Plasma-treated triazole as a novel organic slow-release paint pigment for corrosion control of AA2024-T3
Triazole is effective for corrosion control of AA2024-T3 which is well known to contain Cu-rich intermetallics. However, it cannot be used as a paint pigment because of its high water-solubility. In this research, we present a novel method to modify water-soluble triazole particles using a plasma po...
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Veröffentlicht in: | Progress in organic coatings 2004-08, Vol.50 (3), p.149-161 |
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description | Triazole is effective for corrosion control of AA2024-T3 which is well known to contain Cu-rich intermetallics. However, it cannot be used as a paint pigment because of its high water-solubility. In this research, we present a novel method to modify water-soluble triazole particles using a plasma polymerization technique. Time-of-flight secondary ion mass spectrometry (TOFSIMS) confirmed the presence of an ultrathin polymer film on the particles. The plasma-treated triazole was used as a paint pigment in a water-based epoxy coating. Using electrochemical impedance spectroscopy (EIS) techniques and immersion tests, it was demonstrated that the encapsulated water-soluble inhibitor could slowly release into the environment to protect a metal as needed. This technique is a feasible and promising method to promote the replacement of chromate pigments in paints. |
doi_str_mv | 10.1016/j.porgcoat.2003.10.006 |
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However, it cannot be used as a paint pigment because of its high water-solubility. In this research, we present a novel method to modify water-soluble triazole particles using a plasma polymerization technique. Time-of-flight secondary ion mass spectrometry (TOFSIMS) confirmed the presence of an ultrathin polymer film on the particles. The plasma-treated triazole was used as a paint pigment in a water-based epoxy coating. Using electrochemical impedance spectroscopy (EIS) techniques and immersion tests, it was demonstrated that the encapsulated water-soluble inhibitor could slowly release into the environment to protect a metal as needed. This technique is a feasible and promising method to promote the replacement of chromate pigments in paints.</description><identifier>ISSN: 0300-9440</identifier><identifier>EISSN: 1873-331X</identifier><identifier>DOI: 10.1016/j.porgcoat.2003.10.006</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>Applied sciences ; Chromate pigments ; Coatings. Paints, varnishes and inks ; Corrosion ; EIS ; Exact sciences and technology ; Manufacturing ; Paint pigment ; Plasma polymerization ; Polymer industry, paints, wood ; Slow-release ; Triazole</subject><ispartof>Progress in organic coatings, 2004-08, Vol.50 (3), p.149-161</ispartof><rights>2004 Elsevier B.V.</rights><rights>2004 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c412t-9daa0e43f310bd2abf44a9b43d4b796c83bcffd9edfb7dd0475a3fbee54e408c3</citedby><cites>FETCH-LOGICAL-c412t-9daa0e43f310bd2abf44a9b43d4b796c83bcffd9edfb7dd0475a3fbee54e408c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.porgcoat.2003.10.006$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,777,781,3537,27905,27906,45976</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=15791968$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Yang, Hai</creatorcontrib><creatorcontrib>van Ooij, Wim J.</creatorcontrib><title>Plasma-treated triazole as a novel organic slow-release paint pigment for corrosion control of AA2024-T3</title><title>Progress in organic coatings</title><description>Triazole is effective for corrosion control of AA2024-T3 which is well known to contain Cu-rich intermetallics. However, it cannot be used as a paint pigment because of its high water-solubility. In this research, we present a novel method to modify water-soluble triazole particles using a plasma polymerization technique. Time-of-flight secondary ion mass spectrometry (TOFSIMS) confirmed the presence of an ultrathin polymer film on the particles. The plasma-treated triazole was used as a paint pigment in a water-based epoxy coating. Using electrochemical impedance spectroscopy (EIS) techniques and immersion tests, it was demonstrated that the encapsulated water-soluble inhibitor could slowly release into the environment to protect a metal as needed. This technique is a feasible and promising method to promote the replacement of chromate pigments in paints.