanofiber-like surface morphology. The Ag–TiO2 nanofibers (NFs) exhibits an optical band gap energy is 2.5 eV. Methylene blue (MB), malachite green (MG), Congo red (CR), and crystal violet (CV) dye aqueous solutions were used to evaluate the photocatalytic performance of the synthesized Ag-modified TiO2 nanofibers (NFs) under direct sunlight irradiation. The effects of catalyst size on the efficient breakdown of MB dye were also investigated. The optimum catalyst concentration was found to be at 0.02 mg/mL. At 120 min of direct sunlight, the highest photosynthetic degradation efficiency (DE percentage) of 94% was achieved for MB dye. Ag–TiO2 nanofibers (NFs) have been demonstrated to have exceptional antibacterial activity against Gram-positive bacteria such as Staphylococcus aureus and Gram-negative bacteria E-Coli. Because of these great qualities, it seems likely that the Ag–TiO2 nanofibers (NFs) made could be a great photocatalyst for getting dye pollutants out of wastewater.
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•Ag nanoparticles modified with TiO2 nanofibers was synthesized by the hydrothermal method.•TheAg-TiO2 Nanofiber achieved high photocatalytic performance toward the removal of Methylene blue.•The Ag–TiO2 Nanofibers displayed the attractive antibacterial efficacy against both gram positive and gram negative bacteria.•The Ag–TiO2 nanofibers are suitable for waste water treatment and biomedical applications. |
doi_str_mv | 10.1016/j.chemosphere.2023.138077 |
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[Display omitted]
•Ag nanoparticles modified with TiO2 nanofibers was synthesized by the hydrothermal method.•TheAg-TiO2 Nanofiber achieved high photocatalytic performance toward the removal of Methylene blue.•The Ag–TiO2 Nanofibers displayed the attractive antibacterial efficacy against both gram positive and gram negative bacteria.•The Ag–TiO2 nanofibers are suitable for waste water treatment and biomedical applications.</description><identifier>ISSN: 0045-6535</identifier><identifier>EISSN: 1879-1298</identifier><identifier>DOI: 10.1016/j.chemosphere.2023.138077</identifier><language>eng</language><publisher>Elsevier Ltd</publisher><subject>Antibacterial ; antibacterial properties ; crystal structure ; energy ; gentian violet ; Hydrothermal method ; irradiation ; malachite green ; Methylene blue ; nanofibers ; nanosilver ; photocatalysis ; photocatalysts ; Photodegradation ; photosynthesis ; pollution ; solar radiation ; Staphylococcus aureus ; Visible light irradiations ; wastewater</subject><ispartof>Chemosphere (Oxford), 2023-04, Vol.321, p.138077-138077, Article 138077</ispartof><rights>2023 Elsevier Ltd</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c387t-eac2291471c5b3a6b8ab1c98235e656cecf62c5376c241dc7afbca1ca4d3f1f3</citedby><cites>FETCH-LOGICAL-c387t-eac2291471c5b3a6b8ab1c98235e656cecf62c5376c241dc7afbca1ca4d3f1f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0045653523003442$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids></links><search><creatorcontrib>Aravind, M.</creatorcontrib><creatorcontrib>Amalanathan, M.</creatorcontrib><creatorcontrib>Aslam, Sadia</creatorcontrib><creatorcontrib>Noor, Arsh E</creatorcontrib><creatorcontrib>Jini, D.</creatorcontrib><creatorcontrib>Majeed, Saadat</creatorcontrib><creatorcontrib>Velusamy, P.</creatorcontrib><creatorcontrib>Alothman, Asma A.</creatorcontrib><creatorcontrib>Alshgari, Razan A.</creatorcontrib><creatorcontrib>Saleh Mushab, Mohammed Sheikh</creatorcontrib><creatorcontrib>Sillanpaa, Mika</creatorcontrib><title>Hydrothermally synthesized Ag-TiO2 nanofibers (NFs) for photocatalytic dye degradation and antibacterial activity</title><title>Chemosphere (Oxford)</title><description>This work successfully utilised eco-friendly green synthesis to produce Ag–TiO2 nanofibers (NFs). As pollution and energy limitations have become global issues, there is an ongoing need to develop more effective catalysts through straightforward and environmentally friendly methods. The Ag–TiO2 nanofibers (NFs) XRD pattern exhibits an anatase TiO2 and FCC crystal structure of Ag nanoparticles. The SEM investigation revealed a nanofiber-like surface morphology. The Ag–TiO2 nanofibers (NFs) exhibits an optical band gap energy is 2.5 eV. Methylene blue (MB), malachite green (MG), Congo red (CR), and crystal violet (CV) dye aqueous solutions were used to evaluate the photocatalytic performance of the synthesized Ag-modified TiO2 nanofibers (NFs) under direct sunlight irradiation. The effects of catalyst size on the efficient breakdown of MB dye were also investigated. The optimum catalyst concentration was found to be at 0.02 mg/mL. At 120 min of direct sunlight, the highest photosynthetic degradation efficiency (DE percentage) of 94% was achieved for MB dye. Ag–TiO2 nanofibers (NFs) have been demonstrated to have exceptional antibacterial activity against Gram-positive bacteria such as Staphylococcus aureus and Gram-negative bacteria E-Coli. Because of these great qualities, it seems likely that the Ag–TiO2 nanofibers (NFs) made could be a great photocatalyst for getting dye pollutants out of wastewater.
