Performance of a magnesium-lithium alloy as an anode for magnesium batteries

In this work, we describe an evaluation of an Mg-Li alloy (Li: 13 wt %) for possible use in magnesium primary reserve batteries. Higher OCP for the Mg-Li alloy have been observed in 2 M MgCl2 and MgBr2 electrolyte. The corrosion rate of the Mg-Li alloy is found to be in the order: MgCl2 < Mg(COOC...

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Veröffentlicht in:Journal of applied electrochemistry 2004-11, Vol.34 (11), p.1135-1139
Hauptverfasser: SIVASHANMUGAM, A, PREM KUMAR, T, RENGANATHAN, N. G, GOPUKUMAR, S
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Sprache:eng
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Zusammenfassung:In this work, we describe an evaluation of an Mg-Li alloy (Li: 13 wt %) for possible use in magnesium primary reserve batteries. Higher OCP for the Mg-Li alloy have been observed in 2 M MgCl2 and MgBr2 electrolyte. The corrosion rate of the Mg-Li alloy is found to be in the order: MgCl2 < Mg(COOCH3)2 < MgSO4 < MgBrz < Mg(ClO4)2. Mg-Li alloys exhibit higher (81 %) anodic efficiencies even when the current density is increased to 8.6 mA cm-2. It has been observed that Mg-Li/MgCl2/CuO cells offer higher operating voltage and capacity than those with the conventionally used Mg-Al alloy.
ISSN:0021-891X
1572-8838
DOI:10.1007/s10800-004-2728-3