</description><subject>Applied sciences</subject><subject>Chromate pigments</subject><subject>Coatings. Paints, varnishes and inks</subject><subject>Corrosion</subject><subject>EIS</subject><subject>Exact sciences and technology</subject><subject>Manufacturing</subject><subject>Paint pigment</subject><subject>Plasma polymerization</subject><subject>Polymer industry, paints, wood</subject><subject>Slow-release</subject><subject>Triazole</subject><issn>0300-9440</issn><issn>1873-331X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNqFkE1rHDEMhk1JoZtt_0LxJbnNVh575-OWJaQfEGgPKfRmNLacevGOJ7aT0v76etmEHnuSEI_eV3oZey9gI0B0H_abJaZ7E7FsWgBZhxuA7hVbiaGXjZTixxlbgQRoRqXgDTvPeQ-VkHJcsZ_fAuYDNiURFrK8JI9_YiCOmSOf4xMFXtVx9obnEH81iQJhJr6gnwtf_P2BanUxcRNTitnHuXZzSbEuOr7btdCq5k6-Za8dhkzvnuuaff94c3f9ubn9-unL9e62MUq0pRktIpCSTgqYbIuTUwrHSUmrpn7szCAn45wdybqptxZUv0XpJqKtIgWDkWt2edJdUnx4pFz0wWdDIeBM8THrdqh_C9VXsDuBpl6dEzm9JH_A9FsL0Mdg9V6_BKuPwR7nx9jW7OLZAbPB4BLOxud_29t-FGM3VO7qxFF998lT0tl4mg1Zn8gUbaP_n9VfgrWUDQ</recordid><startdate>20040801</startdate><enddate>20040801</enddate><creator>Yang, Hai</creator><creator>van Ooij, Wim J.</creator><general>Elsevier B.V</general><general>Elsevier Sequoia</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7SE</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20040801</creationdate><title>Plasma-treated triazole as a novel organic slow-release paint pigment for corrosion control of AA2024-T3</title><author>Yang, Hai ; van Ooij, Wim J.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c412t-9daa0e43f310bd2abf44a9b43d4b796c83bcffd9edfb7dd0475a3fbee54e408c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><topic>Applied sciences</topic><topic>Chromate pigments</topic><topic>Coatings. Paints, varnishes and inks</topic><topic>Corrosion</topic><topic>EIS</topic><topic>Exact sciences and technology</topic><topic>Manufacturing</topic><topic>Paint pigment</topic><topic>Plasma polymerization</topic><topic>Polymer industry, paints, wood</topic><topic>Slow-release</topic><topic>Triazole</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yang, Hai</creatorcontrib><creatorcontrib>van Ooij, Wim J.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Corrosion Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Progress in organic coatings</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yang, Hai</au><au>van Ooij, Wim J.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Plasma-treated triazole as a novel organic slow-release paint pigment for corrosion control of AA2024-T3</atitle><jtitle>Progress in organic coatings</jtitle><date>2004-08-01</date><risdate>2004</risdate><volume>50</volume><issue>3</issue><spage>149</spage><epage>161</epage><pages>149-161</pages><issn>0300-9440</issn><eissn>1873-331X</eissn><abstract>Triazole is effective for corrosion control of AA2024-T3 which is well known to contain Cu-rich intermetallics. However, it cannot be used as a paint pigment because of its high water-solubility. In this research, we present a novel method to modify water-soluble triazole particles using a plasma polymerization technique. Time-of-flight secondary ion mass spectrometry (TOFSIMS) confirmed the presence of an ultrathin polymer film on the particles. The plasma-treated triazole was used as a paint pigment in a water-based epoxy coating. Using electrochemical impedance spectroscopy (EIS) techniques and immersion tests, it was demonstrated that the encapsulated water-soluble inhibitor could slowly release into the environment to protect a metal as needed. This technique is a feasible and promising method to promote the replacement of chromate pigments in paints.</abstract><cop>Lausanne</cop><pub>Elsevier B.V</pub><doi>10.1016/j.porgcoat.2003.10.006</doi><tpages>13</tpages></addata></record> |
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subjects | Applied sciences Chromate pigments Coatings. Paints, varnishes and inks Corrosion EIS Exact sciences and technology Manufacturing Paint pigment Plasma polymerization Polymer industry, paints, wood Slow-release Triazole |
title | Plasma-treated triazole as a novel organic slow-release paint pigment for corrosion control of AA2024-T3 |
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