[Display omitted]
•Ag nanoparticles modified with TiO2 nanofibers was synthesized by the hydrothermal method.•TheAg-TiO2 Nanofiber achieved high photocatalytic performance toward the removal of Methylene blue.•The Ag–TiO2 Nanofibers displayed the attractive antibacterial efficacy against both gram positive and gram negative bacteria.•The Ag–TiO2 nanofibers are suitable for waste water treatment and biomedical applications.</description><subject>Antibacterial</subject><subject>antibacterial properties</subject><subject>crystal structure</subject><subject>energy</subject><subject>gentian violet</subject><subject>Hydrothermal method</subject><subject>irradiation</subject><subject>malachite green</subject><subject>Methylene blue</subject><subject>nanofibers</subject><subject>nanosilver</subject><subject>photocatalysis</subject><subject>photocatalysts</subject><subject>Photodegradation</subject><subject>photosynthesis</subject><subject>pollution</subject><subject>solar radiation</subject><subject>Staphylococcus aureus</subject><subject>Visible light irradiations</subject><subject>wastewater</subject><issn>0045-6535</issn><issn>1879-1298</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNqNkU1v1DAQhi0EEkvhP5hbOWTxR2wnx2pFKVJFL3u3JuNJ16tsvLXdSuHXk2o5cIPDaGak9xlp9DD2WYqtFNJ-PW7xQKdUzgfKtFVC6a3UnXDuDdvIzvWNVH33lm2EaE1jjTbv2YdSjkKssOk37OluCTnVlT7BNC28LPO6lPiLAr95bPbxQfEZ5jTGgXLh1z9vyxc-pszPh1QTQoVpqRF5WIgHeswQoMY0c5jDWjUOgJVyhImvQ3yJdfnI3o0wFfr0p1-x_e23_e6uuX_4_mN3c9-g7lxtCFCpXrZOohk02KGDQWLfKW3IGouEo1VotLOoWhnQwTggSIQ26FGO-opdX86ec3p6plL9KRakaYKZ0nPxqtOtEp3U_b-jzhkrtRB2jfaXKOZUSqbRn3M8QV68FP5ViD_6v4T4VyH-ImRldxeW1q9fImVfMNKMFGImrD6k-B9XfgMZWZzD</recordid><startdate>202304</startdate><enddate>202304</enddate><creator>Aravind, M.</creator><creator>Amalanathan, M.</creator><creator>Aslam, Sadia</creator><creator>Noor, Arsh E</creator><creator>Jini, D.</creator><creator>Majeed, Saadat</creator><creator>Velusamy, P.</creator><creator>Alothman, Asma A.</creator><creator>Alshgari, Razan A.</creator><creator>Saleh Mushab, Mohammed Sheikh</creator><creator>Sillanpaa, Mika</creator><general>Elsevier Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7S9</scope><scope>L.6</scope></search><sort><creationdate>202304</creationdate><title>Hydrothermally synthesized Ag-TiO2 nanofibers (NFs) for photocatalytic dye degradation and antibacterial activity</title><author>Aravind, M. ; Amalanathan, M. ; Aslam, Sadia ; Noor, Arsh E ; Jini, D. ; Majeed, Saadat ; Velusamy, P. ; Alothman, Asma A. ; Alshgari, Razan A. ; Saleh Mushab, Mohammed Sheikh ; Sillanpaa, Mika</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c387t-eac2291471c5b3a6b8ab1c98235e656cecf62c5376c241dc7afbca1ca4d3f1f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Antibacterial</topic><topic>antibacterial properties</topic><topic>crystal structure</topic><topic>energy</topic><topic>gentian violet</topic><topic>Hydrothermal method</topic><topic>irradiation</topic><topic>malachite green</topic><topic>Methylene blue</topic><topic>nanofibers</topic><topic>nanosilver</topic><topic>photocatalysis</topic><topic>photocatalysts</topic><topic>Photodegradation</topic><topic>photosynthesis</topic><topic>pollution</topic><topic>solar radiation</topic><topic>Staphylococcus aureus</topic><topic>Visible light irradiations</topic><topic>wastewater</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Aravind, M.</creatorcontrib><creatorcontrib>Amalanathan, M.</creatorcontrib><creatorcontrib>Aslam, Sadia</creatorcontrib><creatorcontrib>Noor, Arsh E</creatorcontrib><creatorcontrib>Jini, D.</creatorcontrib><creatorcontrib>Majeed, Saadat</creatorcontrib><creatorcontrib>Velusamy, P.</creatorcontrib><creatorcontrib>Alothman, Asma A.</creatorcontrib><creatorcontrib>Alshgari, Razan A.</creatorcontrib><creatorcontrib>Saleh Mushab, Mohammed Sheikh</creatorcontrib><creatorcontrib>Sillanpaa, Mika</creatorcontrib><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>AGRICOLA</collection><collection>AGRICOLA - Academic</collection><jtitle>Chemosphere (Oxford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Aravind, M.</au><au>Amalanathan, M.</au><au>Aslam, Sadia</au><au>Noor, Arsh E</au><au>Jini, D.</au><au>Majeed, Saadat</au><au>Velusamy, P.</au><au>Alothman, Asma A.</au><au>Alshgari, Razan A.</au><au>Saleh Mushab, Mohammed Sheikh</au><au>Sillanpaa, Mika</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Hydrothermally synthesized Ag-TiO2 nanofibers (NFs) for photocatalytic dye degradation and antibacterial activity</atitle><jtitle>Chemosphere (Oxford)</jtitle><date>2023-04</date><risdate>2023</risdate><volume>321</volume><spage>138077</spage><epage>138077</epage><pages>138077-138077</pages><artnum>138077</artnum><issn>0045-6535</issn><eissn>1879-1298</eissn><abstract>This work successfully utilised eco-friendly green synthesis to produce Ag–TiO2 nanofibers (NFs). As pollution and energy limitations have become global issues, there is an ongoing need to develop more effective catalysts through straightforward and environmentally friendly methods. The Ag–TiO2 nanofibers (NFs) XRD pattern exhibits an anatase TiO2 and FCC crystal structure of Ag nanoparticles. The SEM investigation revealed a nanofiber-like surface morphology. The Ag–TiO2 nanofibers (NFs) exhibits an optical band gap energy is 2.5 eV. Methylene blue (MB), malachite green (MG), Congo red (CR), and crystal violet (CV) dye aqueous solutions were used to evaluate the photocatalytic performance of the synthesized Ag-modified TiO2 nanofibers (NFs) under direct sunlight irradiation. The effects of catalyst size on the efficient breakdown of MB dye were also investigated. The optimum catalyst concentration was found to be at 0.02 mg/mL. At 120 min of direct sunlight, the highest photosynthetic degradation efficiency (DE percentage) of 94% was achieved for MB dye. Ag–TiO2 nanofibers (NFs) have been demonstrated to have exceptional antibacterial activity against Gram-positive bacteria such as Staphylococcus aureus and Gram-negative bacteria E-Coli. Because of these great qualities, it seems likely that the Ag–TiO2 nanofibers (NFs) made could be a great photocatalyst for getting dye pollutants out of wastewater.
[Display omitted]
•Ag nanoparticles modified with TiO2 nanofibers was synthesized by the hydrothermal method.•TheAg-TiO2 Nanofiber achieved high photocatalytic performance toward the removal of Methylene blue.•The Ag–TiO2 Nanofibers displayed the attractive antibacterial efficacy against both gram positive and gram negative bacteria.•The Ag–TiO2 nanofibers are suitable for waste water treatment and biomedical applications.</abstract><pub>Elsevier Ltd</pub><doi>10.1016/j.chemosphere.2023.138077</doi><tpages>1</tpages></addata></record> |
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subjects | Antibacterial antibacterial properties crystal structure energy gentian violet Hydrothermal method irradiation malachite green Methylene blue nanofibers nanosilver photocatalysis photocatalysts Photodegradation photosynthesis pollution solar radiation Staphylococcus aureus Visible light irradiations wastewater |
title | Hydrothermally synthesized Ag-TiO2 nanofibers (NFs) for photocatalytic dye degradation and antibacterial activity |
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